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Analysis of formaldehyde using DNPH cartridge/LC-MS in the Ban-Woll.Shi-Hwa Industrial Complex  

Cho Deok-Hee (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Song Il-Seok (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Kim In-Gu (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Kim Woong-Soo (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Kim Jong-Bo (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Kim Tae-Hyun (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Hwang Sun-Min (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Nam Woo-Kyong (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
Publication Information
Journal of environmental and Sanitary engineering / v.21, no.1, 2006 , pp. 35-43 More about this Journal
Abstract
Formaldehyde is important because of their irritant and toxic properties, mutagenicity and carcinogenicity. In this study, liquid chromatography-mass spectrometry (LC-MS) is used for the analysis of formaldehyde after derivatization with 2,4-dinitrophenylhydrazine (DNPH) cartridge. Analytical parameters such as linearity, repeatability and minimum detection limit were evaluated. The linearity ($r^2$) was 0.9997 when analyte concentration ranges from 25 to $200{\mu}g/l$. The relative standard deviation (%RSD) was 1.25 % for concentration of $200{\mu}g/l$. The minimum detection limit (MDL) was 0.73 ppbv. It was shown that LC-MS method has a great potential for formaldehyde analysis. The results of formaldehyde from the survey of Ban-Woll and Shi-Hwa Industrial Complex samples, the highest level was 6.20, 3.93 ppb, respectively. The highest emission level of formaldehyde at chemical plants in the Ban-Woll' Shi-Hwa Industrial Complex was 5421.25 ppb.
Keywords
Formaldehyde; DNPH cartridge; LC-MS; Ban-Woll.Shi-Hwa Industrial Complex;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
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