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http://dx.doi.org/10.4491/KSEE.2011.33.12.900

Distribution and Source Identification of PCDD/Fs and Co-PCBs in Sediments from the Geum River  

Park, Jong-Eun (Dept. of Environmental Engineering, Chonbuk National University)
Kim, Jong-Guk (Dept. of Environmental Engineering, Chonbuk National University)
Ahn, Sung-Yun (Dept. of Environmental Engineering, Chonbuk National University)
Publication Information
Abstract
To investigate concentration and sources of PCDD/Fs and Co-PCBs in sediments, total 52 sediment samples were measured at 17 sites in Geum River. As a result of analysis, total concentrations of PCDD/Fs and Co-PCBs were ranged from not detected (N.D.)~193.47 pg/g-d.w. (mean value: 84.52 pg/g-d.w) and 0.34~359.19 pg/g-d.w (mean value: 114.65 pg/g-d.w.) respectively. Also, toxic equivalent (TEQ) concentration of PCDD/Fs and Co-PCBs were ranged from N.D.~5.12 (mean value: 0.88) pg I-TEQ/g-d.w and N.D.~0.58 (mean value: 0.09) $WHO_{2005}$-TEQ pg/g-d.w. respectively. The upstream indicate the highest concentration and as it goes to the downstream, it has tendency to decrease. Higher chlorinated compounds were dominant in most of site which detected PCDD/Fs. Occurrence of Co-PCBs isomer patterns appear similar to each sampling site was found. The isomer patterns showed similar between sediment and PCB products. The principal component analysis also showed that the samples contained the characteristics of PCBs products.
Keywords
PCDD/Fs; PCBs; Sediment; Source Identification; PCA;
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Times Cited By KSCI : 4  (Citation Analysis)
연도 인용수 순위
1 황성민, 이석형, 박노진, 옥곤, "신규잔류성유기오염물질 헥사클로로헥산의 대기-토양-물-저질에서의 잔류특성," 한국환경과학회지, 19(12), 1343-1354(2010).
2 W. Wayne Brubaker, and Ronald A, Hites, "Polychlorinated dibenzo-p-dioxins and dibenzofurans: Gas-phase hydroxyl radical reactions and related atmospheric removal," Environ. Sci. Technol., 31, 1805-1810(1997).   DOI   ScienceOn
3 Haijun Zhang, Xiaofeng Zhao, Yuwen Ni, Xianbo Lu, Jiping Chen, Fan Su, Liang Zhao, Ning Zhang, and Xueping Zhang, "PCDD/Fs and PCBs in sediments of the Liaohe River, China: Levels, distribution, and possible sources," Chemosphere, 79, 754-762(2010).   DOI   ScienceOn
4 UNEP chemicals, "Guidelines for the identification of PCBs and materials containing PCBs"(1999).
5 Basel Convention, "Preparation of a national environmentally sound management plan for PCBs and PCBs-contaminated equipment"(2003).
6 강희영, 이인석, 허인애, 신원식, 황인성, 김영훈, 허진, 신현상, 김준하, 오정은, "낙동강 하천 및 호소 퇴적물에서의 PAHs, OCPs, Co-PCBs 농도 분포와 발생원 평가," 대한환경공학회지, 32(7), 656-664(2010).
7 국립환경연구원, 내분비계장애물질 측정분석방법(2002).
8 국립환경과학원, "환경 중 다이옥신 배출 및 오염실태 조사와 발생기전 규명에 관한 연구"(2005).
9 김영호, 오정근, 김종국, 김경수, "하천 퇴적물 중 PCBs 농도분포 및 발생원 해석," 대한환경공학회지, 32(11), 995-1000(2010).
10 금강유역 환경청, http://www.me.go.kr/gg/
11 K. I. Choi, and D. H. Lee, "PCDD/DF in leachates from Korean MSW landfills," Chemosphere, 63, 1353-1360(2006).   DOI   ScienceOn
12 국립환경과학원, 하천 퇴적물 중 POPs 축적도 모니터링 사업(III),(2008).
13 Kim, K. S., Hirai, Y., Kato, M., Urano, K. and Masunaga, S., "etailed PCB congener patterns in incinerator flue gas and commercial PCB formulations (Kaneclor)," Chemosphere, 55, 539-553(2004).   DOI   ScienceOn
14 Shin, S. K., Kim, K. S., You, J. C., Song, B. J. and Kim, J. G., "Concentration and congener patterns of polychlorinated biphenyls in industrial and municipal waste incinerator flue gas in Korea," J. Hazard. Mater, A133, 53-59(2006).
