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Preparation of Poly-DCPD/Silicate Nanocomposites and Their Physical and Mechanical Properties  

Hong Chae-Hwan (Hyundai-Kia Motors Co., Ltd.)
Song Suk-Woo (Department of Chemical Engineering, Korea University of Technology and Education)
Nam Byeong-Uk (Department of Chemical Engineering, Korea University of Technology and Education)
Cha Bong-Jun (Dept. of Environmental Eng. and Biotechnology, Myongji University)
Kim Baek-Jin (Korea Institute of Industrial Technology)
Publication Information
Polymer(Korea) / v.30, no.4, 2006 , pp. 311-317 More about this Journal
Abstract
Poly-DCPD and poly-DCPD/silicates hybrids were prepared by in-situ ROMP poly-merization using $WCl_6$ catalyst. Good dispersion of silicates in DCPD medium can be accomplished by sonication method. Compared with nanocomposites prepared using $Na^+MMT$, the nanocomposites with CL 15A showed well dispersed silicate's morphology. superior thermal and mechanical properties. Additionally, well dispersed silicates in DCPD matrix enhanced the gas barrier property of the nanocomposites.
Keywords
DCPD; ROMP; $WCl_6$; $Et_2AlCl$; silicate hybrid;
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1 G. Galgali, C. Ramesh, and A. Lele, Macromolecules, 34, 852 (2001)   DOI   ScienceOn
2 S. Hayano, H. Kurakata, Y. Tsunogae, Y. Nakayama, Y. Sato, and H. Yasuda, Macromolecules, 36, 7422 (2003)   DOI   ScienceOn
3 J. H. Oskam and R. R. Schrock, J. Am. Chem. Soc., 115, 11813 (1993)
4 Y. Chekanov and A. J. Pojman, Macromolecules, 34, 6539 (2000)   DOI   ScienceOn
5 J. H. Oskam, H. H. Fox, K. B. Yap, D. H. McConville, R. O'Dell, B. J. Lichtenstein, and R. R. Schrock, J. Oganomet. Chem 459, 185 (1993)   DOI
6 P. J. Hine, T. Leejarkpai, E. Khosravi, R. A. Duckett, and W. J. Feast, Polymer, 42, 9413 (2001)   DOI   ScienceOn
7 R. Michael, Chem. Rev., 100, 1565 (2000)   DOI   ScienceOn
8 M. J. Abadie, M. Dimonie, C. Couve, and V. Dragutan, Eum. Polym. J., 36, 1213 (2000)   DOI   ScienceOn
9 A. Della Martina, J. G. Hirborn, and A. Muhlebach, Macromolecules, 33, 2916 (2000)   DOI   ScienceOn
10 Y. Mitra, T. Hossein, L. K. William, and U. P. Charles, Macromolecules, 37, 2511 (2004)   DOI   ScienceOn
11 H. Cho, Polymer Science and Technology, 5, 227 (1994)
12 H. Cho, Polymer Science and Technology, 12, 351 (2001)
13 P. Schwab, R. H. Grubbs, and J. W. Ziller, J. Am. Chem. Soc., 118, 100 (1996)   DOI   ScienceOn
14 N. Hasegawa and A. Usuki, J. Appl. Polym. Sci, 93, 464 (2004)   DOI   ScienceOn
15 G. C. Bazan, J. H. Oskam, H. N. Cho, L. Y. Park, and R. R. Schrock, J. Am. Chem. Soc., 113, 6899 (1991)   DOI
16 J. Li, C. Zhou, G. Wang, and D. Zhao, J. Appl. Polym. Sci, 89, 3690 (2003)
17 K. Ivin and J. Mol, Olefin metathesis and metathesis polymerization, London, Academic Press, 1997
18 C. Hong, Y. Lee, J. Bae, J. Jho, B. Nam, G. Nam, and K. Lee, J. Appl. Polym. Sci., 97, 2375 (2005)   DOI   ScienceOn
19 P. Schwab, M. B. France, J. W. Ziller, and R. H. Grubbs, Angew. Chem., 34, 2039 (1996)
20 S. T. Nguyen and R. H. Grubbs, J. Am. Chem. Soc., 115, 9858 (1993)   DOI   ScienceOn