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http://dx.doi.org/10.4491/KSEE.2011.33.10.731

Catalytic Ozonation of Phenol  

Lee, Cheal-Gyu (Department of Environmental Engineering, Chongju University)
Woo, Jeong-Hun (Department of Environmental Engineering, Chongju University)
Publication Information
Journal of Korean Society of Environmental Engineers / v.33, no.10, 2011 , pp. 731-738 More about this Journal
Abstract
In this study AOPs of $O_3/UV$ radiation, $O_3/Mg(OH)_2/UV$ radiation and $O_3/MgO/UV$ radiation system for phenol treatment in aqueous solution was performed in a laboratory scale circulating batch reacter. Flow rate of ozone 1.0 L/min, ozone concentrations $150{\pm}10mg/L$ was maintained constantly at the above-mentioned oxidation processes. During the oxidation processes the $COD_{Cr}$ and TOC was measured in the composition. The pseudo first-order rate constants of the processes was $5.12{\times}10^{-5}$, $1.19{\times}10^{-4}$ and $1.79{\times}10^{-4}sec^{-1}$, and the activation energy was 3.03, 1.79 and $2.32kcal{\cdot}mol^{-1}$ at $20^{\circ}C$, respectively. It was found that both $Mg(OH)_2$ and MgO had remarkable accelerations on degradation of phenol and removal of COD in water. On this basis, $O_3/MgO/UV$ system is an effective and feasible routes for catalytic ozonation of phenol in water.
Keywords
Phenol; AOPs; $Mg(OH)_2$; MgO; Activation Energy;
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