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http://dx.doi.org/10.5487/TR.2008.24.3.227

Analysis of Lead Ions in a Waste Solution Using Infrared Photo-Diode Electrode  

Ly, Suw-Young (Biosensor Research Institute in Seoul National University of Technology)
Lee, Hyun-Kuy (Biosensor Research Institute in Seoul National University of Technology)
Kwak, Kyu-Ju (Department of Chemistry, Yonsei University)
Ko, Jun-Seok (Advanced Scientific Experiment Group in DaeJin High School)
Lee, Jeong-Jae (Advanced Scientific Experiment Group in DaeJin High School)
Cho, Jin-Hee (Advanced Scientific Experiment Group in DaeJin High School)
Kim, Ki-Hong (Advanced Scientific Experiment Group in DaeJin High School)
Kim, Min-Seok (Advanced Scientific Experiment Group in DaeJin High School)
Lee, So-Jung (The Science Group in CheongWon Women's High School)
Publication Information
Toxicological Research / v.24, no.3, 2008 , pp. 227-233 More about this Journal
Abstract
To detect lead ions using electrochemical voltammetric analysis, Infrared Photo-Diode Electrode(IPDE) was applied via cyclic and square wave stripping voltammetry. Lead ions were deposited at 0.5 V(versus Ag/AgCl) accumulation potential. Instrumental measurements systems were made based on a simple and compact detection system. The stripping voltammetric and cyclic voltammetric optimal parameters were searched. The results yielded a cyclic range of $40{\sim}240mgl^{-1}$ Pb(II) and a square wave stripping working range of $0.5{\sim}5.00mgl^{-1}$ Pb(II). The relative standard deviation at 2 and 4 $mgl^{-1}$ Pb(II) was 0.04% and 0.02%(n=15), respectively, using the stripping voltammetric conditions. The detection limit was found to be 0.05 $mgl^{-1}$ with a 40 sec preconcentration time. Analytical interference ions were also evaluated. The proposed method was applied to determine lead ions in various samples.
Keywords
Infrared photo diode electrode; Voltammetry; Lead;
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1 Christian, D.G., Adam, M.S., Greg, P.S., Jansuz, K., Laren, M.T. and Jin, Z.Z. (2003). Optical and dlectrochemical characterization of poly(3-undecyl-2,2-bithiophene)in thin film solid state $TiO_2$ photovoltaic solar cells. Synthetic Metals, 132, 197-204   DOI   ScienceOn
2 Eric, H.C. and Khalil, J.S. (1997). Retrospective analysis of anthropogenic inputs of lead and other heavy metals to the hawaiian sedimentary environment. Applied Organometallic Chemistry, 11, 415-437   DOI   ScienceOn
3 Georges, D. (2002). Balloon-borne near-infrared diode laser spectroscopy for in situ measurements of atmospheric $CH_4\;and\;H_2O$. Spectrochimica Acta Part A, 57, 1855- 1863   DOI   ScienceOn
4 Scarponi, G., Barbante, C., Turetta, C., Gambaro, A. and Cescon, P. (1997). Chemical contamination of antarctic snow: The case of lead. Microchemical Journal, 55, 24-32   DOI   ScienceOn
5 Mohammed, B., Jean, P.P., Joel, J.E.M., Francoise, S.S. and Raigna, A.S. (2002). A thienylene-phenylene copolymer with di(ethylene oxide) side chains and its use in light emitting diodes. Synthetic Metals, 126, 241-244   DOI   ScienceOn
6 Yuwu, C., Jianping, D., Zheng, F.Z., Hongqinq. and C., Guonan, C. (2003). A Study on the electrochemical and electrochemiluminescent behavior of homogentisic acid at carbon electrodes. Electroanalysis, 15, 208-218   DOI   ScienceOn
7 Suw, Y.L., Duck, H.K. and Myung, H.K. (2002). Square-wave cathodic stripping voltammetric analysis of RDX using mercury-film plated glassy carbon electrode. Talanta, 58, 919-926   DOI   ScienceOn
8 Xueji, Z., Bozidar, O., Marjan, R., Marko, K. and Robert, Z. (1999). Cathophoresis paint insulated carbon $^{\circledR}bre$ ultramicro disc electrode and its application to in vivo amperometric monitoring of quantal secretion from single rat melanotrophs. Analytica Chimica Acta, 378, 135-143   DOI   ScienceOn
9 Yamamoto, K. and Yoshida, N. (2002). High-precision isotopic ratio measurement system for methane ($^{12}CH_3\;D^{12}CH_4,\;^{13}CH_4/^{12}CH_4$) by using near-infrared diode laser absorption spectroscopy. Spectrochimica Acta Part A, 58, 2699-2707   DOI   ScienceOn
