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Spectroscopic Characterization and Seasonal Distribution of Aquatic Humic Substances Isolated from Han River Water  

Kim, Hyun-Chul (Water Environment and Remediation Center, Korea Institute of Science and Technology)
Lee, Seock-Heon (Water Environment and Remediation Center, Korea Institute of Science and Technology)
Kim, Kyung-Ju (Department of Urban Engineering, Graduate School of Engineering, University of Tokyo)
Yu, Myong-Jin (Department of Environmental Engineering, University of Seoul)
Publication Information
Journal of Korean Society of Environmental Engineers / v.29, no.5, 2007 , pp. 540-547 More about this Journal
Abstract
Humic substances(HS) from Han River water was physic-chemically isolated by fractionational methods to investigate the seasonal distribution and to characterize the properties compared with intrinsic humic materials. Various HS samples were analyzed by element, Fourier transform infrared(FT-IR), proton nuclear magnetic resonance$(^1H-NMR)$ and fluorescence analyzers. The portion of HS from Han River water(HRHS) was 47.0% on the average, however it appeared that rainfall event brought about higher fraction of HS in Han River water by the periodic investigation. Aromaticity and humification degree of the HRHS were relatively lower than those of intrinsic humic materials originated from decomposing vegetation. FT-IR, $^1H-NMR$ and fluorescence spectroscopy showed the distinct differences between HRHS and intrinsic humic materials. Commercial humic materials could not represent structural and functional characteristics of local HS. The fluorescence spectroscopy, a relatively simple measurement, was found most useful tool to estimate humification degree for humic materials from particular sources.
Keywords
Humic Substanced(HS); Aromaticity; Humification; Fluorescence; FT-IR; $^1H-NMR$;
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Times Cited By KSCI : 2  (Citation Analysis)
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