Browse > Article

Characterizations of Cellulose Blend Films: Morphology, Mechanical Property, and Gas Permeability  

Jang, Seo-Won (Department of Polymer Science and Engineering, Kumoh National Institute of Technology)
Chang, Jin-Hae (Department of Polymer Science and Engineering, Kumoh National Institute of Technology)
Publication Information
Polymer(Korea) / v.32, no.1, 2008 , pp. 63-69 More about this Journal
Abstract
The mechanical properties and morphologies of cellulose blends with two different additives were compared. Poly (vinyl alcohol) (PVA) of ethylene glycol (EG) were used as additives in the formation of cellulose blends through the solution blending. The properties of blends were varied with the additive content in the polymer matrix. The ultimate tensile strength and initial modulus of the cellulose blends were highest for a blend PVA content of 30 wt% and for a blend EG content of 10 wt%, respectively. Ternary blended systems of composition of cellulose/PVA (70/30=w/w)/EG were also prepared by the solution blending method with different EG contents. The mechanical properties of these systems were found to be optimal for EG contents of up to 40 wt%. The mechanical properties of the cellulose ternary blend films were superior to those of the cellulose binary blend films. The oxygen permeability transmission rate ($O_2TR$) monotonically decreased with increasing EG content in the ternary blend films. Overall, the mechanical properties of the cellulose blend films were found to be better than those of pure cellulose films.
Keywords
collulose; poly (vinyl alcohol); ethylene glycol; blend; film;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
Times Cited By Web Of Science : 0  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
연도 인용수 순위
1 Y. Ikeda and H. Tsuji, Macromol. Rapid Commun., 21, 117 (2000)   DOI   ScienceOn
2 D. N. Saheb and J. P. Jog, Adv. Polym. Technol., 18, 351 (1999)   DOI   ScienceOn
3 W. M. patrick, Regenerated Cellulose Fibers, CRC Press, Cambridge UK., Chap. 4 (2001)
4 T. Rosenau, A. Potthast, H. Sixta, and P. Kosma, Prog. Polym. Sci., 26, 1763 (2001)   DOI   ScienceOn
5 J. C. Grunlan, A. Grigorian, C. B. Hamilton, and A. R. Mehrabi, J. Appl. Polym. Sci., 93, 1102 (2004)   DOI   ScienceOn
6 X. Li, T. Kang, W.-J. Jo, J.-K. Lee, and C.-S. Ha, Macromol. Rapid Commum., 22, 1306 (2001)   DOI   ScienceOn
7 J.-H. Chang, D.-K. Park, and K. J. Ihn, J. Polym. Sci.; Part B: Polym. Phys., 39, 471 (2001)   DOI   ScienceOn
8 S. Y. Nam, K. S. Sung, S. W. Chon, and J. W. Rhim, Membrane J., 12, 255 (2002)
9 O. Kanie, A. Tanaka, T. Mayumi, T. Kitaoka, and H. Wariishi, J. Appl. Polym. Sci., 96, 861 (2005)   DOI   ScienceOn
10 J. W. Rhim, H. S. Hwang, D. S. Kim, H. B. Park, C. H. Lee, Y. M. Lee, G. Y. Moon, and S. Y. Nam, Macromol. Res., 13, 135 (2005)   과학기술학회마을   DOI
11 A. B. Morgan and J. W. Gilman, J. Appl. Polym. Sci., 87, 1329 (2003)   DOI   ScienceOn
12 C. R. Woodings, Int. J. Biol. Macromol., 17, 305 (1995)   DOI   ScienceOn
13 Y. H. Park, C. S. Ki, I. C. Um, and D. H. Baek, Polym. Sci. Tech., 16, 542 (2005)
14 S. Mitsushiro, Y. Hiroyuki, K. Hidenobu, and N. Shunji, Polymer, 29, 2066 (1988)   DOI   ScienceOn
15 H. Chanzy, S. Peguy, S. Chaunis, and P. Monzie, J. Polym. Sci.; Part B: Polym. Phys., 18, 1137 (1980)   DOI
16 J.-H. Chang, T.-G. Jang, K. J. Ihn, W.-K. Lee, and G. S. Sur, J. Appl. Polym. Sci., 90, 3208 (2003)   DOI   ScienceOn
17 B. C. Kim, Polym. Sci. Tech., 8, 573 (1997)
18 G. Galgali, C. Ramesh, and A. Lele, Macromolecules, 34, 852 (2001)   DOI   ScienceOn
19 R. A.Vaia, K. D. Jandt, E. J. Kramer, and E. P. Giannelis, Chem. Mater., 8, 2628 (1996)   DOI   ScienceOn
20 A. K. Bledzki and J. Gassan, Prog. Polym. Sci., 24, 221 (1999)   DOI   ScienceOn
21 S.-K. Ham, M. H. Jung, and J.-H. Chang, Polymer(Korea), 30, 545 (2006)   과학기술학회마을
22 S.-K. Ham, M. H. Jung, and J.-H. Chang, Polymer(Korea), 30, 298 (2006)   과학기술학회마을
23 R. Thomas, P. Antje, S. Herbert, and K. Paul, Prog. Polym. Sci., 26, 1763 (2001)   DOI   ScienceOn
24 J.-H. Yeun, G.-S. Bang, B. J. Park, S. K. Ham, and J.-H. Chang, J. Appl. Polym. Sci., 101, 591 (2006)   DOI   ScienceOn