10 Jyh, M.Z., Hsieh, H.C. and Govindasamy, I. (1999). Selective voltammetric determination of lead(II) on partially quaternized poly(4-vinylpyridine)ymercury film electrodes. Electroanalysis, 11, 108-113   DOI   ScienceOn
11 Kevin, A., Meredith, H., Lynn, H.T., Judy, D., Lee S. and Peter, F.B. (1998). Field Investigation of On-Site Techniques for the Measurement of Lead in Paint Films . Field Analytical Chemistry And Technology, 2, 39-50   DOI   ScienceOn
12 Prinya, M., Saisunee, L., Yuthsak, V. and Boonsom, L. (2002). Design and fabrication of a low-cost flow-through cell for the determination of acetaminophen in pharmaceutical formulations by flow injection cyclic voltammetry. Talanta, 58, 1221-1234   DOI   ScienceOn
13 Maria, S.D., Miriam, E.P. and Beatriz, S.F.B. (2004). A sensitive spectrophotometric method for lead determination by flow injection analysis with on-line preconcentration. Talanta, 63, 405-409   DOI   ScienceOn
14 Schlosser, E., Fernholz, T., Teichert, H. and Ebert, V. (2002). In situ detection of potassium atoms in high-temperature coal-combustion systems using near-infrared-diode lasers. Spectrochimica Acta Part A, 58, 2347-2359   DOI   ScienceOn
15 Sung, O.J., Youn, G.K., Hyung, S.K., Yun, H.K., Chang, L.L., Jang, J.K., Sung, K.L. and Soon, K.K. (2004). Effect of substitution of methyl groups on the luminescence performance of Ir III complexes: Preparation, structures, electrochemistry, photophysical properties and their applications in organic light-emitting diodes (OLEDs). Eur. J. Inorg. Chem., 3415-3423
16 Suw, Y.L. (2008). Voltammetric Assay of Mercury ion in fish Kidneys. Toxicol. Res., 24, 23-28   DOI   ScienceOn
17 Hai-bo, Q., David, T., Paul, W.S. and Michael, J.P. (2000). Dynamic frequency stabilization of infrared diode laser for kinetic studies. Chemical Physics Letters, 322, 57-64   DOI   ScienceOn
18 Kwang, S.P., Pil, S.C., Sang, H.L., Chul, W.L., Ji, S.R., Sung, S.C., Hong, I.R. and Dong, I.C (1998). Endocrine disrupting effects of lead on the ontogeny of oryzias latips. J. Toxicol. Pub. Health, 14, 379-384
19 Gagliardi, G. and Gianfrani, L. (2002). Trace-gas analysis using diode lasers in the near-IRand long-path techniques. Optics and Lasers in Engineering, 37, 509-520   DOI   ScienceOn
20 Kozelka, P.B., Sanudo, W., Flegalc, A.R. and Bruland, E. (1997). Physico-chemical speciation of lead in south san francisco bay. Coastal and Shelf Science, 44, 649-658   DOI   ScienceOn
21 Lauralynn, T., Robert, L.J., Lorna, K., James, A.D., Kevin, A. and Wayne, T.S. (2001). Evaluation of a portable blood lead analyzer with occupationally exposed populations. American Journal of ndustrial Medicine, 40, 354-362   DOI   ScienceOn
22 Jing, L., Jun, Z., Lili, Z., Tao, C., Guangyun, X. and Xiwen, H. (2001). The effects of multi minerals on susceptibility to lead tpxicity in rats. J. Toxicol. Pub. Health, 17, 135-138
23 Jose, G.H., Pedro, H., Yolanda, B. and Lucas, H. (2001). Determination of linuron in soil by stripping voltammetry with a carbon fiber microelectrode. Talanta, 54, 1077-1085   DOI   ScienceOn
24 Huaisheng, W., Aimei, Z., Hui, C., Daojie, L. and Renmin, L. (1998). Adsorptive stripping voltammetric determination of phenol at an electrochemically pretreated carbon-paste electrode with solid paraffin as a binder. Microchimical Journal, 59, 448-456   DOI   ScienceOn
25 El-Hefnawey, G.B., El-Hallag, I.S., Ghoneim, E.M. and Ghoneim, M.M. (2004). Voltammetric behavior and quantification of the sedative-hypnotic drug chlordiazepoxide in bulk form, pharmaceutical formulation and human serum at a mercury electrode. Journal of Pharmaceutical and Biomedical Analysis, 34, 75-86   DOI   ScienceOn
26 Joseph, W., Beatriz, S., Suw, Y.L., Jianmin, L. and Jose, M.P. (2001). Determination of micromolar bromate concentrations by adsorptive-catalytic stripping votammetry of the molybdenum-3-methoxy-4-hydroxymandelic acid complex 2001. Talanta, 54, 147-151   DOI   ScienceOn
