Browse > Article

Photocatalytic Oxidation of Indoor Air Volatile Organic Compounds (VOCs) in pub Level  

Jo, Wan-Kuen (Department of Environmental Engineering, Kyungpook National University)
Kim, Dong-Hyun (Department of Chemical Engineering, Kyungpook National University)
Ki, Jae-Chang (Department of Chemical Engineering, Kyungpook National University)
Huh, Jeung-Soo (Department of Material Sciences and Metallurgy, Kyungpook Notional University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.19, no.E4, 2003 , pp. 157-168 More about this Journal
Abstract
This study evaluated the technical feasibility of the application of titanium oxide (TiO$_2$) photocatalysis for the removal of VOCs in low ppb concentrations commonly associated with non -occupational indoor air quality issues. A series of experiments were conducted to evaluate four parameters (relative humidity (RH), hydraulic diameter (HD), photocatalytic oxidation (PCO) reactor material (RM), and inlet port size (IPS) of PCO reactor) for the PCO destruction efficiencies of the selected target VOCs. None of the target VOCs presented significant dependency on the RH, which is inconsistent with a few previous studies. However, it is noted that the three parameters (HD, RM and IPS) should be considered for better VOCs removal efficiencies for the application of TiO$_2$ photocatalytic technology for cleansing non -occupational indoor air. The PCO destruction of VOCs at concentrations associated with non-occupational indoor air quality issues can be up to nearly 100%. The amount of CO generated during PCO would be negligible in comparison to the indoor CO levels. These results can make the PCO reactor an important tool in the effort to improve non-occupational indoor air quality.
Keywords
Indoor air; Parameter; Photocatalytic oxidation; Titanium oxide; VOCs;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Blanco, J., P. Avila, A. Bahamonde, E. Alvarez, B. Sanchez, and M. Romero (1996) Photocatalytic destruction of toluene and xylene at gas phase on a titania based monolithic catalyst. Catal. Today 29, 437-442
2 Fu, X., W.A. Zeltner, and M.A. Anderson (1995) The gas-phase photocatalytic mineralization of benzene on porous titania-based catalysts. Appl. Catal., B 6, 209-224
3 Heavner, D.L., W.T. Morgan, and M.W. Ogden (1995) Determination of volatile organic compounds and ETS apportionment in 49 homes. Environ. Int., 21, 3-21
4 Lee, B.Y., S.W. Kim, and S.J. Choung (2001) The study on preparation parameters of $TiO_2$ catalyst for photodecomposition of ethanol as a VOC. J. Kor. Soc. Atmos Environ., 17,363-370
5 Murabayashi, M., K. Itoh, J.S. Kim, E. Katori, K. Iguchi, K. Okamura, K. Kawashima, and R. Masuda (1994) Abstracts of Papers, The First International Conference on Advanced Oxidation technologies for Water and Air Remediation, London, Ontario, Canada; Elsevier: Amsterdam, June 25-30, pp. 335-336
6 Obee, T.N. (1996) Photooxidation of sub-parts-per-million toluene and formaldehyde levels on titania using a glass-plate reactor. Environ. Sci. Technol., 30, 3578-3584
7 Tancrede, M.R., W.L. Zeise, and E.A.C. Crouch (1987) The carcinogenic risk of some organic vapors indoors: a theoretical survey. Atmos. Environ., 21, 2187-2205
8 United States Environmental Protection Agency (USEPA) (1990) Cancer risk from outdoor exposure to airtoxics. PA-450/1-90-004a
9 Weedon, A.C. (1994) Abstracts of Papers, The First International Conference on Advanced Oxidation technologies for Water and Air Remediation, London, Ontario, Canada; Elsevier: Amsterdam; June 25-30, 127pp
10 Cho, I.C., J.H. Byun, E.S. Byun, D.G. Lee, and S.W. Kim (2001) Gas phase photocatalytic oxidation of PCE with $TiO_2$. J. Kor. Soc. Atmos. Environ., 17, 57-66
11 Damme, H. and W.K. Hall (1981) Photocatalytic properties of Perovskites for $H_2$ and CO oxidation-influence of ferroelectric properties. J. Catal., 69, 371-383
12 Ibusuki, T. and K. Takeuchi (1986) Toluene oxidation on UV-jrradiated titanium dioxide with and without $O_2$,$NO_2$ or $H_2O$ at ambient temperature. Atmos. Environ., 20, 1711-1715
