[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.1016/j.jiec.2012.10.031

Preparation and characterization of PVC based heterogeneous ion exchange membrane coated with Ag nanoparticles by (thermal-plasma) treatment assisted surface modification

Hosseini, S.M. (Department of Chemical Engineering, Faculty of Engineering, Arak University)
Madaeni, S.S. (Membrane Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University)
Zendehnam, A. (Thin film laboratory, Department of physic, Faculty of Science, Arak University)
Moghadassi, A.R. (Department of Chemical Engineering, Faculty of Engineering, Arak University)
Khodabakhshi, A.R. (Department of chemistry, Faculty of Science, Arak University)
Sanaeepur, H. (Department of Chemical Engineering, Faculty of Engineering, Arak University)

Publication Information

Journal of Industrial and Engineering Chemistry / v.19, no.3, 2013 , pp. 854-862 More about this Journal

Abstract

PVC based heterogeneous cation exchange membranes were prepared by solution casting technique. Ag nanoparticles were also utilized as surface modifier by plasma treatment. Thermal treatment was used to improve the Ag nanoparticles stability on membrane surface. The effect of treating temperature on separation characteristics of coated membranes was studied. SEM images showed membrane rugosity increasing by the increase of treating temperature. Transport number, selectivity and permeability were enhanced initially by increase of treating temperature up to $80^{\circ}C$ and then showed decreasing trend. Conversely membrane resistance showed opposite trend. Modified membrane at $80^{\circ}C$ showed better performance compared to others.

Keywords

Thermal/Plasma treatment; Surface modification; Ag nanoparticles; Electrochemical characterization;

Citations & Related Records

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