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http://dx.doi.org/10.4491/eer.2010.15.3.129

Application of Taguchi Experimental Design for the Optimization of Effective Parameters on the Rapeseed Methyl Ester Production  

Kim, Sun-Tae (Department of Environmental Engineering, Daejeon University)
Yim, Bong-Been (R&D Center, Envors Co., Ltd.)
Park, Young-Taek (Department of Environmental Engineering, Daejeon University)
Publication Information
Environmental Engineering Research / v.15, no.3, 2010 , pp. 129-134 More about this Journal
Abstract
The optimization of experimental parameters, such as catalyst type, catalyst concentration, molar ratio of alcohol to oil and reaction temperature, on the transesterification for the production of rapeseed methyl ester has been studied. The Taguchi approach (Taguchi method) was adopted as the experimental design methodology, which was adequate for understanding the effects of the control parameters and to optimize the experimental conditions from a limited number of experiments. The optimal experimental conditions obtained from this study were potassium hydroxide as the catalyst, at a concentration of 1.5 wt %, and a reaction temperature of $60^{\circ}C$. According to Taguchi method, the catalyst concentration played the most important role in the yield of rapeseed methyl ester. Finally, the yield of rapeseed methyl ester was improved to 96.7% with the by optimal conditions of the control parameters which were obtained by Taguchi method.
Keywords
Biodiesel; Taguchi method; Rapeseed oil; Transesterification reaction; Basic catalyst;
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  • Reference
1 Freedman B, Pryde EH, Mounts TL. Variables affecting the yields of fatty esters from transesterified vegetable oils. J. Am. Oil Chem. Soc. 1984;61:1638-1643.   DOI
2 Freedman B, Butterfield RO, Pryde EH. Transesterification kinetics of soybean oil 1. J. Am. Oil Chem. Soc. 1986;63:1375-1380.   DOI
3 Mittelbach M, Trathnigg B. Kinetics of alkaline catalyzed methanolysis of sunflower oil. Fat Sci. Technol. 1990;92:145-148.
4 Roy RK. Design of experiments using the Taguchi approach: 16 steps to product and process improvement. New York: Wiley; 2001.
5 Canakci M, Van Gerpen J. Biodiesel production from oils and fats with high free fatty acids. Trans. ASAE 2001;44:1429-1436.
6 Vicente G, Martinez M, Aracil J. Integrated biodiesel production: A comparison of different homogeneous catalysts systems. Bioresour. Technol. 2004;92:297-305.   DOI   ScienceOn
7 Meher LC, Dharmagadda VSS, Naik SN. Optimization of alkali-catalyzed transesterification of Pongamia pinnata oil for production of biodiesel. Bioresour. Technol. 2006;97:1392-1397.   DOI   ScienceOn
8 Ma F, Hanna MA. Biodiesel production: A review. Bioresour. Technol. 1999;70:1-15.   DOI   ScienceOn
9 Pinto AC, Guarieiro LLN, Rezende MJC, et al. Biodiesel: An overview. J. Braz. Chem. Soc. 2005;16:1313-1330.   DOI   ScienceOn
10 Lang X, Dalai AK, Bakhshi NN, Reaney MJ, Hertz PB. Preparation and characterization of bio-diesels from various biooils. Bioresour. Technol. 2001;80:53-62.   DOI   ScienceOn
11 Foidl N, Foidl G, Sanchez M, Mittelbach M, Hackel S. Jatropha curcas L. as a source for the production of biofuel in Nicaragua. Bioresour. Technol. 1996;58:77-82.   DOI   ScienceOn
12 Karmee SK, Chadha A. Preparation of biodiesel from crude oil of Pongamia pinnata. Bioresour. Technol. 2005;96:1425-1429.   DOI   ScienceOn
13 Cvengros J, Povazanec F. Production and treatment of rapeseed oil methyl esters as alternative fuels for diesel engines. Bioresour. Technol. 1996;55:145-150.   DOI   ScienceOn
14 Meher LC, Vidya Sagar D, Naik SN. Technical aspects of biodiesel production by transesterification-A review. Renew. Sustain. Energ. Rev. 2006;10:248-268.   DOI   ScienceOn
15 Barnwal BK, Sharma MP. Prospects of biodiesel production from vegetable oils in India. Renew. Sustain. Energ. Rev. 2005;9:363-378.   DOI   ScienceOn
16 Canakci M, Van Gerpen J. Biodiesel production via acid catalysis. Trans. ASAE 1999;42:1203-1210.   DOI
17 Encinar JM, Gonzalez JF, Rodriguez JJ, Tejedor A. Biodiesel fuels from vegetable oils: Transesterification of Cynara cardunculus L. Oils with ethanol. Energy Fuels 2002;16:443-450.   DOI   ScienceOn