Browse > Article
http://dx.doi.org/10.4313/TEEM.2013.14.3.125

Electrochemical Oxidations of Alcohols on Platinum/Carbon Nanotube Composites  

Kim, Jungsoo (Dongnam Regional Division, Korea Institute of Industrial Technology)
Nam, Dae-Geun (Dongnam Regional Division, Korea Institute of Industrial Technology)
Oh, Weontae (Department of Materials & Components Engineering, Dong-Eui University)
Publication Information
Transactions on Electrical and Electronic Materials / v.14, no.3, 2013 , pp. 125-129 More about this Journal
Abstract
Composites of platinum and multiwalled carbon nanotubes (MWNTs) were prepared in various reduction conditions and characterized using cyclic voltammetry. The MWNTs were functionalized with carboxylic acid and/or hydroxyl groups in acidic solutions prior to the formation of MWNT-Pt composites. Platinum nanoparticles were deposited onto the chemically-oxidized MWNTs in 1-propanol and 1,3-propanediol. The reduction of Pt precursors in other solutions could induce differences in their morphologies in composite thin films. The morphologies of MWNTs with Pt deposited were dependent on the reduction solutions, and the electrocatalytic activities on alcohols changed accordingly. The electrochemical activities of the as-prepared MWNT-Pt thin films on common alcohols such as methanol and ethanol were investigated.
Keywords
Multi-walled carbon nanotubes; Pt nanoparticles; Alcohols; Cyclic voltammetry;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 H. Hitmi, E. M. Belgsir, J. M. Leger, C. Lamy, and R. O. Lezna, Electrochim. Acta 39, 407 (1994) [DOI: 10.1016/0013-4686(94)80080-4].   DOI   ScienceOn
2 N. Fujiwara, K. A. Friedrich, and U. Stimming, J. Electroanal. Chem. 472, 120 (1999) [DOI: http://dx.doi.org/10.1016/S0022-0728(99)00282-X]   DOI   ScienceOn
3 M. Chatterjee, A. Chatterjee, S. Ghosh, and I. Basumallick, Electrochim. Acta 54, 7299 (2009) [DOI: http://dx.doi.org/10.1016/j.electacta.2009.07.054].   DOI   ScienceOn
4 C. A. Morris, M. L. Anderson, R. M. Stroud, C. I. Merzbacher, and D. R. Rolison, Science 284, 622 (1999) [DOI: http://dx.doi.org/10.1126/science.284.5414.622].   DOI   ScienceOn
5 Y. Y. Tong, C. Rice, A. Wieckowski, and E. Oldfield, J. Am. Chem. Soc. 122, 1123 (2000) [DOI: http://dx.doi.org/10.1021/ja9922274].   DOI   ScienceOn
6 P. Serp, M. Corrias, and P. Kalck, Appl. Catal. A: Gen. 253, 337 (2003) [DOI: http://dx.doi.org/10.1016/S0926-860X(03)00549-0].   DOI   ScienceOn
7 H. T. Gomes, P. V. Samant, P. Serp, P. Kalck, J. L. Figueiredo, and J. L. Faria, Appl. Catal. B: Environ. 54, 175 (2004) [DOI: http://dx.doi.org/10.1016/j.apcatb.2004.06.009].   DOI   ScienceOn
8 J. Garcia, H. T. Gomes, P. Serp, P. Kalck, J. L. Figueiredo, and J. L. Faria, Catal. Today 102-103, 101 (2005) [DOI: http://dx.doi.org/10.1016/j.cattod.2005.02.013].   DOI   ScienceOn
9 H. Vu, F. Goncalves, R. Philippe, E. Lamouroux, M. Corrias, Y. Kiln, D. Plee, P. Kalck, and P. Serp, J. Catal. 240, 18 (2006) [DOI:http://dx.doi.org/10.1016/j.jcat.2006.03.003].   DOI   ScienceOn
10 D. Menard, X. Py, and N. Mazet, Chem. Eng. Process. 46, 565 (2007) [DOI: http://dx.doi.org/10.1016/j.cep.2006.07.013].   DOI   ScienceOn
11 Z. Qi, M.C. Lefebvre, and P. G. Pickup, J. Electroanal. Chem. 459, 9 (1998) [DOI: http://dx.doi.org/10.1016/S0022-0728(98)00241-1].   DOI   ScienceOn
12 S. D. Tompson, L. R. Jordan, and M. Forsyth, Electrochim. Acta 46, 1657 (2001) [DOI: http://dx.doi.org/10.1016/S0013-4686(00)00767-2].   DOI   ScienceOn
13 Z. Liu, X. Lin, J. Y. Lee, W. Zhang, M. Han, and L. M. Gan, Langmuir 18, 4054 (2002) [DOI: http://dx.doi.org/10.1021/la0116903].   DOI   ScienceOn
14 C. Wang, M. Waje, X. Wang, J. M. Tang, R. C. Haddon, and Y. Yan, Nano Lett. 4, 345 (2004) [DOI: http://dx.doi.org/10.1021/nl034952p].   DOI   ScienceOn
15 M. Koo, J.-S. Bae, H.-C. Kim, D.-G. Nam, C. H. Ko, J.H. Yeum, and W. Oh, Bull. Mater. Sci. 35, 545 (2012) [DOI: http://dx.doi.org/10.1007/s12034-012-0335-1].   DOI   ScienceOn
