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http://dx.doi.org/10.4283/JMAG.2009.14.1.001

Magnetic Property of BixCa1-xMnO3: Experimental and First Principles Calculation Study  

Na, Sung-Ho (Department of Physics/RCDAMP, Pusan National University)
Kim, Dong-Jin (Department of Physics/RCDAMP, Pusan National University)
Publication Information
Abstract
The magnetic properties of ${Bi_x}{Ca_{1-x}}{MnO_3}$ for x = 0.12, 0.13, 0.14, 0.15, and 0.16 were examined by measuring magnetic susceptibility, resistivity and electron magnetic resonance at different temperatures. ${Bi_x}{Ca_{1-x}}{MnO_3}$ showed complicated magnetic structure that varies with temperature and composition, particularly around Bi composition x. 0.15. The aim of this study was to determine how the magnetic and physical properties of ${Bi_x}{Ca_{1-x}}{MnO_3}$ change in this region. In addition, first principles calculations of the magnetic phase of ${Bi_x}{Ca_{1-x}}{MnO_3}$ for x = 0, 0.125, 0.25 were carried out, and the spin state, electric and magnetic characteristics are discussed.
Keywords
${Bi_x}{Ca_{1-x}}{MnO_3}$; susceptibility; density functional theory; electron magnetic resonance; resistivity;
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