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http://dx.doi.org/10.5478/MSL.2012.3.2.43

Application of Comprehensive 2D GC-MS and APPI FT-ICR MS for More Complete Understanding of Chemicals in Diesel Fuel  

Cho, Yun-Ju (Kyungpook National University, Department of Chemistry)
Islam, Annana (Kyungpook National University, Department of Chemistry)
Ahmed, Arif (Kyungpook National University, Department of Chemistry)
Kim, Sung-Hwan (Kyungpook National University, Department of Chemistry)
Publication Information
Mass Spectrometry Letters / v.3, no.2, 2012 , pp. 43-46 More about this Journal
Abstract
In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotron resonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have been combined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturated cyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with more than two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings were identified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compounds were observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICR MS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each other for more complete understanding of oil samples.
Keywords
2D GC-MS; High resolution mass spectrometry; FT-ICR MS; Oil;
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