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Preparation of Amine-Containing Poly(amide-sulfone)s Using Vinylsulfone Reactive Monomers and Their Properties  

Jeon, Young-Min (Department of Chemistry and Institute of Basic Science, Dankook University)
Lim, Tai-Ho (Department of Chemistry and Institute of Basic Science, Dankook University)
Kim, Soo-Han (Department of Chemistry and Institute of Basic Science, Dankook University)
Kim, Jong-Gyu (Department of Chemistry and Institute of Basic Science, Dankook University)
Gong, Myoung-Seon (Department of Chemistry and Institute of Basic Science, Dankook University)
Publication Information
Macromolecular Research / v.15, no.1, 2007 , pp. 17-21 More about this Journal
Abstract
A series of new, vinyl sulfone-containing monomers was prepared by p-aminophenyl vinyl sulfone (1) with various acid chlorides such as adipoly chloride, terephthaloyl chloride and isophthaloyl chloride. Finally, tertiary amine-containing poly(amide-sulfone)s were prepared by the Michael-type addition polymerization using N,N-dimethylethylenediamine (DMEDA), p-phenylenediamine and piperazin. To evaluate the relevant properties for permselective membranes and enzyme substrate, various physical properties such as molecular weight, solubility, quaternization behavior and thermal properties were examined.
Keywords
poly(amide-sulfone)s; vinyl sulfone; Michael addition; tertiary amine;
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