[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.1016/j.jiec.2018.04.022

Performance of EMIMFSI ionic liquid based gel polymer electrolyte in rechargeable lithium metal batteries

Balo, Liton (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University)
Gupta, Himani (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University)
Singh, Shishir Kumar (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University)
Singh, Varun Kumar (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University)
Kataria, Shalu (Centre of Material Sciences, IIDS, University of Allahabad)
Singh, Rajendra Kumar (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University)

Publication Information

Journal of Industrial and Engineering Chemistry / v.65, no., 2018 , pp. 137-145 More about this Journal

Abstract

Flexible gel polymer electrolytes based on polymer polyethylene oxide, salt lithium bis(fluorosulfonyl) imide and ionic liquid 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide are synthesized. Prepared samples show high thermal stability, high ionic conductivity at room temperature and an electrochemical stability window of ~3.51V vs. $Li/Li^+$ . Lithium deposition-striping voltage profiles show the formation of a stable solid electrolyte interface. A $Li/GPE/LiFePO_4$ cell was assembled by low cost thermal lamination technique. This cell can deliver $143mAh\;g^{-1}$ capacity at room temperature at C/20 rate with good discharge efficiency. Use of micro grid mesh type Al current collector in cathode exhibits significant improvement in capacity retention.

Keywords

Lithium metal battery; Polymer electrolyte; Ionic liquid; Voltammetry; Capacity loss;

Citations & Related Records

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