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A Study on Analysis of Atmospheric Behavior of PCBs by an One-compartment Box Model  

Kim, Kyoung-Soo (Department of Environmental Engineering, Cheongju University)
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Abstract
To analyze atmospheric fate of PCBs in the Kanto region, Japan, an one-compartment box model was used and the relationship between behavior of each PCB homologue and air temperature was simulated. In addition, the emission rates and the deposition fluxes in the overall Kanto region were estimated by the model. The total emission rate and deposition flux was 3,320 kg/yr and 1,480 kg/yr, respectively. The contribution of advection was ranged from 22 to 38% among elimination processes(advection, dry & wet deposition and degradation) of PCBs from atmosphere. The rates of degradation(OH radical process) for PCBs in the Kanto region would be negligible. This study showed that one-compartment box model can be available to understand the overall atmospheric behavior of PCBs.
Keywords
Kanto Region of Japan; Ambient Air; PCB; One-compartment Box Model;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 Erickson, M. D, Analytical Chemistry of PCBs, Lewis Publishers, Boston, pp. 1-14(1992)
2 Pankow, J. F., 'Common y-intercept and single compound regressions of gas-particles partitioning data vs l/T,' Atmospheric Environment, 25A, 2229-2239(1991)
3 中地史裕, 殘留性汚染物質の大氣を経由した移動の解析, 橫浜國立大學, 碩士學位論文(2004)
4 平井佑介, Congener情報を用いた大氣中のDioxin-like PCBの發生源に關する硏究. 橫浜國立大學, 碩士學位論文(2002)
5 Ogura, J., Masunaga, S., and Nakanishi, J., 'Analysis of atmospheric behavior of PCDDs/PCDFs by a one-compartment box model,' Chemosphere, 53, 399-412(2003)   DOI   ScienceOn
6 (株) エックス都市硏究所, へキサクロロベンゼン等排出インベントリ整備調査業務 結果報告書(2003)
7 Yamassaki, H., Kuwata, K., Miyamoto, H., 'Effects of ambient temperature on aspects of airborne polycyclic aromatic hydrocarbons,' Environmental Science and Technology, 16, 189-194(1982)   DOI   ScienceOn
8 Pankow, J. F. and Bidleman, T. F., 'Interdpendence of the slopes and intercepts from log-log correlationsof measured gas-particle partitioning and vapor pressure- 1. Theory and analysis of available data,' Atmospheric Environment, 26A, 1071-1080(1992)
9 USEPA, 1990 Emissions inventory of section 112(c)(6) pollutants: polycyclic organic matter(POM), 2,3,7,8-tetrachlorodibenzo-p-dioxin(TCDD)/2,3, 7 ,8-tetrachloridibenzof uran(TCDF), polychlorinated biphenyl compounds(PCBs), hexachlorobenzene, mercury, and alkylated lead. Final report, Research Triangle Park, North Carolina(1998)
10 Hutzinger, O., Safe, S., and Zitko, V., The Chemistry of PCB's, 2nd Ed., Robert E. Krieger Publishing Company, Malabar, Florida, pp. 1-17(1983)
11 Sehmel, G. A., 'Particle and gas dry deposition: a review,' Atmospheric Environment, 14, 983-1011(1980)   DOI
12 Ogura, I., Masunaga, S., and Nakanishi, J., 'Atmospheric deposition of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans and dioxin-like polychlorinated biphenyls in the Kanto region, Japan,' Chemosphere, 44, 1473-1487(2001)   DOI   ScienceOn
13 Koester, C. J. and Hites, R. A., 'Photodegradation of polychlorinated debeno-p-dioxins and dibenzofurans adsorbed to fly ash,' Environ. Sci. Technol., 26, 502-507 (1992)   DOI
14 Horstmann, M. and McLachlan, M. S., 'Atmospheric deposition of semivolatile organic compounds to two forest canopies,' Atmospheric Environment, 32, 1799-1809(1998)   DOI   ScienceOn
15 Brubaker, Jr., W. W., and Hites, R. A., 'Polychlorinated dibenzo-p-dioxins and dibenzofurans: Gas-phase hydroxyl radical reactions and related atmospheric removal,' Environ. Sci. Technol., 31, 1805-1810(1997)   DOI   ScienceOn
16 김경수, '일본 요코하마 대기 중 PCBs 가스-입자 분배,' 한국대기환경학회지, 21(3), 285-293(2005)   과학기술학회마을
17 Wania, F. and Daly, G. L, 'Estimating the contribution of degradation in air and deposition to the deep sea to the global loss of PCBs,' Atmospheric Environment, 36, 5581-5593(2002)   DOI   ScienceOn
18 細見正明, '螢光灯からPCBが揮發,' PCB國際シンポジウム, 일본 동경(2002)
19 環境省, PCB特別措置法に基づくPCB廢棄物の保管などの届出の全國集計結果につにて(2003)
20 Atkinson, R., Atmospheric chemistry of PCBs, PCDDs and PCDFs. In: Issues in Environmental Science and Technology: Chlorinated Organic Micropollutants, vol. 6. The Royal Society of Chemistry, Cambridge, UK, pp. 53-72(1997)
21 Zhang, L., Gone, S., Padro, J., and Barrie, L., 'A sizesegregated particle dry deposition scheme for an atmospheric aerosol module,' Atmospheric Environment, 35, 549-560(2001)   DOI   ScienceOn
22 金暻洙, 大氣中PCBの擧動及びMass Balanceに關する硏究, 橫浜國立大學, 博士學位論文(2004)
23 環境省, 日本の廢棄物處理, 平成12年度(2000)