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http://dx.doi.org/10.4491/KSEE.2011.33.1.032

Correlation of Heavy Metal Concentrations between Total Digestion and Aqua Regia Digestion for Sediments from Yeongsan and Seomjin Watersheds  

Oh, Da-Yeon (Department of Environmental Engineering, Chonnam National University)
Choi, Kyoung-Kyoon (Department of Environmental Engineering, Chonnam National University)
Huh, In-Ae (National Institute of Environmental Research)
Hwang, In-Seong (Department of Civil and Environmental Engineering, Pusan National University)
Kim, Young-Hoon (Department of Environmental Engineering, Andong National University)
Hur, Jin (Department of Environmental and Energy, Sejong University)
Shin, Hyun-Sang (Department of Environmental Engineering, Seoul National University of Science and Technology)
Oh, Jeong-Eun (Department of Civil and Environmental Engineering, Pusan National University)
Shin, Won-Sik (Department of Environmental Engineering, Kyungpook National University)
Park, Jeong-Hun (Department of Environmental Engineering, Chonnam National University)
Publication Information
Abstract
In this study, the correlations of concentrations in sediment heavy metals between two pretreatment methods, total digestion and aqua regia digestion, have been investigated. Total 43 samples had been collected from streams and lakes in Yeongsan and Seomjin watersheds. They were decomposed in two pretreatment methods and five metal components (Cd, Cr, Ni, Pb, Zn) were analyzed. Overall average concentrations of heavy metals were Zn>Cr>Pb>Ni>Cd in the order. The concentrations of aqua regia digestion were 35.0% (Cd), 53.8% (Cr), 66.2% (Ni), 64.4% (Pb) and 76.4% (Zn) of the concentrations of total digestion and heavy metal concentrations of total digestion were higher. Heavy metal concentrations in sediments from lakes were higher than those from streams. The correlation equations between the concentrations of total digestion and aqua regia digestion were obtained. The concentrations of Zn and Ni, which showed strong linear correlations, increased in aqua regia digestion as the concentration in total digestion increased. The linear correlation coefficients between two digestion methods for most analyzed metals were above the average correlation. However, these results can be applied with limitations due to heterogeneity of sediments.
Keywords
Yeongsan River; Sediment; Heavy Metals; Total Digestion; Aqua Regia Digestion; Correlation;
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Times Cited By KSCI : 3  (Citation Analysis)
연도 인용수 순위
1 박선구, 양영모, "호소내 퇴적물의 근접도에 따른 수질오염물질 분석(I) - COD, T-N, T-P, pH -," Anal. Sci. Technol., 14(3), 238-243(2001).
2 박선구, 송기봉, 조기환, "호소내 퇴적물의 중금속 분석 비교," 한국분석과학회지, 14(2), 173-179(2001).
3 장병욱, 우철웅, 김성필, "농촌 중.소 하천 및 저수지 퇴적물의 오염현황," 농촌계획, 9(2), 1-6(2003).
4 이준기, 김석구, 송재홍,이 태윤, "부산시 도심하천 퇴적물의 유기물 및 중금속 오염도 평가," 한국지반환경공학회논문집, 11(1), 35-43(2010).
5 김주용, 정철환, 오강호, 고영구, 문정준, 유경아, "광주부근 영산강과 광주천의 하상퇴적물의 중금속 오염," 한국지구과학회지, 20, 96-100(1999).
6 조영길, 김주용, "영산강 하상퇴적물의 중금속 함량," 한국환경과학회지, 7, 281-290(1998).
7 환경부, "하천 호소 퇴적물 모니터링 기본계획 수립 연구," 환경부(2007).
8 국토해양부, "해양환경공정시험방법," 국토해양부(2008).
9 환경부, "토양오염공정시험기준," 환경부(2009).
10 Wenzel, W. W., Kirchbaumer, N., Prohaska, T., Stingeder, G., Lombi, E. and Adriano, D. C., "Arsenic fractionation in soils using an improved sequential extraction procedure," Anal. Chim. Acta, 436, 309-323(2001).   DOI   ScienceOn
11 박성현, "SPSS (PASW) 17.0 이해와 활용," (2009).
12 김주용, 은고요나, 고영구, 윤석태, 오강호, 김동주, "전남 나주-영암지역의 영산강 하류 시추퇴적물의 퇴적환경과 지구화학적 특성," 한국지구과학회지, 22, 301-317(2001).
13 Balcerzak, M., "Sample Digestion Methods for the Determination of Traces of Precious Metals by Spectrometric Techniques," Anal. Sci., 18, 737-750(2002).   DOI   ScienceOn
14 Chen, M. and Ma, L. Q., "Comparison of Three Aqua Regia Digestion Methods for Twenty Florida Soils," Soil Sci. Soc. Am. J., 65, 491-499(2001).   DOI   ScienceOn
15 Gaudino, S., Galas, C., Belli, M., Barbizzi, S., Zorzi, P. d., Jacimovic, R., Jeran, Z., Pati, A. and Sansone, U., "The role of different soil sample digestion methods on trace elements analysis: a comparison of ICP-MS and INAA measurement results," Acc. Qual. Assur., 12, 84-93(2007).   DOI   ScienceOn
16 류호돈 김선준, "동두천 부근 신천의 하천수 및 하상퇴적물의 중금속오염," 한국자원공학회지, 35, 80-89(1998).
17 박선구, 김성수, 고오석, "호소내 퇴적물의 수질오염물질 분석(II) - 중금속," Anal. Sci. Technol., 14(2), 140-146(2001).
18 윤정기, 김동호, 김태승, 박종결, 정일록, 김종하,김혁, "우리나라 토양의 중금속 자연배경농도 평가," 한국지하수토양환경학회지, 14(3), 32-39(2009).
19 임동일, 최진용, 정회수, 최현우, 김영옥, "한국 연안 퇴적물 내 중금속 원소의 자연적 배경농도 연구," Ocean and Polar Res., 29(4), 379-389(2007).   DOI   ScienceOn
20 국토해양부, "해양환경기준 설정 및 개선방안 연구," (2009).
21 원태연, "통계조사분석 : SPSS (PASW staticstics) 18.0," (2010).