Browse > Article
http://dx.doi.org/10.1016/j.jiec.2018.07.042

Influence of ionic liquid structures on polyimide-based gel polymer electrolytes for high-safety lithium batteries  

Kim, Jae-Kwang (Department of Solar & Energy Engineering, Cheongju University)
Publication Information
Journal of Industrial and Engineering Chemistry / v.68, no., 2018 , pp. 168-172 More about this Journal
Abstract
This study first investigates the effect of the choice of cation on three different ionic-liquid-based gel polymer electrolytes (ILPEs) with polyimide membranes. The preparation of three ILPEs based on electrospun membranes of PI and incorporating a room-temperature ionic liquid, 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide complexed with lithium bis(trifluoromethylsulfonyl)imide, is described. ILPE-EMImTFSI has an ionic conductivity as high as $5.3{\times}10^{-3}S\;cm^{-1}$ at $30^{\circ}C$. Furthermore, it shows higher thermal stability and electrochemical oxidation stability compared to the other two ILPEs because of its stronger bonds. These results indicate that polyimide-based ILPE-EMImTFSI is a good candidate for use in high-safety rechargeable lithium metal batteries.
Keywords
Cation; Ionic liquid; Gel polymer electrolyte; Polyimide; Electrochemical property;
Citations & Related Records
연도 인용수 순위
  • Reference
1 C. Xu, B. Sun, T. Gustafsson, K. Edström, D. Brandell, M. Hahlin, J. Mater. Chem. A 2 (2014) 7256.   DOI
2 D.-J. You, Z. Yin, Y. Ahn, S. Cho, H. Kim, D. Shin, J. Yoo, Y.S. Kim, J. Ind. Eng. Chem. 52 (2017) 1.   DOI
3 J.H. Shin, W. Henderson, S. Passerini, Electrochem. Commun. 5 (2003) 1016.   DOI
4 M. Keller, A. Varzi, S. Passerini, J. Power Sources 392 (2018) 206.   DOI
5 J.H. Baik, D.G. Kim, J. Shim, J.H. Lee, Y.S. Choi, J.C. Lee, Polymer 99 (2016) 704.   DOI
6 K. Karuppasamy, D. Kim, Y.H. Kang, K. Prasanna, H.W. Rhee, J. Ind. Eng. Chem. 52 (2017) 224.   DOI
7 J.-H. Baik, D.-G. Kim, J.H. Lee, S. Kim, D.G. Hong, J.-C. Lee, J. Ind. Eng. Chem. 64 (2018) 453.   DOI
8 L.C. Rodrigues, P.C. Barbosa, M.M. Silva, M.J. Smith, Electrochim. Acta 53 (2007) 1427.   DOI
9 M. Wetjen, G.T. Kim, M. Joost, G.B. Appetecchi, M. Winter, S. Passerini, J. Power Sources 246 (2014) 846.   DOI
10 M. Galinski, A. Lewandowski, I. Stepniak, Electrochim. Acta 51 (2006) 5567.   DOI
11 J.K. Kim, G. Cheruvally, X. Li, J.H. Ahn, K.W. Kim, H.J. Ahn, J. Power Sources 178 (2008) 815.   DOI
12 H. Ye, J. Huang, J.J. Xu, A. Khalfan, S.G. Greenbaum, J. Electrochem. Soc. 154 (2007) A1048.   DOI
13 P. Yang, L. Liu, L. Li, J. Hou, Y. Xu, X. Ren, M. An, N. Li, Electrochim. Acta 115 (2014) 454.   DOI
14 J.K. Kim, J.H. Ahn, P. Jacobsson, Electrochim. Acta 116 (2014) 321.   DOI
15 X. Li, G. Cheruvally, J.K. Kim, J.W. Choi, J.H. Ahn, K.W. Kim, H.J. Ahn, J. Power Sources 167 (2007) 491.   DOI
16 J.-C. Lassegues, J. Grondin, C. Aupetit, P. Johansson, J. Phys. Chem. A 113 (2009) 305.   DOI
17 J.K. Kim, J.W. Choi, G. Cheruvally, J.U. Kim, J.H. Ahn, G.B. Cho, K.W. Kim, H.J. Ahn, Mater. Lett. 61 (2007) 3822.   DOI
18 X. Li, Z. Zhang, K. Yin, L. Yang, K. Tachibana, S. Hirano, J. Power Sources 278 (2015) 128.   DOI
19 I. Rey, P. Johansson, J. Lindgren, J.-C. Lassegues, J. Grondin, L. Servant, J. Phys. Chem. A 102 (1998) 3249.
20 J.K. Kim, A. Matic, J.H. Ahn, P. Jacobsson, J. Power Sources 195 (2010) 7639.   DOI
21 S. Duluard, J. Grondin, J.-L. Bruneel, I. Pianet, A. Grelard, G. Campet, M.-H. Delville, J.-C. Lassegues, J. Raman Spectrosc. 39 (2008) 627.   DOI
22 P.C. Howlett, E.I. Izgorodina, M. Forsyth, D.R. MacFarlane, Z. Phys. Chem. 220 (2006) 1483.   DOI
23 Y.-E. Miao, G.-N. Zhu, H. Hou, Y.-Y. Xia, T. Liu, J. Power Sources 226 (2013) 82.   DOI
24 L. Kong, Y. Yan, Z. Qiu, Z. Zhou, J. Hu, J. Membr. Sci. 549 (2018) 321.   DOI
25 J.K. Kim, J. Scheers, T.J. Park, Y. Kim, ChemSusChem 8 (2015) 636.   DOI
26 P. Raghavan, X. Zhao, H. Choi, D.H. Lim, J.K. Kim, A. Matic, P. Jacobsoon, C. Nah, J. H. Ahn, Solid State Ionics 262 (2014) 77.   DOI
27 G.G. Eshetu, M. Armand, B. Scrosati, S. Passerini, Angew. Chem. Int. Ed. 53 (2014) 13342.   DOI
28 J.K. Kim, L. Niedzicki, J. Scheers, C.R. Shin, D.H. Lim, W. Wieczorek, P. Johansson, J.H. Ahn, A. Matic, P. Jacobsson, J. Power Sources 224 (2013) 93.   DOI
29 M. Holzapfel, C. Jost, P. Novak, Chem. Commun. (2004) 2098.
30 M. Montanino, M. Moreno, M. Carewska, G. Maresca, E. Simonetti, R.L. Presti, F. Alessandrini, G.B. Appetecchi, J. Power Sources 269 (2014) 608.   DOI
31 H. Zheng, K. Jiang, T. Abe, Z. Ogumi, Carbon 44 (2006) 203.   DOI
32 K. Murata, S. Izuchi, Y. Yoshihisa, Electrochim. Acta 45 (2000) 1501.   DOI