27 Ouassim, G., Gwenael, C. and Daniel, B. (2004). Chemical reactivity of 4 bromophenyl modified glassy carbon electrode. Electrochemistry Communications, 6, 254-258   DOI   ScienceOn
28 Cidalia, M.S.B., Rui, A.R.B., Maria, L.S.G. and Ana, M.M. (2001). Dissolved Pb(II) speciation in a polluted river. Electroanalysis, 13, 1497-1540   DOI   ScienceOn
29 Greg, A.G. and Alexander, F.H. (2001). Effects of recording media composition on the responses of Nafion-coated carbon fiber microelectrodes measured using high-speed chronoamperometry. Journal of Neuroscience Methods, 109, 13-21   DOI   ScienceOn
30 Jeong, W.C., Yun, S.N., Byung, K.O., Won, H.L. and Masamichi, F. (2001). Artificial molecular photodiode consisting of GFP/viologen hetero-thin film. Synthetic Metals, 117, 241-243   DOI   ScienceOn
31 Yu, C.T., Barry, A.C., Katherine, H., John, S.F., Frank, M. and Richard, G.C. (2001). Selective voltammetric determination of lead(II) on partially quaternized poly(4-vinylpyridine)ymercury film electrodes. Electroanalysis, 13, 831-835   DOI   ScienceOn
32 Khiena, Z.B., Inna, V.K., Elena, and G.M., Stanislav, I.P., Yuri, G.M. and Andrei, E.V. (2001). Small-size sensors for the in-field stripping voltammetric analysis of water. Field Analytical Chemistry and Technology, 5, 260-271   DOI   ScienceOn
33 Chau, Y.K. and Yang, F. (1997). A novel technique for direct derivatization of ionic organotin and alkyl-lead compounds in sediment: Simultaneous determination of organotin and alkyl-lead compounds in sediment by gas chromatographyplasma atomic emission (GC-AED) dual-channel detection. Applied Organometallic Chemistry, 11, 851-858   DOI   ScienceOn
34 Jahan, B.R., Reza, O. and Abolfazl, K. (2001). Carbon paste electrode spiked with ferrocene carboxylic acid and its application to the electrocatalytic determination of ascorbic acid. Journal of Electroanalytical Chemistry, 515, 45-51   DOI   ScienceOn
35 Kai, M.A., Horst, S., Robert, S., Franz, S., Farideh, M., Alexander, P., Gunther, L., Kai, C.M and Jurgen, O.B. (2004). Blue-green light emitting poly(phenylenevinylene) derivatives as candidates for polymer LEDs: Synthesis and characterization. Chem. Phys., 205, 1840-1850
36 Robert, J.R., Janie, L.G., James, A.D., Martin, R.P. and William, E.H. (1999). Blood lead levels among children of lead-exposed workers: A meta-analysis. American Journal of Industrial Medicine, 36, 475-481   DOI   ScienceOn
37 Suw, Y.L., Young, S.J., Myung, H.K., In, K.H., Woon, W.J. and Hyun, S.K. (2004). Measuring caffeine using a simple graphite pencil electrode with square wave anodic stripping voltammetry. Microchim, Acta, 146, 207-213   DOI
38 Eninari, V.Z., Parvitte, B., Courtois, D., Kapitanov, V.A. and Yu, N.P. (2003). Methane detection on the sub-ppm level with a near-infrared diode laser photoacoustic sensor. Technology, 44, 253-261
39 Cristina, M.B. and Margarida, M.C. (2001). Speciation of inorganic arsenic in natural waters by square-wave cathodic stripping voltammetry. Electroanalysis, 13, 1098-1104   DOI   ScienceOn
40 Lung, C.C. and Yin, L.H. (2004). High reliability GaN-based light-emitting diodes with photo-enhanced wet etching. Solid-State Electronics, 48, 1239-1242   DOI   ScienceOn
41 Priya, V.J., Vijaykumar, S.I. and Ashwini, K.S. (2001). Voltammetric behavior of a-tocopherol and its determination using surfactant +ethanol +water and surfactant +acetonitrile +water mixed solvent systems. Analytica Chimica Acta., 441, 201-206   DOI   ScienceOn
42 Dong, X., Qundong, S., Suyang, Z. and Xiqun, J. (2003). Synthesis and characterization of novel soluble alternating copoly(phenylene vinylene) derivative for light-emitting electrochemical cell. Journal of Applied Polymer Science, 88, 1350-1356   DOI   ScienceOn
43 Emanuele, S., Alessandra, L., Lucia, P., Maria, R.S. and Giovanni, F. (2003). Blood and hair lead levels in boys and girls living in two Sardinian towns at different risks of lead pollution. Ecotoxicology and Environmental Safety, 55, 293-299   DOI   ScienceOn