Browse > Article
http://dx.doi.org/10.4491/KSEE.2014.36.5.311

Phenol Removal by Ozone-Activated Carbon Hybrid Process  

Kim, Hwanik (Department of Environmental Engineering & Green Technology Institute, Gyeongnam National University of Science and Technology)
Moon, Ji-Hoon (Central Laboratory, Gyeongnam National University of Science and Technology)
Chung, Jae Woo (Department of Environmental Engineering & Green Technology Institute, Gyeongnam National University of Science and Technology)
Publication Information
Abstract
Effects of operating parameters such as activated carbon dose and pH on the phenol oxidation in ozone-activated carbon hybrid process were investigated through a kinetic study. Activated carbon enhanced the self-decomposition of ozone, generating $OH{\cdot}$, thus promoting phenol degradation. The pseudo-first order rate constants of phenol degradation increased and half-life of phenol decreased with activated carbon dose. The increase of pH enhanced $OH{\cdot}$ generation through chain reactions initiated by $OH^-$, therefore increasing the phenol degradation rate. TOC removal efficiency increased about 3.2 times by adding activated carbon in ozonation process.
Keywords
Phenol; Ozone; Activated Carbon; Catalytic Oxidation; Hybrid Process;
Citations & Related Records
Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 Kang, J. W., Choie, H. C., Jung, S. W. and Choie, S. I., "Evaluation of the Ozone / high pH and Ozone / Hydrogen Peroxide Advanced Oxidation Processes(II)," J. Kor. Soc. Environ. Eng., 15(3), 537-547(1993).
2 Gunten, U., "Ozonation of drinking water: Part I. Oxidation kinetics and product formation," Water Res., 37(7), 1443-1467(2003).   DOI   ScienceOn
3 Zeng, Z., Zou, H., Lic, X., Arowo, M., Sun, B., Chen, J., Chu, G. and Shao, Lei., "Degradation of phenol by ozone in the presence of Fenton reagent in a rotating packed bed," Chem. Eng. J., 229, 404-411(2013).   DOI   ScienceOn
4 Wu, J., Rudy, K. and Spark, J., "Oxidation of aqueous phenol by ozone and peroxidase," Adv. Environ. Res., 4(4), 339-346(2000).   DOI   ScienceOn
5 Oliveira, T. F., Chedeville, O., Cagnon, B. and Fauduet, H., "Degradation kinetic of DEP in water by ozone/activated carbon process: Influence of pH," Desalination, 269(1-3), 271-275(2011).   DOI   ScienceOn
6 Rivas, F. J., Beltran, F., Gimeno, O., Acedo, B. and Carvalho, F., "Stabilized leachates: Ozone-activated carbon treatment and kinetics," Water Res., 37(20), 4823-4834(2003).   DOI   ScienceOn
7 Poloa, M. S., Gunten, U. V. and Utrilla, J., "Efficiency of activated carbon to transform ozone into OH radicals: Influence of operational parameters," Water Res., 39(14), 3189-3198(2005).   DOI   ScienceOn
8 Polo, M. S., Utrilla, J. R., Joya, G. P., García, M. A. F. and Toledo, I. B., "Removal of pharmaceutical compounds, nitroimidazoles, from waters by using the ozone/carbon system," Water Res., 42(15), 4163-4171(2008).   DOI   ScienceOn
9 Oliveira, T. F., Chedeville, O., Fauduet, H., Cagnon, B., "Use of ozone/activated carbon coupling to remove diethyl phthalate from water: Influence of activated carbon textural and chemical properties," Desalination, 276(1-3), 359-365(2011).   DOI   ScienceOn
10 Valdes, H., Zaror, C.A., "Heterogeneous and homogeneous catalytic ozonation of benzothiazole promoted by activated carbon: Kinetic approach," Chemosphere, 65(7), 1134-1136(2006).
11 Moon, J. H., "The catalytic effect of the ozone/CNT process using para-chlorobenzoic acid," Department of Environmental Engineering, Graduate School Yonsei University(2013).
