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Flame Retardancy of UV-Cured Epoxy Acrylate Resin Containing Combined Flame Retardants  

Kim, Ho-Gyum (Department of Polymer Science, Kyungpook National University)
Lee, Dong-Ho (Department of Polymer Science, Kyungpook National University)
Min, Kyung-Eun (Department of Polymer Science, Kyungpook National University)
Publication Information
Polymer(Korea) / v.31, no.1, 2007 , pp. 53-57 More about this Journal
Abstract
In this study, the flame retardancy and tensile properties of epoxy acrylate resin containing flame retardants based on phosphorous, bromine or metal hydroxide are investigated. It was found that the enhancement in flame retardancy of epoxy acrylate with decabromodiphenyl oxide (DECA) addition was better than the addition of 2,2,2-trichloroethyl dichlorophosphate (TCEDP). It seems that the high loading of TCEDP may delay the formation of crosslinking network and consequently decreases the conversion of epoxy acrylate. It was found that magnesium hydroxide ($Mg(OH)_2$) does not improve the flame retardancy of epoxy acrylate after added up to 40 wt%. The synergic effects were clearly observed for epoxy acrylate containing DECA/TCEDP combined flame retardants.
Keywords
epoxy; flame retardant; montmorillonite; UL-94V; UV;
Citations & Related Records
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Times Cited By Web Of Science : 0  (Related Records In Web of Science)
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1 D. K. Chattopadhyay, S. S. Panda, and K. V. S. N. Raju, Prog. Org. Coat., 54, 10 (2005)   DOI
2 S. Jahromi, W. Gabrielse, and A. Braam, Polymer, 44, 25 (1993)
3 P. R. Hornsby, Fire Mater., 18, 269 (1994)
4 Z. Z. Wang, B. J. Qu, W. C. Fan, and D. Huang, J Appl. Polym. Sci., 81, 206 (2001)   DOI   ScienceOn
5 J. D. Nam and K. J. Ahn, Polym. Sci. Tech. (Korea). 6, 459 (1995)
6 J. H. Lee, J. H. Nam, D. H. Lee, M. D. Kim, J. H. Kong, Y. K. Lee, and J. D. Nam, Polymer(Korea), 27, 569 (2003)
7 W. C. Kuryla and A. J. Papa, Flame Retardancy of Polymeric Materials, Marcel Dekker, N. Y., 1973-1978
8 S. B. Kwak, S. D. Hwang, J. D. Nam, J. S. Ko, H. K. Choi, and J. H. Kong, Polymer(Korea), 26, 260 (2002)
9 C. P. Yang and T. W. Lee, J. Appl. Polym. Sci., Part A; Polym. Chem., 27, 2239 (1989)   DOI
10 J. S. Jang, H. S. Chung, M. H. Kim, and H. J. Sung, Polym. Test., 19, 269 (2000)
11 J. Wang, M. Y. Tung, F. Ahmad, and P. R. Hornsby, J Appl. Polym. Sci., 60, 1425 (1996)
12 C. P. Yang. and T. W. Lee, J. Appl. Polym. Sci., Part A; Polym. Chem., 27, 3551 (1989)   DOI
13 G. Pal and H. Macskav, Plastics, Their Behavior in Fires, Elsevier, Amsterdam, 1991
14 Y. Tanaka, Epoxy Resin Chemistry and Technology, Marcel Dekker, N. Y., 1998
15 J. P. Kim, S. G. Lyu, K. S. Bae, and S. G. Sur, Polymer (Korea), 25, 263 (2001)
16 C. P. Yang and T. W. Lee, J. Appl. Polym. Sci., 32, 3005 (2006)
17 J. Ding and W. Shi, Polym. Degrad Stabil., 84,159 (2004)   DOI   ScienceOn
18 J. Green, Polym. Degrad. Stabil., 54,189 (1996)
19 C. L. Chiang and C. C. M. Ma, Eur. Polym. J., 38, 2219 (2002)
20 J. H. Hong, UV Radiation Coating, Chosun University Press, 2002
21 I. W. Shim, H. J. Jo, H. S. Park, S. K. Kim, and Y. G. Kim, Polymer(Korea), 30, 238 (2006)   과학기술학회마을
22 S. J. Park, S. W. Song, J. R. Lee, B. G. Min, and J. S. Shin, J. Korea Ind. Eng. Chem., 15, 41 (2004)