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http://dx.doi.org/10.5229/JECST.2018.9.1.69

Effect of [Al(DMSO2)3]3+ Concentration on Al Electrodeposition from AlCl3/Dimethylsulfone Baths  

Kim, Sangjae (Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University)
Matsunaga, Naoya (Department of Materials Science & Engineering, Graduate School of Engineering, Nagoya University)
Kuroda, Kensuke (Institute of Materials and Systems for Sustainability, IMaSS, Nagoya University)
Okido, Masazumi (Institute of Materials and Systems for Sustainability, IMaSS, Nagoya University)
Publication Information
Journal of Electrochemical Science and Technology / v.9, no.1, 2018 , pp. 69-77 More about this Journal
Abstract
Aluminum electrodeposition was carried out in dimethylsulfone ($DMSO_2$) baths containing 6.2-28.3 mol% $AlCl_3$ at 403 K. The electrochemically active species for Al electrodeposition in $DMSO_2$ baths were investigated. Electrochemical behavior of the electrolyte and the deposition mechanism were studied via cyclic voltammetry (CV). Properties of the deposits were assessed by scanning electron microscopy with energy-dispersive X-ray spectroscopy and X-ray diffraction. In addition, structures of the ionic complexes formed with aluminum in the bath were characterized by $^{27}Al$ nuclear magnetic resonance (NMR) spectroscopy. NMR spectra revealed that all baths contained two ionic species: $AlCl_4{^-}$ and $[Al(DMSO_2)_3]^{3+}$. Al electrodeposited when the $[Al(DMSO_2)_3]^{3+}$ concentration was the highest (23.3 mol% $AlCl_3$) exhibited fine grain sizes, relatively smooth surfaces, and high purities.
Keywords
Electrodeposition; Aluminum; Nuclear magnetic resonance; Dimethylsulfone;
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