12 Alvarez, P. M., Garcia-Araya, J. F., Beltrana, F. J., Giraldez, I., Jaramillo, J. and Gomez-Serrano, V., "The influence of various factors on aqueous ozone decomposition by granular activated carbon and the development of mechanistic approach," Carbon, 44(14), 3102-3112(2006).   DOI   ScienceOn
13 Jans, U. and Horigne, J., "Activated Carbon and Carbon Black Catalyzed transformation of aqueous ozone into OH radical," Ozone Sci. Eng., 20(1), 67-87(1998).   DOI   ScienceOn
14 Kim, H., Lee, M. E., Kang, S. and Chung, J. W., "Thermodynamic Analysis of Phenol Adsorption by Powdered Activated Carbon," J. Kor. Soc. Environ. Eng., 35(3), 220-225(2013).   과학기술학회마을   DOI   ScienceOn
15 Song, S. J,, Oh, B. S., Kim, K. S., Na, S. J., Lee, E. T. and Kang, J. W., "A Study on the Advanced Oxidation Process by Catalytic Ozonation with Granular Activated Carbon," J. Kor. Soc. Environ. Eng., 26(1), 52-57(2004).   과학기술학회마을
16 Liu, Q.-S., Zheng, T., Wang, P., Jiang, J.-P. and Li N., "Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers," Chem. Eng. J., 157, 348-356(2010).   DOI   ScienceOn
17 Dąbrowski, A., Podkoscielny, P., Hubicki, Z. and Barczak, M., "Adsorption of phenolic compounds by activated carbon- a critical review," Chemosphere, 58(8), 1049-1070(2005).   DOI   ScienceOn
18 Park, J, "Effects of operating parameters on ozone generation and phenol conversion in ozonation process," Department of Environmental Engineering, Graduate School JinJu National University(2009).
19 Kang, J. W., "Kinetic Studies of the Advanced Oxidation Processes Involving Ozone, Hydrogen peroxide, and Ultraviolet Radiation(I)," J. Kor. Soc. Environ. Eng., 15(2), 501-510(1993).
20 Zhang, J., Lee, K. H., Cuic, L. and Jeong, T. S., "Degradation of methylene blue in aqueous solution by ozone-based process," J. Ind. Eng. Chem., 15(2), 185-189(2009).   DOI   ScienceOn
21 Orra, P. T., Jonesa, G. J. and Hamilton, G. R., "Removal of saxitoxins from drinking water by granular activated carbon, ozone and hydrogen peroxide-implications for compliance with the Australian drinking water guidelines," Water Res., 38(20), 4455-4461(2004).   DOI   ScienceOn
22 Lei, L., Gu, L., Zhang, X. and Su, Y., "Catalytic oxidation of highly concentrated real industrial wastewater by integrated ozone and activated carbon," Appl. Catal. A: General, 327(2), 287-294(2007).   DOI   ScienceOn
23 Dehoulia, H., Chedeville, O., Cagnon, B., Caquereta, V. and Portea, C., "Influences of pH, temperature and activated carbon properties on the interaction ozone/activated carbon for a wastewater treatment process," Desalination, 254(1-3), 12-16(2010).   DOI   ScienceOn
24 Utrilla, J. R., Diaz, J. M., Polo, M. S., Garcia, F. M. A. and Toledo, I. B., "Removal of the surfactant sodium dodecylbenzenesulphonate from water by simultaneous use of ozone and powdered activated carbon: Comparison with systems based on $O_3$ and $O_3/H_2O_2$," Water Res., 40(8), 1717-1725(2006).   DOI   ScienceOn
25 Sanchez-Polo, M. and Rivera-Utrill, J., "Effect of the ozonecarbon reaction on the catalytic activity of activated carbon during the degradation of 1, 3, 6-naphthalenetrisulphonic acid with ozone," Carbon, 41(2), 303-307(2003).   DOI   ScienceOn