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A Study on the Operational Variables of the UV-TiO$_2$ Based Photocatalytic Air Cleaning System  

Han, Chang-Seok (School of Civil and Environmental Engineering, Yeungnam University)
Chang, Hyuk-Sang (School of Civil and Environmental Engineering, Yeungnam University)
Publication Information
Abstract
A study on the operational variables of the UV-TiO$_2$ based photocatalytic air cleaning system was tried. In this study, to examine effects as various air cleaning system conditions, a duct-type reactor was made, and TiO$_2$ was immobilized on a stainless mesh. Benzene was chosen as a target compound. Removal experiments for benzene were done under different initial benzene concentration, air velocity, TiO$_2$ loading, area coated TiO$_2$ as the same TiO$_2$ loading, and UV light intensity conditions. During the experiments, relative humidity was 55%, and reactor temperature was 45$^{\circ}C$. As a result, the photocatalytic degradation of benzene decreased as the inlet concentration increased. But the photocatalytic degradation increased as the concentration boundary layer thickness, amount of TiO$_2$, area coated TiO$_2$ as the same amount of TiO$_2$, and UV light intensity increased. Based on results of current study, they can be applied to the design of air cleaning system over low level VOCs in the indoor air.
Keywords
Benzene; UV; TiO$_2$; Photocatalytic Reaction; Volatile Organic Compounds(VOCs); Boundary Layer;
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Times Cited By KSCI : 3  (Citation Analysis)
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1 Wang, W., Chiang, L.W., and Ku, Y., "Decomposition of benzene in air streams by UV/$TiO_{2}$ process," J. Hazardous Materials, 101(2), 133-146(2003)   DOI   ScienceOn
2 Ao, C.H., Lee, S.C., Mak, C.L., and Chan, L.Y., 'Photodegradation of volatile organic compounds(VOCs) and NO for indoor air purification using $TiO_{2}$: promotion versus inhibition effect of NO,' Appl. Catal. B: Environ., 42, 119-129(2004)   DOI   ScienceOn
3 Somorjai, G.A., Chemistry in two dimensions ; Surfaces, Cornell University Press Ithaca, U.S.A., 551(1981)
4 정상철, 김병훈, 조용익, 김선재, "CVD법 $TiO_{2}$ 광촉매를 이용한 에틸렌의 광촉매 분해," 대한환경공학회지, 24(11), 1873-1879(2002)
5 정상근, 배귀남, 정주영, 김신도, "흡착.광촉매 반응을 적용한 에어필터의 유해가스 제거 특성," 한국실내환경학회지, 2(2), 138-150(2006)
6 Sano, T., Negishi, N., Uchino, K., Tanaka, J., Matsuzawa, S., and Takeuchi, K., "Photocatalytic degradation of gaseous acetaldehyde on $TiO_{2}$ with photodeposited metals and metal oxides," J. Photochem. Photobiol. A: Chem., 160, 93-98(2003)   DOI   ScienceOn
7 최원용, "$TiO_{2}$ 광촉매 반응 연구," 공업화학, 14(8), 1011-1022(2003)
8 정기원, 이승범, 홍인권, "$UV/TiO_{2}$ 광촉매 공정을 이용한 BTX의 분해특성," 공업화학, 13(6), 524-530(2002)
9 Incropera, F.P. and DeWitt, D.P., Introduction to Heat Transfer, John Wiley & Sons, Inc., 3rd Ed.(1996)
10 전보경, 최금찬, 서정민, "광촉매/광산화를 이용한 VOCs 처리장치 개발," 한국환경과학회지, 15(9), 855-864(2006)   과학기술학회마을   DOI
11 이정우, 장혁상, "화염 합성에 의한 $TiO_{2}$ 제조와 VOCs 제거에 대한 적용 I : 화염 합성 $TiO_{2}$의 광촉매적 성질," 대한환경공학회지, 24(5), 889-900(2002)
12 배신철, 김병하, 김성훈, 조동현, 한규일, 한화택, 열전달 제6판, 사이텍미디어(2002)
13 장한권, 이정우, 장혁상, "예혼합화염 에어로졸 반응기에서 응집체의 형상 전개," 공업화학, 39(5), 563-572(2001)
14 허경욱, 양성봉, 이성화, 홍영기, 신수연, 강정훈, "광촉매 플라즈마 반응에 의한 몇가지 VOCs의 제거에 관한 연구," 한국대기환경학회지, 16(4), 373-380(2000)
15 Prandtl, L., Uber Flüssigkeitsbewegung bei sehr kleiner Reibung, In: Proc. 3rd Int. Math. Congress, Heidelberg, pp. 484-491(1904)
16 Choi, W., Ko, J.Y., Park, H., and Chung, J.S., "Investigation of $TiO_{2}$-coated optical fibers for gas-phase photocatalytic oxidation of acetone," Appl. Catal. B: Environ., 31, 209-220(2001)   DOI   ScienceOn
17 Kim, S.B. and Hong, S.C., "Kinetic study for photocatalytic degradation of volatile organic compounds in air using thin film $TiO_{2}$ photocatalyst," Appl. Catal. B: Environ., 35, 305-315(2002)   DOI   ScienceOn
18 Yamazaki, S., Fujinaga, N., and Araki, K., "Effect of sulfate ions for sol-gel synthesis of titania photocatalyst," Appl. Catal. A: General, 210, 97-102(2001)   DOI   ScienceOn
19 Jeong, J., Sekiguchi, K., Lee, W., and Sakamoto, K., "Photodegradation of gaseous volatile organic compounds (VOCs) using $TiO_{2}$ photoirradiated by an ozone-producing UV lamp: decomposition characteristics, identification of by-products and water-soluble organic intermediates," J. Photochem. Photobiol. A: Chem., 169, 279-287(2005)   DOI   ScienceOn
20 Ao, C.H., Lee, S.C., Zou, S.C., and Mak, C.L., "Inhibition effect of $SO_{2}$ on $NO_{x}$ and VOCs during the photodegradation of synchronous indoor air pollutants at parts per billion(ppb) level by $TiO_{2}$," Appl. Catal. B: Environ., 49, 187-193(2004)   DOI   ScienceOn
21 Hager, S. and Bauer, R., "Heterogeneous photocatalytic oxidation of organics for air purification by near UV irradiated titanium dioxide," Chemosphere, 38(7), 1549-1559(1999)   DOI   ScienceOn
22 박달근, 김범준, 이중기, 변동진, 윤운영, 이원재, 성준용, "공기중의 벤젠제거에 대한 산화티타늄 광촉매 반응특성," 한국대기환경학회지, 16(4), 389-397(2000)
23 Blasius, M., "Grenzschichten in Flüssigkeiten mit Kleiner Reibung," Z Math. Phys., 56(1), (1908)