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Characterization of Ionic Liquid Contained Polymer Gel Electrolyte  

Ryu, Sang-Woog (School of Chemical Engineering, College of Engineering. Chungbuk National University)
Song, Eui-Hwan (Samsung SDI Corporate R&D Center)
Publication Information
Polymer(Korea) / v.32, no.1, 2008 , pp. 85-89 More about this Journal
Abstract
Acrylate polymer gel electrolytes containing N-methoxymethyl-N-methylpyrrolidium bis (trifluoro - methansulfonyl) imide (MPSI) as an ionic liquid were synthesized by solution polymerization in the presence of carbonate solvent. ionic conductivity and mechanical properties of the polymer gel electrolytes were investigated by impedance analyzer and universal testing machine as a function of the amount of polymer, and ionic liquid and type of crosslinker. The maximum ionic conductivity of polymer gel electrolytes was 0.8 mS/cm at $25^{\circ}C$ with 15 wt% of polymer, 30 wt% of ionic liquid and 5 wt% of crosslinker. The mechanical analysis showed that the tensile strength of polymer gel electrolytes increased with additional polymer contents and had the maximum value of 0.5 MPa with a reasonable ionic conductivity.
Keywords
ionic liquid; polymer gel electrolyte; ionic conductivity; tensile strength; electrochemical stability;
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