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Detection of Extremely Low Concentration Compound and Adsorption by Activated Carbon  

Lee, Sung-Bum (Department of Civil Engineering, Hanyang University)
Yoon, Yeo-Min (CH2ML HILL KOREA)
Choi, Chang-Kyoo (Department of Civil Engineering, Hanyang University)
Jung, Jin-Wook (R&D Center, Samsung Engineering)
Lee, Yong-Woo (R&D Center, Samsung Engineering)
Park, Se-Yong (Department of Civil Engineering, Hanyang University)
Kim, Moon-Il (Department of Civil Engineering, Hanyang University)
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Abstract
Since the difficulty of analysis at low concentration and the uncertainty of the removal mechanism for Nitrosodimethylamine (NDMA) have been reported, this study has detected extremely low concentration $^{14}$C-NDMA using the LSC(Liquid Scintillation Counter) and tested NDMA removal by Powdered Activated Carbon(PAC). The results showed the highest correlation over 99% when samples were measured with the mixture ratio of sample to scintillation liquid of 10 : 10 and at the detection time of 10 min. For $^{14}$C-NDMA removal by the PACs(S-A(Sigma-Aldrich co.) and Dj(Daejung co.)) raging from 50$\sim$10,000 mg/L, $^{14}$C-NDMA was removed over 90% by adsorption treatment. In addition, S-A showed twice greater adsorption capacity than that of Dj. However, the required PAC amount for $^{14}$C-NDMA removal was higher than that of other amine compounds.
Keywords
NDMA; Liquid Scintillation Counter; Adsorption; Disinfection by Product;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 이만호, '분리막과 전해소독장치를 이용한 정수처리공정 연구,' 서울시립대학교, 환경공학과, 박사학위논문, pp. 52-59(2007)
2 Mitch, W. A. and Sedlak, D. L., 'Formation of N-Nitrosodimethylamine(NDMA) from dimethylamine during chlorination,' Environ. Sci. Technol., 36, 588-595(2002)   DOI   ScienceOn
3 Mitch, W. A., Gerecke, A. C., and Sedlak, D. L., 'A N-Nitrosodimethylamine(NDMA) precursor analysis for chlorination of water and wastewater,' Water Res., 37, 3733-3741(2003)   DOI   ScienceOn
4 Bryant, E. A., Fulton, G. P., and Budd, G. C., 'Disinfection alternatives for safe drinking water,' Hazen and Sawyer, 10-20(1992)
5 Tchobanoglous, G., Burton, F. L., Stensel, H. D., 'Wastewater engineering treatment and reuse 4th edition,' (2004)
6 Mitch, W. A., Sharp, J. O., Trussell, R. R., and Valentine, R. L., Alvarez-Cohen, L., Sedlak, D. L., 'N-Nitrosodimethylamine(NDMA) as a drinking water contaminant: a review,' Environ. Eng. Sci., 20(5), 389-404(2003)   DOI   ScienceOn
7 Charrois, J. W. A. and Hrudey, S. E., 'Breakpoint chlorination and free-chlorine contact time: Implication for drinking water N-Nitrosodimethylamine concentrations,' Water Res., 41, 674-682(2007)   DOI   ScienceOn
8 Fleming, E. C., Pennington, J. C., Wachob, B. G., Howe, R. A. and Hill, D. O., 'Removal of N-nitrosodimethylamine from waters using physical-chemical techniques,' J. Hazard. Mater., 51, 151-164(1996)   DOI   ScienceOn
9 김진근, 정상기, 신창수, 조혁진, '국내정수장의 소독부산물 생성 특성,' 상하수도학회논문집, 19(3), 301-311(2005)
10 Elif, P. M. and Sedlak, D. L., 'The fate of wastewaterderived NDMA precursors in the aquatic environment,' Water Res., 40, 1287-1293(2006)   DOI   ScienceOn
11 Dean-Raymond, D. and Alexander, M., 'Plants uptake and leaching of dimethylnitrosamine,' Nature, 262, 394-396(1976)   DOI
12 환경부, '수도시설의 청소 및 위생관리 등에 관한 규칙,' (2007)
13 김승현, 유이종, 'NDMA; 새로운 도전', 대한환경공학회학회지, 24(4), 743-746(2002)