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Kinetic Study of Cyclization of High-Tacticity Polyacrylonitrile Heat-Treated under Air Atmosphere via XRD  

Xu, Zhi-Xian (Anyang Normal College)
Xu, Jing (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology)
Xu, Liang-Hua (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology)
Dai, Yong-Qiang (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology)
Xue, Li-Wei (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology)
Jin, Ri-Guang (State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology)
Publication Information
Polymer(Korea) / v.32, no.2, 2008 , pp. 150-156 More about this Journal
Abstract
Two different polyacrylonitrile samples (PANs, triad tacticity fraction is 0.25 and 0.64) were synthesized and used to study the kinetics of cyclization. Polymers were treated at different temperatures between 250 to $300^{\circ}C$ under air atmosphere, and analyzed by X-ray diffractometer. The sharp and strong peak at $2{\theta}=16.5^{\circ}$ corresponds to a lateral repeat distance that is the (100) diffraction in hexagonal lattice, while the peak at $2{\theta}=25.5^{\circ}$ reflects the (101) diffraction. In comparing their areas of different heat treated samples, the cyclization of both PANs was identified as a first-order reaction. The rate constants of cyclization reaction at different temperatures and the active energy parameter were obtained. This results might provide an important effect on pre-oxidation of polyacrylonitrile fiber.
Keywords
high-tacticity polyacrylonitrile; cyclization; kinetics;
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