Browse > Article

Resin Synthesis of Adsorbent Metal Ions using 1-Aza-12-Crown-4  

Kim Joon-Tae (Dept. of Environmental Administration, Gwangju Health College)
Roh Gi-Hwan (Dept. of Environmental Administration, Gwangju Health College)
Publication Information
Journal of environmental and Sanitary engineering / v.19, no.3, 2004 , pp. 52-57 More about this Journal
Abstract
Content of chlorine in s쇼rene-DVB copolymer was decreased as crosslink increased and it is because as crosslink increased $1\%,\;2\%,\;5\%\;and\;10\%$ DVB content increased and crosslink density increased and cavity was reduced. Functional group of resin almost disappeared as C-C1 peak around $700cm^{-1}$ was substituted with 1-aza-12-C-4 macrocyclic ligand and new peak of C-N around $1020cm^{-1}$ appeared, so it was confirmed that styrene-DVB copolymer and ligand were compounded. As crosslink increased in the analysis of element contents, it resulted in the reduction of nitrogen content and it is because as crosslink increased, it led to the reduction of chlorine content in the process of substitution reaction and it affected macrocyclic ligand substituted. Form of functional synthetic resin showed distortion of its particles as macrocyclic ligand was introduced to styrene-DVB copolymer and hydrogen of ligand caused substitution with chlorine element of styrene molecule.
Keywords
styrene; 1-aza-12-crown-4(1-aza-12-C-4); macrocyclic ligand; crossline divinylbenzene(DVB);
Citations & Related Records
연도 인용수 순위
  • Reference
1 H. Otsuka, H. Najima, M. Takagi and K. Ueno, Anal. Chem. Acta, 147, 227 (1983).
2 L. F. Lindoy, K. R. Adam, D. S. Bladwine, A. Bashall, M. McPartlin, H. R. Powell, J. Chem. Soc., Dalton Trans., 237 (1994).
3 C. A. Davis, A. J. Leong, L. F. Lindoy, J. Kim and S. H. Lee, J Aust. Chem. Soc, Dalton Trans., 51, 189 (1998).
4 T. Hayashita, J. H. Lee, S. Chern and R. A. Bartsch, Anal. Chem., 63, 1844 (1991)
5 T. Kato, T. Kago, K. Kusakabe, S. Morooka and H. Egawa, J. Chem. Eng. Japan, 23, 744 (1990).
6 S. K. Park, j. T. Kim, and G. H. Noh, J. Kor. sani., 15, 77 (2000)
7 C. H. Kim and H. L. Hwang, J Kor. Chem. Soc., 43, 418 (1999).
8 K. Kimura, H. Harino, E. Hayata and T. Shono, Anal. Chem. 58, 2233 (1986).
9 M. Nakajima, K. Kimura and T. Shono, Anal. Chem., 55, 463 (1983)
10 G. Bombieri and G. Depaoli, Inorg. Chem. Acta., 18, 123 (1976).
11 M. A. Ahearn, j. Kim, A. J. Leong, L. F. Lindoy, G. V. Meehan and O. A. Mattews, J Chern. Soc., Dalton Trans., 3591(1996)
12 H. Egawa, T. Nonaka and M. Ikari, J. Appl. Poly. Sci., 29, 2054 (1984)
13 K. S. Huh and S. G. Sin, J. Kor. Ind. Eng. Chem., 9, 680 (1998)
14 E. Blasius, W. Adrian, K. P. Janzen, and G. Klautke, J Chromatogr., 68, 89 (1974)
15 C. J. Pederson, J. Am. Chem. Soc., 92, 386 (1970)