Browse > Article

Electrical and Optical Properties of phosphorus doped ZnO Thin Films at Various Post-Annealing Temperatures  

Han, Jung-Woo (Dept. of Electronics Engineering, Inha University)
Kang, Seong-Jun (Dept. of Electrical and Semiconductor Engineering, Chonnam National University)
Yoon, Yung-Sup (Dept. of Electronics Engineering, Inha University)
Publication Information
Abstract
The effects of post-annealing temperature on the optical and electrical properties of P-doped ZnO thin films grown on sapphire substrate have been investigated under oxygen ambient. The XRD shows that regardless of the post-annealing temperature, all P-doped ZnO thin films indicate the c-axis orientation. The results of hall effect measurements indicate the P-doped ZnO thin film annealed at $850^{\circ}C$ exhibits p-type behavior with hole concentration of $1.18{\times}1016cm^{-3}$ and hole mobility of $0.96cm^2/Vs$. The low-temperature (10K) Photoluminescence results reveal that the peak related to the neutral-acceptor exciton (A0X), free electrons to neutral acceptor (FA) and donor acceptor pair (DAP) at 3.351ev, 3.283eV and 3.201eV are observed in the films showing p-type behavior with acceptor. The optimization of deposition and post-annealing conditions will certainly make the P-doped ZnO thin films promising materials for the application to the next generation of optical devices.
Keywords
P-doped ZnO thin films; Annealing; PLD; Hall-effect; PL;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Dae-Kue Hwang, Min-Suk Oh, Jae-Hong Lim, and Seong-Ju Park, 'ZnO thin films and light-emitting diodes', J. Phys. D: Appl. Phys, Vol.40, pp. R387-R413, 2007   DOI   ScienceOn
2 Yu-Jia Zeng, Zhi-Zhen Ye, Wei-Zhong Xu, Lan-Lan Chen, Dan-ying Li, Li-Ping Zhu, Bing-Hui Zhao, and Ying-Lin Hu, 'Realization of p-type ZnO films via monodoping of Liacceptor', J.Cryst. Grwoth. Vol. 283, pp.180-184, 2005   DOI   ScienceOn
3 Z.Y. Ning, S.H Cheng, S.B. Ge, y. Chao, Z.Q.Gang,Y.x. Zhang, Z.G. Liu, 'Preparation and characterization of ZnO:AI films by pulsed laser deposition', thin solid films, 307, pp.50-53 (1997)   DOI   ScienceOn
4 D.K Hwang, MS. Oh, J.H. Lim, C.G. Kang, and S.J. Park, 'Effect of annealing temperature and ambient gas on phosphorus doped p-type ZnO'. Appl. Phys.Lett, Vol.90, pp021106, 2007   DOI   ScienceOn
5 J.D. Ye, S.L.Gu, S.M Zhu, F.Qin, S.M Liu, W. Liu, X. Zhou, L.Q. Hu, R Zhang, Y. Shi, And Y.D. Zheng, 'production of high-quality ZnO films by the two-step annealing method', J. Appl. Phys, Vol. 96, pp5308, 2004   DOI   ScienceOn
6 Dae-Kue Hwang, Hyun-Sik Kim, Jae-Hong Lim, Jin-Yong Oh, Jun-Ho Yang, Seong-Ju Park and Kyoung-Kook Kim, 'Study of the photoluminescence of phosphorus-doped p-type ZnO thin films grown by radio-frequency magnetron sputtering', Appl. Phys. Lett. Vol. 86, pp. 151917, 2005   DOI   ScienceOn
7 A I. Ali,C. H Kim, l H Cho and Bog G. Kim, 'Growth and Characterization of ZnO:AI Thin Film Using RF Sputtering for Transparent Conducting Oxide', J.Korean. Phys. Soc. 49, s652, (2006).
8 Dae-Kue Hwang, Min-Suk Oh, Yong-Seok Choi, and Seong-Ju Park, 'Effect of pressure on the properties of phosphorus-doped p-type ZnO thin films grown by radio frequency-magnetron sputtering;, Appl. Phys. Lett, Vol.92, pp.161109, 2008   DOI   ScienceOn
9 J. L. Zhao, X. M Li, l M. Bian, W. D. Yu, and C. Y. Zhang. 'Growth of nitrogen-doped p-type ZnO films by spray pyrolysis and their electrical and optical properties', J. Crystal. Growth. Vol. 280, pp. 495-501. 2005   DOI   ScienceOn
10 G.Du, Y.Ma,Y. Zhang, T.Yang, 'Preparation of intrinsic and N -doped p-type ZnO thin films by metalorganic vapor phase epitaxy', Appl, Phys. Lett, Vol.87, pp.213103, 2005   DOI   ScienceOn
11 D.e.Look, G.MRenlund, RH Burgener and lR Sizelove, 'As-doped p-type ZnO produced by an evaporation/sputtering process', Appl. Phys. Lett, Vol. 85, pp.5269-5271, 2004   DOI   ScienceOn
12 Chongmu LEE, Jongmin LIM, Suyoung PARK and Hyounwoo KIM, "Growth of nitrogen-doped p-type ZnO thin films prepared by atomic layer epitaxy, Rare Metals,Vol.25, pp.110-114, 2006   DOI   ScienceOn
13 L. P. Dai ,H Deng , F. Y. Mao and l D. Zang, 'The recent advances of research on p-type ZnO thin film', J Mater Sci: Mater Electron, Vo1.19, pp. 727 -734, 2008
14 B.J.Jin, S.H.Bae, S.Y.Lee and S.Im, 'Effects on native defects on optical and electrical properties of ZnO prepared by pulsed laser deposition', mater. sci.eng. B, Vol.71 , pp.301-305, 2000   DOI   ScienceOn
15 Soon-Jin So and Choon-Bae Park, 'Diffusion of phosphorus and arsenic using ampoule-tube method on undoped ZnO thin films and electrical and optical properties of P-type ZnO thin films.', Journal of Crystal Growth; Vol.285, pp.606-612, 2005   DOI   ScienceOn
16 K K Kim. HS. Kim, DK Hwang, lH Lim and S.l Park, 'Realization of p-type ZnO thin films via phosphorus doping and thermal activation of the dopant', Appl. Phys. Lett. Vol 83. pp. 63-65. 2003   DOI   ScienceOn
17 Veeramuthu Vaithianathan, Byung-Teak Lee, and Sang Sub Kim, 'Pulsed-laser-deposited p-type ZnO films with phosphorus doping', J. Appl. Phys. Vol.98, pp.043579, 2005
18 A Martin, JP. Espinos, A Justo, JP. Holgado,F. Yubero, AR Gonzalez Elipe, 'Preparation of transparent and conductive AI-doped ZnO thin films by ECR plasma enhanced CVD', surface&coatings technology , 151-152, pp. 289-293, (2002)   DOI   ScienceOn