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http://dx.doi.org/10.4313/TEEM.2005.6.4.144

Influence of Dysprosia Addition on Microstructure and Electrical Properties of Praseodymia-based Zinc Oxide Varistors  

Nahm, Choon-Woo (Department of Electrical Engineering, Dongeui University)
Publication Information
Transactions on Electrical and Electronic Materials / v.6, no.4, 2005 , pp. 144-148 More about this Journal
Abstract
The microstructure and electrical properties of varistor ceramics, which are composed of Zn-Pr­Co-Cr-Dy-oxide system, were investigated at various dysprosia $(Dy_2O_3)$ addition contents. The $DY_2O_3$ microstructurally played the role of inhibition for the densification and grain growth. As the $DY_2O_3$ content increased, the density decreased in the range of $5.51-4.90 g/cm^3$, reaching maximum at $0.5 mol\%$ and the average ZnO grain size decreased in the range of $17.7-6.0{\mu}m$. The incorporation of $DY_2O_3$ significantly improved the nonlinear properties of varistors, above 30 in nonlinear exponent, compared with that without $DY_2O_3$. The varistors with the best performance of nonlinear properties was obtained $DY_2O_3$ content of $1.0 mol\%$, 49 in nonlinear exponent and $0.5{\mu}A$ in leakage current.
Keywords
Microstructure; Electrical properties; Varistors;
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1 L. M. Levinson and H. R. Philipp, 'Zinc oxide varistor-a review', Amer. Ceram. Soc. Bull., Vol. 65, No.4, p. 639, 1986
2 T. K. Gupta, 'Application of zinc oxide varistor', J. Amer. Ceram. Soc., Vol. 73, No.7, p. 1817, 1990
3 Y. S. Lee and T. Y. Tseng, 'Phase identification and electrical properties in ZnO-glass varistors', J. Amer. Ceram. Soc., Vol. 75, No.6, p. 1636, 1992
4 A. B. Alles and V. L. Burdick, ''The effect ofliquidphase sintering on the properties of $Pr_6O_{11}$-based ZnO varistors', J. Appl. Phys., Vol. 70, No. 11, p. 6883, 1991
5 Y.- S. Lee, K.-S. Liao, and T.- Y. Tseng, 'Microstructure and crystal phases of praseodymium in zinc oxides varistor ceramics', J. Amer. Ceram. Soc., Vol. 79, No.9, p. 2379, 1996
6 C.-W. Nahm, 'The nonlinear properties and stability of ZnO-$Pr_O_{11}-CoO-Cr_2O_3-Er_2O_3$ ceramic varistors', Mater. Lett., Vol. 47; No.4, 3, p. 182, 2001   DOI   ScienceOn
7 C.-W. Nahm and J.-S. Ryu, 'Influence of sintering temperature on varistor characteristics of ZPCCEbased ceramics', Mater. Lett., Vol. 53, No. 1-2, p. 110, 2002   DOI   ScienceOn
8 C.-W. Nahm and B.-C. Shin, 'Effect of sintering temperature on electrical properties and stability of Pr60u-based ZnO varistors', J. Mater. Sci: Mater. Electron., Vol. 12, No.2, p. 111, 2002
9 C.-W. Nahm, 'Microstructure and electrical properties of $Y_2O_3$ doped ZnO-$Pr_6O_{11}$-based varistor', Mater. Lett., Vol. 57, No.7, p. 1317, 2003
10 C.-W. Nahm and B.-C. Shin, 'Highly stable electrical properties of ZnO-$Pr_6O_{11}-CoO-Cr_2O_3Y_2O_3$-based varistor cearmics', Mater. Lett., Vol. 57, No. 7, p. 1322, 2003
11 L. Hozer, 'Semiconductor Ceramics: Grain Boundary Effects', Ellis Horwood, p. 22, 1994
12 J. C. Wurst and J. A. Nelson, 'Lineal intercept technique for measuring grain size in two-phase polycrystalline ceramics', J. Amer. Ceram. Soc., Vol. 55, No. 97-12, p. 109, 1972   DOI
13 M. Mukae, K. Tsuda, and I. Nagasawa, 'Capacitance-vs-voltage characteristics of ZnO varistor', J. Appl. Phys., Vol. 50, No.6, p. 4475, 1979
14 C.-W. Nahm, C.-H. Park, and H.-S.Yoon, 'Microstructure and varistor properties of ZnO-$Pr_6O_{11}-CoO-Nd_2O_3$ based ceramics', J. Mater. Sci. Lett., Vol. 19, No.4, p. 271, 2000
15 C.-W. Nahm, 'The electrical properties and d.c. degradation characteristics of $Dy_2O_3$-doped $Pr_6O_{11}$ based ZnO varistors', J. Euro. Ceram. Soc., Vol. 21, No.4, p. 545, 2001
16 C.-W. Nahm and C.-H. Park, 'Effect of $Er_2O_3$ addition on the microstructure, electrical properties, and stability of $Pr_O_{11}$-based ZnO ceramic varistors', J. Mater. Sci., Vol. 36, No.7, p. 1671, 2001