13 IIgen, E., N. Karfich, K. Levsen, J. Angerer, P. Schneider, J. Heinrich, H. Wichmann, L. Dunemann, and J. Begerow (2001) Aromatic hydrocarbons in the atmospheric environment: Part I. Indoor versus outdoor sources, the influence of traffic. Atmos. Environ., 35, 1235-1252
14 Stevens, L., J.A. Lanning, L.G. Anderson, W.A. Jacoby, and N. Chornet (1998)Investigation of the photocatalytic oxidation of low-level carbonyl compounds. J. Air & Waste Manage. Assoc., 48, 979-984
15 Wallace, L.A., E.D. Pellizzari, T.D. Hartwell, V. Davis, L.C. Michael, and R.W. Whitmore (1989) The influence of personal activities on exposure to volatile organic compounds. Environ. Res. 50, 37-55
16 Wallace, L., W. Nelson, R. Ziegenfus, E. Pellizzari, L. Michael, R. Whitmore, H. Zelon,T. Hartwell, and R. Perritt (1991) The Los Angeles TEAM study: personal exposures, indoor-outdoor air concentrations, and breath concentrations of 25 volatile organic compounds. J. Expos. Anal. Environ. Epidemiol., 1, 157-192
17 Peral, J. and D.F. Ollis (1992) Heterogeneous photocatalytic oxidation of gas-phase organics for air purification,acetone, 1-butanol, butyraldehyde, formaldehyde and m-xylene oxidation. J. Catal., 136, 554-565
18 Jeong, C.H., J.N. Suh, S.T. Kim, and K.C. Choi (2000) A study on the photocatalytic oxidation of trichloroethylene in air. J. Kor. Soc. Atmos. Environ., 16, 521-528
19 Suzuki, K. (1993) Photocatalytic Purification and treatment of Water and Air, Ollis DF, AI-Ekabi H, Eds.; Elsevier: Amsterdam, pp. 421-434
20 Baek, S.O., Y.S. Kim, and R. Perry (1997) Indoor air quality in homes, offices and restaurants in Korean urban areas-indoor/outdoor relationships. Atmos. Environ. 31, 529-544
21 Kim, S.B., Y.M. Jo, and S.C. Hong (2001) A kinetic study on the photocatalytic degradation of gas-phase VOCs using $TiO_2$ catalyst. J. Kor. Soc. Atmos. Environ., 17, 117-124
22 Schneider, P., G. Lorinci, I.L. Gebefiigi, J. Heinrich, A. Kettrup, and H.E. Wichmann (1999) Vertical and horizontal variability of volatile organic compoundsin homes in Eastern Germany. J. Expos. Anal. Environ. Epidemiol., 9, 282-292
23 Anderson, M.A., W.A. Zeltner, X. Fu, D.T. Tompkins, and D.T. Reindl (1996)Photocatalytic degradation of formaldehyde and other VOCs in indoor air. Center for Indoor Air Research Currents, December, 1, 4
24 d'Hennezel, O., P. Pichat, and D.F. Ollis (1998). Benzene and toluene gas-phase photocatalytic degradation over $H_2O$ and HCL pretreated $TiO_2$: by-products and mechanisms. J. Photochem. Photobiol. A: Chem., 118, 197-204
25 Jacoby, W.A., D.M. Blake, J.A. Fennell, J.E. Boulter, L.M. Vargo, M.C. George, and S.K. Dolberg (1996) Heterogeneous photocatalysis for control of volatile organic compounds in indoor air. J. Air & Waste Manage. Assoc., 46, 891-898
26 Obee, T.N. and R.T. Brown (1995) $TiO_2$ photocatalysis for indoor air applications: effects of humidity and trace contaminant levels on the oxidation rates of formaldehyde, toluene, and 1, 3-butadiene. Environ. Sci. Technol. 29, 1223-1231
27 Jacoby, W.A., D.M. Blake, R.D. Noble, and C.A. Koval (1995) Kinetics of the oxidation of trichloroethylene in air via heterogeneous photocatalysis. J. Catal., 157, 87-96
28 Jo, W.K. and J.W. Oh (2001) Exposure to methyl tertiary butyl ether and benzene in close proximity to service stations. J. Air & Waste Manage. Assoc., 51, 1122-1128
29 Linsebigler, A., G. Lu, and J.T. Yates Jr (1996) CO photooxidation on $TiO_2$. J. Phys. Chem., 1000, 6631-6636
30 Higgins, C.E., W.H. Greist, and G. Olerich (1983) Applications of Tenax trapping to cigarrete smoking. J. Assoc. Off. Anal. Chem., 66, 1074-1083
31 Vorontsov, A.V., E.N. Savinov, G.B. Barannik, V.N. Troitsky, and V.N. Parmon (1997) Quantitative studies on the heterogeneous gas-phase photooxidation of CO and simple VOCs by air over $TiO_2$. Cat. Today, 39, 207-218
32 Park, D.K., B.J. Kim, J.K. Lee, D.J. Byun, W.Y. Yoon, W.J. Lee, and J.Y. Sung (2000) Photocatalytic reactivity of titanioum dioxide in the removal of of benezene from air. J. Kor. Soc. Atmos. Environ., 16, 389-397
33 Chan, C.Y., L.Y. Chan, X.M. Wang, Y.M. Liu, S.C. Lee, S.C. Zou, G.Y. Sheng, and J.M. Fu (2002) Volatile organic compounds in roadside microenvironments of metropolitan Hong Kong. Atmos. Environ., 36, 2039-2047