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http://dx.doi.org/10.5229/JECST.2015.6.3.88

Physioelectrochemical Investigation of Electrocatalytic Oxidation of Saccharose on Conductive Polymer Modified Graphite Electrode  

Naeemy, A. (Departement of Chemistry, Faculty of Science, K. N. Toosi university of technology, Tehran, Iran)
Ehsani, A. (Departement of Chemistry, Faculty of Science, Qom university, Qom, Iran)
Jafarian, M. (Departement of Chemistry, Faculty of Science, K. N. Toosi university of technology, Tehran, Iran)
Moradi, M. (Departement of Chemistry, Faculty of Science, K. N. Toosi university of technology, Tehran, Iran)
Publication Information
Journal of Electrochemical Science and Technology / v.6, no.3, 2015 , pp. 88-94 More about this Journal
Abstract
In this study we investigated the electrocatalytic oxidation of saccharose on conductive polymer- Nickel oxide modified graphite electrodes based on the ability of anionic surfactants to form micelles in aqueous media. This NiO modified electrode showed higher electrocatalytic activity than Ni rode electrode in electrocatalytic oxidation of saccharose. The anodic peak currents show linear dependency with the square root of scan rate. This behavior is the characteristic of a diffusion controlled process. Under the CA regime the reaction followed a Cottrellian behavior and the diffusion coefficient of saccharose was found in agreement with the values obtained from CV measurements.
Keywords
Fuel cell; NiO; electrocatalyst; modified electrodes; conductive polymer;
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