16 V. Selvaraj, M. Vinoba, and M. Alagar, J. Colloid Interf. Sci. 322, 537 (2008) [DOI: http://dx.doi.org/10.1016/j.jcis.2008.02.069].   DOI   ScienceOn
17 G. -W. Lee, J. Kim, J. Yoon, J. -S. Bae, B. C. Shin, I.S. Kim, W. Oh, and M. Ree, Thin Solid Films 516, 5781 (2008) [DOI: http://dx.doi.org/10.1016/j.tsf.2007.10.071].   DOI   ScienceOn
18 Y.-P. Sun, K. Fu, Y. Lin, and W. Huang, Acc. Chem. Res. 35, 1096 (2002) [DOI: http://dx.doi.org/10.1021/ar010160v].   DOI   ScienceOn
19 S. Niyogi, M. A. Hamon, H. Hu, B. Zhao, P. Bhowmik, R. Sen, M. E. Itkis, and R. C. Haddon, Acc. Chem. Res. 35, 1105 (2002) [DOI:http://dx.doi.org/10.1021/ar010155r].   DOI   ScienceOn
20 A. Hirsch, Angew. Chem. Int. Ed. 41, 1853 (2002) [DOI: http://dx.doi.org/10.1002/1521-377(2002060341:11<1853::AIDANIE1853>3.0.CO;2-N].   DOI   ScienceOn
21 D. Tasis, N. Tagmatarchis, V. Georgakilas, and M. Prato, Chem. Eur. J. 9, 4000 (2003) [DOI: http://dx.doi.org/10.1002/chem.200304800].   DOI   ScienceOn
22 G. Gao, G. Yang, M. Xu, C. Wang, C. Xu, and H. Li, J. Power Sources 173, 178 (2007) [DOI: http://dx.doi.org/10.1016/j.jpowsour.2007.06.160]   DOI   ScienceOn
23 K. Y. Chan, J. Ding, J. W. Ren, S .A. Cheng, and K. Y. Tsang, J. Mater. Chem. 14, 505 (2008) [DOI: http://dx.doi.org/10.1039/B314224H].   DOI   ScienceOn
24 S. Mukerjee, S. Srinivasan, M. Soriaga, and P. McBreen, J. Electrochem. Soc. 142, 1409 (1995) [DOI: http://dx.doi.org/10.1149/1.2049993].   DOI
25 S. Mukerjee, and S. Srinivasan, J. Electroanal. Chem. 357, 201 (1993) [DOI: http://dx.doi.org/10.1016/0022-0728(93)80380-Z].   DOI   ScienceOn
26 G. A. Capuano, and G. Thamizhmani, J. Electrochem. Soc. 141, 968 (1994) [DOI: http://dx.doi.org/10.1149/1.2054866].   DOI
27 R. Parsons, and T. VandefNoot, J. Electroanal. Chem. 257, 9 (1988) [DOI: http://dx.doi.org/10.1016/0022-0728(88)87028-1].   DOI   ScienceOn
28 X. Xia, T. Iwasita, F. Fe, and W. Vielstich, Electrochim. Acta 41, 711 (1996) [DOI: http://dx.doi.org/10.1016/0013-4686(95)00360-6].   DOI   ScienceOn
29 Z. Liu, X.Y. Ling, X. Su, J.Y. Lee, and L.M. Gan, J. Power Sources 149, 1 (2005) [DOI: http://dx.doi.org/10.1016/j.jpowsour.2005.02.009].   DOI   ScienceOn
30 K. H. An, W. S. Kim, Y. S. Park, J. M. Moon, D. J. Bae, S. C. Lim, Y. S. Lee, and Y. H. Lee, Adv. Funct. Mater. 11, 387 (2001) [DOI: http://dx.doi.org/10.1002/1616-3028(200110)11:5<387::AIDADFM387>3.0.CO;2-G].   DOI   ScienceOn
31 L. M. Ang, T. S. A. Hor, G. Q. Xu, C. H. Tung, S. P. Zhao, and J. L. S. Wang, Carbon 38, 363 (2000) [DOI: http://dx.doi.org/10.1016/S0008-6223(99)00112-8].   DOI   ScienceOn
32 X. H. Chen, J. T. Xia, J. C. Peng, W. Z. Li, and S. S. Xie, Compos. Sci. Technol. 60, 301 (2000) [DOI: http://dx.doi.org/10.1016/S0266-3538(99)00127-X].   DOI   ScienceOn
33 F. Z. Kong, X. B. Zhang, W. Q. Xiong, E. Liu, W. Z. Huang, Y. L. Sun, J. P. Tu, and X. W. Chen, Surf. Coating Technol. 155, 33 (2002) [DOI: http://dx.doi.org/10.1016/S0257-8972(02)00032-4].   DOI   ScienceOn
34 Z. He, J. Chen, D. Liu, H. Zhou, and Y. Kuang, Diamond Relat. Mater. 13, 1764 (2004) [DOI: http://dx.doi.org/10.1016/j.diamond.2004.03.004].   DOI   ScienceOn
35 B. Yoon, and C. M. Wai, J. Am. Chem. Soc. 127, 17174 (2005) [DOI: http://dx.doi.org/10.1021/ja055530f].   DOI   ScienceOn
36 X. Hu, T. Wang, X. Qu, and S. Dong, J. Phys. Chem. B 110, 853 (2006) [DOI: http://dx.doi.org/10.1021/jp055834o].   DOI   ScienceOn
37 G. G. Wildgoose, C. E. Banks, and R. G. Compton, Small 2, 182 (2006) [DOI: http://dx.doi.org/10.1002/smll.200500324].   DOI   ScienceOn
38 G. Wu, Y. S. Chen, and B. Q. Xu, Electrochem. Commun. 7, 1237 (2005) [DOI: http://dx.doi.org/10.1016/j.elecom.2005.07.015].   DOI   ScienceOn
39 H. K. Kim, and R. Y. Lee, Kor. J. Mater. Res. 19, 192 (2009) [DOI:http://dx.doi.org/10.3740/MRSK.2009.19.4.192].   DOI   ScienceOn