Browse > Article

Synthesis and Luminescent Characteristics of Anthracene Fluoroionophores  

Jeon Young-Min (Department of Chemistry and Institute of Basic Science, Dankook University)
Kim Jong-Gyu (Department of Chemistry and Institute of Basic Science, Dankook University)
Jang Ji-Geun (Department of Electronic Engineering, Dankook University)
Chang Ho-Jung (Department of Electronic Engineering, Dankook University)
Kim Yung-Sup (Department of Electronic Engineering, Dankook University)
Gong Myoung-Seon (Department of Chemistry and Institute of Basic Science, Dankook University)
Publication Information
Polymer(Korea) / v.30, no.5, 2006 , pp. 426-431 More about this Journal
Abstract
Novel azacrown ether containing blue -light emitting anthracene fluorophore, 9,10-bis [p-(1-aza-18-crown-6)methylphenyl] anthracene (3) and N,N-bis [9-(p-methylphenyl) anthracenyl-methyl] -1,6-diaza-18-crown-6 (4) were prepared by reacting anthracene derivatives 1 and 2 with mono- and diaza-18-crown-6, respectively Also, crown ether containing fluorophore copolymer (5) were prepared by reacting 1,6-diaza-18-crown-6 with 1. Their fluorescence emission spectral studies were investigated by binding group I, group II and various metal cations. The fluorophores showed an absorption at ${\lambda}_{max}$= 372 nm and an emission at ${\lambda}_{max}$= 430 nm. pH Dependency of fluorescence emission intensity were examined to determine the optimum pH for the fluorophores.
Keywords
azacrown ether; anthracene fluorophore; fluoroionophore; photoinduced transfer;
Citations & Related Records

Times Cited By Web Of Science : 3  (Related Records In Web of Science)
Times Cited By SCOPUS : 3
연도 인용수 순위
1 R. T. Bronson, J. S. Bradshaw, P. B. Savage, S. Fuangswasdi, S. C. Lee, K. E. Krakowiak, and R. M. Izatt, J. Org. Chem., 66. 4752 (2001)   DOI   ScienceOn
2 C. D. Gutsche and R. Muthukrishnan, J. Org. Chem., 43, 4905 (1978)   DOI
3 R. Ungaro, and A. Pochini, in Frontier in Supra molecular Organic Chemistry and Photochemistry, H. J. Schneider, Editor, VCH, Weinheim, Germany, pp 57-81 (1991)
4 H. -F. Ji, G. M. Brown, and R. Dabestani, J. Am. Chem. Soc., 122, 9306 (2000)   DOI   ScienceOn
5 B. R. Pandya and Y. K. Agrawal, Dye and Pigments, 52, 161 (2002)   DOI   ScienceOn
6 H. -F. Ji, G. M. Brown, and R. Dabestani, Chem. Commun., 609 (1999)
7 U. Oguz, and E. U. Akkaya, Tetrahedron, 39, 5857 (1998)   DOI
8 C. T. Chen and W. P. Huang, J. Am. Chem. Soc., 124, 6246 (2002)
9 H. -F. Ji, G. M. Brown, R. Dabestani, and R. L. Hettich, J. Chem. Soc., Perkins Tretis., 2, 585 (2001)
10 N. Miyaura, K. Yamada, H. Suginoma, and A. Suzuki, J. Am. Chem. Soc., 107, 972 (1985)   DOI   ScienceOn
11 A. J. Pearson, J. J. Hwang, and M. E. Ignatov, Tetrahedron, 42, 3537 (2001)   DOI   ScienceOn
12 G. W. Gokel and B. J. Garcia, Tetrahedron, 4, 317 (1977)
13 Y. Nakamura, Y. Matsumi, W. Zhang, T. Kida, Y. Nakatsumi, and I. Lkeda, Org. Lett., 4, 2641 (2002)   DOI   ScienceOn
14 A. Shahrisa and A. Banaei, Molecules, 6, 721 (2001)   DOI
15 P. Kele, J. Orbulescu, T. L. Calhoun, R. E. Gawley, and R. L. Leblanc, Tetrahedron, 43, 4413 (2002)   DOI
16 J. S. Yang, C. S. Lin, and C. Y. Hwang, Org. Lett., 3, 889 (2001)   DOI   ScienceOn
17 H. Kawai, T. Nagarnura, T. Mori, and K. Yoshida, J. Phys. Chem. A. 6, 660 (1999)
18 N. Miyaura, T. Yanagi, and A. Suzuki, Synth. Commun., 11, 513 (1981)   DOI
19 C. J. Pedersen, J. Am. Chem. Soc., 92, 391 (1970)   DOI
20 C. Hamamcl, H. Hosgoren, and S. Erdogan, Talanta, 47, 229 (1988)   DOI   ScienceOn
21 G. Xue, J. S. Bradshaw, N. K. Dalley, P. B. Savage, R. M. Izatt, L. Prodi, M. Montalti, and N. Zaccheroni, Tetrahedron, 58, 4809 (2002)   DOI   ScienceOn
22 X. Jia, W. Zhu, Y. Zhang, and X. Yan, J. Mol. Struct., 604, 159 (2002)   DOI
23 B. Valeur and I. Leray, Coor. Chem. Rev., 205, 3 (2000)   DOI   ScienceOn
24 W. S. Xia, R. H. Schmehl, and C. J. Li, Tetrahedron, 56, 7045 (2000)   DOI   ScienceOn
25 P. Huszthy, Z. Kontos, B. Vermes, and A. Pinter, Tetrahedron, 57, 4967 (2001)   DOI   ScienceOn
26 R. Bergonzi, L. Fabbrizzi, M. Licchelli, and C. Mangano, Coor. Chem. Rev., 170, 31 (1998)   DOI   ScienceOn
27 F. Z. Badaoui and J. Bourson, Anal. Chim. Acta, 302, 341 (1995)   DOI
28 C. D. Gutsche, Calixarenes, Monograph in Supra molecular Chemistry, J. F. Stoddart, Editor, Royal Society of Chemistry, Cambridge, U. K., Vol. 1 (1989)
29 J. H. Chang, Y. M. Choi, and Y. K. Shin, Bull. Korean Chem. Soc., 22, 527 (2001)
30 M. T. Alonso, E. Brunet, O. Juanes, and J. C. RodriguezUbis, J. Photochem. & Photobiol. A: Chemistry, 147, 113 (2002)   DOI   ScienceOn