15 Joanna Stevens, Nicholas J. L. Green, and Kevin C. Jones, "Survey of PCDD/Fs and Non-ortho PCBs in UK sewage sludge," Chemosphere, 44, 1455-1462(2001).   DOI   ScienceOn
16 Ki-In Choi, and Dong-Hoon Lee, "PCDD/DF in leachates from Korean MSW landfills," Chemosphere, 63, 1353-1360(2006).   DOI   ScienceOn
17 Narayanan Kannan, Sang Hee Hong, Won Joon Shim, and Un Hyuk Yim, "A congener-specific survey for polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) contamination in Masan Bay, Korea," Chemosphere, 68, 1613-1622(2007).   DOI   ScienceOn
18 Man Ren, Ping'an Peng, Deyi Chen, Pei Chen, and Xiaoming Li, "Patterns and sources of PCDD/Fs and dioxin-like PCBs in surface sediments from the East River, China," J. Hazard. Mater., 170, 473-478(2009).   DOI   ScienceOn
19 H. X. Liu, Q. H. Zhang, Y. W. Wang, Z. W. Cai, and G. B. Jiang, "Occurrence of polychlorinated dibenzo-p-dioxins, dibenzofurans and biphenyls pollution in sediments from the Haihe River and Dagu drainage river in Tianjin City, China," Chemosphere, 68, 1772-1778(2007).   DOI   ScienceOn
20 Y. Z. Sun, B. Zhang, L. R. Gao, Z. T. Liu, and M. H. Zheng, "Polychlorinated dibenzop-dioxins and dibenzofurans in surface sediments from the estuary area of Yangtze River, People's Republic of China," B. Environ. Contam. Toxicol., 75, 910-914(2005).   DOI   ScienceOn
21 M. H. Zheng, S. G. Chu, G. Y. Sheng, Y. S. Min, Z. C. Bao, and X. B. Xu, "Polychlorinated dibenzo-p-dioxins and dibenzofurans in surface sediments from the Pearl River Delta in China," B. Environ. Contam. Toxicol., 66, 504-507(2001).   DOI   ScienceOn
22 A. A. El-Kady, M. A. Abdel-Wahhab, B. Henkelmann, M. H. Belal, M. K. S. Morsi, S. M. Galal, and K. W. Schramm, "Polychlorinated biphenyl, polychlorinated dibenzop-dioxin and polychlorinated dibenzofuran residues in sediments and fish of the River Nile in the Cairo region," Chemosphere, 68, 1660-1668(2007).   DOI   ScienceOn
23 O. Kiguchi, T. Kobayashi, Y.Wada, K. and Saitoh, N. Ogawa, "Polychlorinated dibenzop-dioxins and dibenzofurans in paddy soils and river sediments in Akita, Japan," Chemosphere, 67, 557-573(2007).   DOI   ScienceOn
24 C. Rappe, R. Andersson, M. Bonner, K. Cooper, H. Fiedler, F. Howell, S. E. Kulp, and C. Lau, "PCDDs and PCDFs in soil and river sediment samples from a rural area in the United States of America," Chemosphere, 34, 1297-1314(1997).   DOI   ScienceOn
25 Ogura I., Masunaga S., and Nakanishi J., "Congener-specific characterization of PCDDs/PCDFs in atmospheric deposition: comparison of profiles among deposition, source, and environmental sink," Chemosphere, 45, 173-183(2001).   DOI   ScienceOn
26 Yoshinori Ikenaka, Heesoo Eun, Eiki Watanabe, Fujio Kumon, and Yuichi Miyabara, "estimation of sources and inflow of dioxins and polycyclic aromatic hydrocarbons from the sediment core of Lake suwa, Japan" Environ. Pollut., 138, 529-537 (2005).   DOI   ScienceOn
27 Evers, E. H. G., Laane, R. W. P. M., Groeneveld, G. J. J., and Olie, K., "Levels, temporal trends and risk of dioxins and related compounds in the Dutch aquatic environment," Org. Compds, 28, 117-122(1996).
28 Miyabara Y., Hashimoto S., Sagai M, and Morita M., "PCDDs and PCDFs in vihicle exhaust paticles in Japan," Chemosphere, 39, 143-150(1999).   DOI   ScienceOn
29 Shigeki Masunaga, Takumi Takasuga, and Junko Nakanishi, "Dioxin and dioxin-like PCB impurities in some Japanese agrochemical formulations," Chemosphere, 44, 873-885(2001).   DOI   ScienceOn
30 박석운, 김경수, 김종국, 공단지역 주변 토양 중 PCBs 농도 분포 및 발생원 추정에 관한 연구, 대한환경공학회지, 29 (5), 521-527(2007).