Browse > Article
http://dx.doi.org/10.14773/cst.2022.21.1.9

Use of Capparis decidua Extract as a Green Inhibitor for Pure Aluminum Corrosion in Acidic Media  

Al-Bataineh, Nezar (College of Pharmacy, Al Ain University)
Al-Qudah, Mahmoud A. (Department of Chemistry, Faculty of Science, Yarmouk University)
Abu-Orabi, Sultan (Department of Chemistry, Faculty of Science, Yarmouk University)
Bataineh, Tareq (Department of Chemistry, Faculty of Science, Yarmouk University)
Hamaideh, Rasha S. (Department of Chemistry, Faculty of Science, Yarmouk University)
Al-Momani, Idrees F. (Department of Chemistry, Faculty of Science, Yarmouk University)
Hijazi, Ahmed K. (Department of Chemistry, Faculty of Science, Jordan University of Science and Technology)
Publication Information
Corrosion Science and Technology / v.21, no.1, 2022 , pp. 9-20 More about this Journal
Abstract
The aim of this paper is to study corrosion inhibition of Aluminum with Capparis decidua extract. The study was performed in a 1.0 M solution of hydrochloric acid (HCl) and was monitored both by measuring mass loss and by using electrochemical and polarization methods. A scanning electron microscopy (SEM) technique was also applied for surface morphology analysis. The results revealed high inhibition efficiency of Capparis decidua extract. Our data also determined that efficiency is governed by temperature and concentration of extract. Optimum (88.2%) inhibitor efficiency was found with maximum extract concentration at 45 o C. The results also showed a slight diminution of aluminum dissolution when the temperature is low. Based on the Langmuir adsorption model, Capparis decidua adsorption on the aluminum surface shows a high regression coefficient value. From the results, the activation enthalpy (∆H#) and activation entropy (∆S#) were estimated and discussed. In conclusion, the study clearly shows that Capparis decidua extract acted against aluminum corrosion in acidic media by forming a protective film on top of the aluminum surface.
Keywords
Aluminum corrosion; Aluminum corrosion inhibition; Corrosion inhibitor; Green corrosion inhibitor; Organic extract corrosion inhibitor;
Citations & Related Records
연도 인용수 순위
  • Reference
1 M. Metikos-Hukovic, R. Babic, and Z. Guubac, Corrosion protection of aluminium in acidic chloride solutions with nontoxic inhibitors, Journal of Applied Electrochemistry, 28, 433 (1998). https://link.springer.com/article/10.1023/A:1003200808093   DOI
2 S. Safak, B. Duran, A. Yurt, and G. Turkoglu, Schiff bases as corrosion inhibitor for aluminium in HCl solution, Corrosion Science, 54, 251 (2012). Doi: https://doi.org/10.1016/j.corsci.2011.09.026   DOI
3 D. I. Njoku, , O. Ikenna, E. Oguzie, K. Oguzie, and N. Ibisi, Natural products for materials protection: Corrosion protection of aluminium in hydrochloric acid by Kola nitida extract, Journal of Molecular Liquids, 219, 417 (2016). Doi: https://doi.org/10.1016/j.molliq.2016.03.049   DOI
4 M. Deyab, Corrosion inhibition of aluminum in biodiesel by ethanol extracts of Rosemary leaves, Journal of the Taiwan Institute of Chemical Engineers, 58, 536 (2016). Doi: https://doi.org/10.1016/j.jtice.2015.06.021   DOI
5 D. Costa, T. Ribeiro , P. Cornette, and P. Marcus, DFT Modeling of Corrosion Inhibition by Organic Molecules: Carboxylates as Inhibitors of Aluminum Corrosion, The Journal of Physical Chemisty C , 120, 28607 (2016). Doi: https://doi.org/10.1021/acs.jpcc.6b09578   DOI
6 A. Yazdzad, T. Shahrabi, and M. Hosseini, Inhibition of 3003 aluminum alloy corrosion by propargyl alcohol and tartrate ion and their synergistic effects in 0.5% NaCl solution, Materials Chemistry and Physics, 109, 199 (2008). Doi: https://doi.org/10.1016/j.matchemphys.2007.11.012   DOI
