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The First Synthesis of a Transition Metal-Catalyzed Homopolymer Having Pendent t-Boc-Protected Quinizarin for Patterned Fluorescence Images  

Jimmy Yoo (Department of Chemistry, Korea Advanced Institute of Science and Technology)
Lee, Jae-Hyoung (Department of Advanced Materials Engineering, Korea Institute of Science and Technology)
Iwhan Cho (Department of Advanced Materials Engineering, Korea Institute of Science and Technology)
Ahn, Kwang-Duk (Functional Polymer Laboratory, Korea Institute of Science and Technology)
Kim, Jong-Man (Department of Chemical Engineering, Hanyang University)
Publication Information
Macromolecular Research / v.11, no.1, 2003 , pp. 69-72 More about this Journal
Abstract
A homopolymer having pendent t-Boc-protected quinizarin moieties has been prepared for patterned fluorescence images. The homopolymer P(t-BQN (2-norbornenylmethyl di-tert-butoxycarbonylquinizarin)) 5 was prepared by palladium-catalyzed addition polymerization. The t-Boc-protecting groups of the polymer were efficiently removed during chemical amplification process and revealed original properties of quinizarin, allowing patterned fluorescence images in the polymer film.
Keywords
patterned fluorescence image; homopolymer; chemical amplification; addition polymerization;
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