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http://dx.doi.org/10.5572/KOSAE.2018.34.3.430

Chemical Characteristics of PM1 using Aerosol Mass Spectrometer at Baengnyeong Island and Seoul Metropolitan Area  

Park, Taehyun (Department of Environmental Science, Hankuk University of Foreign Studies)
Ban, Jihee (Department of Environmental Science, Hankuk University of Foreign Studies)
Kang, Seokwon (Department of Environmental Science, Hankuk University of Foreign Studies)
Ghim, Young Sung (Department of Environmental Science, Hankuk University of Foreign Studies)
Shin, Hye-Jung (Air Quality Research Division, National Institute of Environmental Research)
Park, Jong Sung (Air Quality Research Division, National Institute of Environmental Research)
Park, Seung Myung (Air Quality Research Division, National Institute of Environmental Research)
Moon, Kwang Joo (Air Quality Research Division, National Institute of Environmental Research)
Lim, Yong-Jae (Air Quality Research Division, National Institute of Environmental Research)
Lee, Min-Do (Air Quality Research Division, National Institute of Environmental Research)
Lee, Sang-Bo (Air Quality Research Division, National Institute of Environmental Research)
Kim, Jeongsoo (Air Quality Research Division, National Institute of Environmental Research)
Kim, Soon Tae (Department of Environmental and Safety Engineering, AJOU University)
Bae, Chang Han (Department of Environmental and Safety Engineering, AJOU University)
Lee, Yonghwan (Air Quality Research Division, National Institute of Environmental Research)
Lee, Taehyoung (Department of Environmental Science, Hankuk University of Foreign Studies)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.34, no.3, 2018 , pp. 430-446 More about this Journal
Abstract
To improve understanding of the sources and chemical properties of particulate pollutants on the Korean Peninsula, An Aerodyne High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) measured non-refractory fine particle ($NR-PM_1$) from 2013 to 2015 at Baengnyeong Island and Seoul metropolitan area (SMA), Korea. The chemical composition of $NR-PM_1$ in Baengnyeong island was dominated by organics and sulfate in the range of 36~38% for 3 years, and the organics were the dominant species in the range of 44~55% of $NR-PM_1$ in Seoul metropolitan area. The sulfate was found to be more than 85% of the anthropogenic origin in the both areas of Baengnyeong and SMA. Ratio of gas to particle partition of sulfate and nitrate were observed in both areas as more than 0.6 and 0.8, respectively, representing potential for formation of additional particulate sulfate and nitrate. The high-resolution spectra of organic aerosol (OA) were separated by three factors which were Primary OA(POA), Semi-Volatility Oxygenated Organic Aerosol (SV-OOA), and Low-Volatility OOA(LV-OOA) using positive matrix factorization (PMF) analysis. The fraction of oxygenated OA (SOA, ${\fallingdotseq}OOA$=SV-OOA+LV-OOA) was bigger than the fraction of POA in $NR-PM_1$. The POA fraction of OA in Seoul is higher than it of Baengnyeong Island, because Seoul has a relatively large number of primary pollutants, such as gasoline or diesel vehicle, factories, energy facilities. Potential source contribution function (PSCF) analysis revealed that transport from eastern China, an industrial area with high emissions, was associated with high particulate sulfate and organic concentrations at the Baengnyeong and SMA sites. PSCF also presents that the ship emissions on the Yellow Sea was associated with high particulate sulfate concentrations at the measurement sites.
Keywords
HR-ToF-AMS; $NR-PM_1$; PMF; PSCF; Aerosol;
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