7 A. El Hosary, R. Saleh. and A. Shams Eldin, Corrosion inhibition by naturally occurringsubstances-I. The effect of Hibiscus subdariffa (karkade) extract on the dissolution of Al and Zn, Corrosion Science, 12, 897 (1972). Doi: https://doi.org/10.1016/s0010-938x(72)80098-2   DOI
8 O. Abiola and J. Otaigbe, Effect of common water contaminants on the corrosion of aluminium alloys in ethylene glycol-water solution, Corrosion Science, 50, 242 (2008). Doi: https://doi.org/10.1016/j.corsci.2007.06.013   DOI
9 G. Gunsekaran and L. Chauhan, Eco friendly inhibitor for corrosion inhibition of mild steel in phosphoric acid medium, Electrochemica Acta, 49, 4387 (2004). Doi: https://doi.org/10.1016/j.electacta.2004.04.030   DOI
10 E. Oguzi, Corrosion Inhibitive Effect and Adsorption Behaviour of Hibiscus Sabdariffa Extract on Mild Steel in Acidic Media, Port Electrochim Acta, 26, 303 (2008). http://www.peacta.org/articles_upload/PEA_26_3_303_314.pdf   DOI
11 A. Maayta and N. Al-Rawashdeh, Inhibition of acidic corrosion of pure aluminum by some organic compounds, Corrosion Science, 46, 1129 (2004). Doi: https://doi.org/10.1016/j.corsci.2003.09.009   DOI
12 R. Bothi, R. Abdul, O. Hasnah, and A. Khalijah, Inhibitory Effect of Kopsia Singapurensis Extract on the Corrosion Behavior of Mild Steel in AcidMedia, Acta Physico-Chimica Sinica, 26, 2171 (2010). Doi: http://www.whxb.pku.edu.cn/EN/10.3866/PKU.WHXB20100646   DOI
13 M. Doche, J. Rameau, R. Durand, and F. Novel-cattin, Inhibition of Corrosion of Aluminium in NaOH Solution by Leave Extract of Mesembryanthemum nodiflorum, Corrosion Science, 41, 805 (2007). https://www.academia.edu/28319653/Inhibition_of_Corrosion_of_Aluminium_in_NaOH_Solution_by_Leave_Extract_of_Mesembryanthemum_nodiflorum   DOI
14 M. Al-Abdallah, A. Maayta, M. Al-Qudah, and N. Al-Rawashdeh, Corrosion Behavior of Copper in Chloride Media, The Open Corrosion Journal, 2, 71 (2009). https://benthamopen.com/contents/pdf/TOCORRJ/TOCORRJ-2-71.pdf   DOI
15 N. Subramanyam, B. Sheshadri, and S. Mayanna, Thiourea and substituted thioureas as corrosion inhibitors for aluminium in sodium nitrite solution, Corrosion Science, 34, 563 (1993). Doi: https://doi.org/10.1016/0010-938X(93)90272-I   DOI
16 P. Okafor, U. Ekpe, E. Ebenso, S. Umoren, and K. Leizou, Inhibition of mild steel corrosion in acidic medium by Allium sativum extracts, Bulletin of Electrochemistry, 21, 347 (2005).
17 N. Al-Rawashdeh and A. Maayta, Cationic surfactant as corrosion inhibitor for aluminum in acidic and basic solutions, Anti-Corrosion Methods and Materials, 52, 160 (2005). Doi: https://doi.org/10.1108/00035590510595157   DOI
18 A. Popova, E. Sokolova, S. Raicheva, and M. Christov, AC and DC Study of the Temperature Effect on Mild Steel Corrosion in Acid Media in the Presence of Benzimidazole Derivatives, Corrosion Science, 45, 33 (2003). Doi: https://doi.org/10.1016/S0010-938X(02)00072-0   DOI
19 E. Oguzie, Studies on the inhibitive effect of Occimum viridis extract on the acid corrosion of mild steel, Materials Chemistry and Physics, 99, 441 (2006). Doi: https://doi.org/10.1016/j.matchemphys.2005.11.018   DOI
20 M. El-Sayed, R. Erasmus, and J. Comins, Inhibition of copper corrosion in acidic chloride pickling solutions by 5-(3-aminophenyl)-tetrazole as a corrosion inhibitor, Corrosion Science, 50, 3439 (2008). Doi: https://doi.org/10.1016/j.corsci.2008.10.002   DOI
21 G. Mu, X. Li, and G. Liu, Synergistic inhibition between tween 60 and NaCl on the corrosion of cold rolled steel in 0.5M sulfuric acid, Corrosion Science, 47, 1932 (2005). Doi: https://doi.org/10.1016/j.corsci.2004.09.020   DOI
