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Characteristics of Chlorination Byproduct Formation of Synthetic Nitrogenous Compounds  

Son, Hee-Jong (Water Quality Research Institute, Waterworks Headquarter, Busan)
Hwang, Young-Do (Water Quality Research Institute, Waterworks Headquarter, Busan)
Roh, Jae-Soon (Water Quality Research Institute, Waterworks Headquarter, Busan)
Bean, Jae-Hoon (Water Quality Research Institute, Waterworks Headquarter, Busan)
Publication Information
Journal of Korean Society of Environmental Engineers / v.32, no.5, 2010 , pp. 523-530 More about this Journal
Abstract
This study was conducted to analyze and determine formation potentials for chlorination disinfection by-products (DBPs) from 14 synthetic nitrogen compounds with or without $Br^-$. 5 of 14 compounds were 3-aminobenzoic acid, 2-aminophenol, aniline, anthranilic acid and 4-nitroaniline that were relatively shown high for formation of THMs/DOC whether or not $Br^-$ presented. 6 compounds that were p-nitrophenol, 3-aminobenzoic acid, 2-aminophenol, aniline, anthranilic acid and 4-nitroaniline were shown high for formation of haloacetic acids (HAAs)/DOC whether or not $Br^-$ presented. Trichloroacetic acid (TCAA) was dominated in 6 compounds. The formation of haloacetonitriles (HANs)/DOC whether or not $Br^-$ presented was high in 3-aminobenzoic acid, 2-aminophenol, aniline and anthranilic acid. Specially, aniline was detected 14.6∼16.1 ${\mu}g/mg$. The formation of chloral hydrate (CH)/DOC and chloropicrin (CP)/DOC were shown high in 3-aminobenzoic acid and 2-aminophenol in 14 compounds. 6 compounds (3-aminobenzoic acid, 2-aminophenol, aniline, anthranilic acid, 4-nitroaniline, p-nitrophenol) and a commercial humic acid were tested for the formation of DBPs/DOC whether or not $Br^-$ presented. When $Br^-$ was added, the DBPs/DOC was higher for the order of aniline> anthranilic acid> 3-aminobenzoic acid> 4-nitroaniline> humic acid> p-nitrophenol> 2-aminophenol. And when $Br^-$ was not added, the DBPs/DOC was higher for the order of anthranilic acid> aniline> p-nitrophenol> humic acid> 4-nitroaniline> 3-aminobenzoic acid> 2-aminophenol.
Keywords
Chlorination By-Products; Synthetic Nitrogenous Compounds; Trihalomethane; Haloacetic acid; Haloacetonitrile; Chloral Hydrate;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
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