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http://dx.doi.org/10.4313/TEEM.2017.18.6.334

Physical Properties of PNN-PMN-PZT Doped with Zinc Oxide and CLBO for Ultrasonic Transducer  

Yoo, Juhyun (Department of Electrical Engineering, Semyung University)
Kim, Tahee (Department of Electrical Engineering, Semyung University)
Lee, Eunsup (Ulsso Hitech Co. Ltd.)
Choi, Nak-Gu (Hitomoroo)
Jeong, Hoy-Seung (Chungbuk Health & Science University)
Publication Information
Transactions on Electrical and Electronic Materials / v.18, no.6, 2017 , pp. 334-337 More about this Journal
Abstract
In this paper, to develop the ceramics with high $d_{33}$ and high $Q_m$ for ultrasonic transducer applications, $0.10Pb(Ni_{1/3}Nb_{2/3})O_3-0.07Pb(Mn_{1/3}Nb_{2/3})O_3-0.83Pb(Zr_{0.5}Ti_{0.5})_{0.83}O_3$ (PNN-PMN-PZT) ceramics were sintered at $940^{\circ}C$ using $CuO-Li_2CO_3-Bi_2O_3$ (CLBO) as a sintering aid by a traditional solid-state technique. The influence of zinc oxide additive on the physical properties of the prepared ceramics were systematically investigated. The R-T (rhombohedral-tetragonal) phase coexistence was found in the ceramics without zinc oxide additive and with increasing amounts of ZnO additive, the specimens showed a tetragonal phase. The formation of a liquid phase between ZnO and $Bi_2O_3$ contributed significantly to the grain growth of specimens. For the 0.1 wt% ZnO ceramics, the optimal physical properties of $d_{33}=370pC/N$, ${\varepsilon}_r=1,344$, $k_p=0.621$, and $Q_m=1,523$ were obtained.
Keywords
Ultrasonic transducer; Sintering aids; Piezoelectric constant ($d_{33}$); Mmechanical quality factor ($Q_m$);
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