22 N. Subramanian N and K. Ramakrishnaiah K, Indian Journal of Technology, 8, 369 (1970).
23 T. Ibrahim, and M. Abou-Zour, Corrosion Inhibition of Mild Steel using Fig Leaves Extract in Hydrochloric Acid Solution, International Journal of Electrochemical Science, 6, 6442 (2011). http://www.electrochemsci.org/papers/vol6/6126442.pdf
24 S. Abd El-Rehim, H. Hassan, and M. Amin, Corrosion inhibition of aluminum by 1,1(lauryl amido)propyl ammonium chloride in HCl solution, Materials Chemistry and Physics, 70, 64 (2001). Doi: https://doi.org/10.1016/S0254-0584(00)00468-5   DOI
25 M. Abu-Dalo, A. Othman, and N. Al-Rawashdeh, Exudate Gum from Acacia Trees as Green Corrosion Inhibitor for Mild Steel in Acidic Media, International Journal of Electrochemical Science, 7, 9303 (2012). http://www.electrochemsci.org/papers/vol7/71009303.pdf
26 L. Nnanna, B. Onwuagba, I. Mejeha, and K. Okeoma, Inhibition effects of some plant extracts on the acid corrosion of aluminium alloy, African Journal of Pure and Applied Chemistry, 4, 11 (2010). Doi: https://academicjournals.org/journal/AJPAC/article-full-text-pdf/B9B67622017
27 E. Noor, Temperature effects on the corrosion inhibition of mild steel in acidic solutions by aqueous extract of fenugreek leaves, International Journal of Electrochemical Science, 2, 996 (2007). http://www.electrochem-sci.org/papers/vol2/2120996.pdf
28 O. Abiola, N. Oforka, E. Ebenso, and N. Nwinuka, Eco-friendly corrosion inhibitors: The inhibitive action of Delonix Regia extract for the corrosion of aluminium in acidic media, Anti-Corrosion Methods and Materials, 54, 54 (2007). Doi: https://doi.org/10.1108/00035590710762357   DOI
29 G. T. Hefter, N. A. North, and S. H. Tan, Organic Corrosion Inhibitors in Neutral Solutions; Part 1 - Inhibition of Steel, Copper, and Aluminum by Straight Chain Carboxylates, Corrosion, 53, 657 (1997). Doi: https://doi.org/10.5006/1.3290298   DOI
30 T. Stimpfling, F. Leroux, and H. Hintze-Bruening, Phosphate-Based Organic Molecules Interleaved with Layered Double Hydroxide: Unraveling the Roles of Host Cations and the Guest-Inhibiting Effect in Aluminum Corrosion Protection, Europian Journal of Inorganic Chemistry, 32, 5396 (2012). Doi: https://doi.org/10.1002/ejic.201200504   DOI
31 A. Ruosan and N. Al-Rawashdeh, Magnetic field effects on inhibition of aluminium corrosion by cationic surfactant in acidic solution, Corrosion Engineering, Science and Technology, 41, 235 (2006). Doi: https://doi.org/10.1179/174327806X132150   DOI
32 T. Bataineh, M. Al-Qudah, E. Nawafleh, and A. Ajlouni, Corrosion Control of Aluminium Alloy in Alkaline Solution Using Leave Extract of Plumbago Europaea, PlumbagoEuropaea. Jordan Journal of Chemistry, 8, 169 (2013). Doi: https://doi.org/10.12816/0001526   DOI
33 T. Bataineh, M. Al-Qudah, E. Nawafleh, and N. Al-Rawashdeh, Sinapis Alba Extract as Green Corrosion Inhibitor for Aluminum in Alkaline Media, International Journal of Electrochemical Science, 9, 3543 (2014). https://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.654.7169&rep=rep1&type=pdf
34 S. Kaya, P. Banerjee, S. Kr. Saha, B. Tuzun, and C. Kaya, Theoretical evaluation of some benzotriazole and phospono derivatives as aluminum corrosion inhibitors: DFT and molecular dynamics simulation approaches, RSC Advances, 6, 74550 (2016). https://pubs.rsc.org/en/content/articlelanding/2016/RA/C6RA14548E   DOI
35 A. Maayta and N. A. F. Al-Rawashdeh, The Inhibiting Effects of Alkyl Benzene Sulphonate and the Magnetic Field on Aluminum Corrosion in Acidic Solution, Jordan Journal of Chemistry, 5, 175 (2010).
36 G. Avwiri and F. OIgho, Inhibitive action of Vernonia amygdalina on the corrosion of aluminum alloys in acidic media, Materials Letters, 57, 3705 (2003). https://www.emerald.com/insight/content/doi/10.1108/03699420710748992/full/html?skipTracking=true   DOI
37 M. Gomma, and M. Wahdan, Schiff bases as corrosion inhibitors for aluminium in hydrochloric acid solution, Materials Chemistry and Physics, 39, 209 (1995). Doi: https://doi.org/10.1016/0254-0584(94)01436-K   DOI
38 S. A. Umoren, I. B. Obot, E. E. Ebenso, P. C. Okafor, O. Ogbobe, and E. E. Oguzie, Anti-Corrosion Methods and Materials, 53, 277 (2006). Doi: https://doi.org/10.1108/00035590610692554   DOI
39 A. Ali, H. Megahed, M Elsayed, and A. El-Etre, Inhibition of acid Corrosion of Aluminum usingSalvadore persica, Journal of Basic and Environmental Sciences, 1, 136 (2014). Doi: https://www.researchgate.net/publication/290194331
40 E. Oguzie, G. Onuoha, and A. Onuchukwu, Inhibitory mechanism of mild steel corrosion in 2 M sulphuric acid solution by methylene blue dye, Materials Chemistry and Physics, 89, 1305 (2005). Doi: https://doi.org/10.1016/j.matchemphys.2004.09.004   DOI