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Quantification of Odorants from Animal Husbandry using Solid-phase Microextraction  

Kim, Jae-Hyuck (Department of Environmental Engineering, University of Seoul)
Choi, Hong-Lim (School of Agricultural Biotechnology, Seoul National University)
Kown, So-Young (Department of Environmental Engineering, University of Seoul)
Lim, Hong-Lae (Department of Environmental Engineering, University of Seoul)
McConnell, Laura L. (US Dept. of Agriculture, Agricultural Research Service, Environmental Quality Laboratory)
Arispe, Susana (Department of Civil & Environmental Engineering, University of Maryland)
Park, Chul-Hwi (Department of Environmental Engineering, University of Seoul)
Kim, Hyun-Ook (Department of Environmental Engineering, University of Seoul)
Publication Information
Journal of Korean Society of Environmental Engineers / v.28, no.2, 2006 , pp. 158-164 More about this Journal
Abstract
Offensive odor from CAFO(concentrated animal feeding operation) and its control have become a significant issue in Korea. Control of odors from the CAFO requires to identify major odorant and their generation mechanisms. In this study, an easy method to collect gas sample and to quantify its odorants is proposed. The method involves on-site odorant extraction with solid-phase microextraction and quantitation with GC/MSD or GC/FID. Analytes of the current study include: trimethylamine(TMA), carbon disulfide($CS_2$), dimethyl sulfide(DMS), dimethyl disulfide(DMDS), acetic acid(AA), propionic acid(PA) and n-butyric acid(BA). The resulting linearity($R^2$) of calibration curve for each analyte was good over the range from several ppbv to ppmv; 0.984 for TMA(0.056-1.437), 0.996 for $CS_2$(0.039-0.999), 0.994 for DMS(0.029-0.756), 0.995 for DMDS(0.024-0.623), 0.992 for AA(0.068-1.314), 0.955 for PA(0.047-0.940), and 0.976 for BA(0.036-0.712). Method detection limits were 5.67, 6.39, 5.78, 25.2, 0.098, 0.363 and 0.099 ppbv for AA, PA, BA, TMA, DMS, $CS_2$, and DMDS, respectively. With the developed method, odorants from poultry, swine, and cattle barns were analysed. All the compounds but DMDS were detected from the sample collected in the poultry barn, and their levels exceeded the representative published human olfactory threshold.
Keywords
SPME(Solid-phase Microextraction); CAFO(Concentrated Animal Feeding Operation); Animal odor; Gas-phase Analysis;
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