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Synthesis and Luminescent Characteristics of Anthracene Fluoroionophores  

Jeon Young-Min (Department of Chemistry and Institute of Basic Science, Dankook University)
Kim Jong-Gyu (Department of Chemistry and Institute of Basic Science, Dankook University)
Jang Ji-Geun (Department of Electronic Engineering, Dankook University)
Chang Ho-Jung (Department of Electronic Engineering, Dankook University)
Kim Yung-Sup (Department of Electronic Engineering, Dankook University)
Gong Myoung-Seon (Department of Chemistry and Institute of Basic Science, Dankook University)
Publication Information
Polymer(Korea) / v.30, no.5, 2006 , pp. 426-431 More about this Journal
Abstract
Novel azacrown ether containing blue -light emitting anthracene fluorophore, 9,10-bis [p-(1-aza-18-crown-6)methylphenyl] anthracene (3) and N,N-bis [9-(p-methylphenyl) anthracenyl-methyl] -1,6-diaza-18-crown-6 (4) were prepared by reacting anthracene derivatives 1 and 2 with mono- and diaza-18-crown-6, respectively Also, crown ether containing fluorophore copolymer (5) were prepared by reacting 1,6-diaza-18-crown-6 with 1. Their fluorescence emission spectral studies were investigated by binding group I, group II and various metal cations. The fluorophores showed an absorption at ${\lambda}_{max}$= 372 nm and an emission at ${\lambda}_{max}$= 430 nm. pH Dependency of fluorescence emission intensity were examined to determine the optimum pH for the fluorophores.
Keywords
azacrown ether; anthracene fluorophore; fluoroionophore; photoinduced transfer;
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