Browse > Article
http://dx.doi.org/10.5572/KOSAE.2015.31.6.497

Time Resolved Analysis of Water Soluble Organic Carbon by Aerosol-into-Mist System  

Cho, In-Hwan (Department of Environmental Engineering, Mokpo National University)
Park, Da-Jeong (Department of Environmental Engineering, Mokpo National University)
Bae, Min-Suk (Department of Environmental Engineering, Mokpo National University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.31, no.6, 2015 , pp. 497-507 More about this Journal
Abstract
Real-time and quantitative measurement of the chemical composition in ambient aerosols represents one of the most challenging problems in the field of atmospheric chemistry. In the present study, time resolved application by Aerosol-into-Mist System (AIMS) following by total organic carbon analyzer (TOC) has been developed. The unique aspect of the combination of these two techniques is to provide quantifiable water soluble organic carbon (WSOC) information of particle-phase organic compounds on timescales of minutes. We also demonstrated that the application of the AIMS method is not limited to water-soluble organic carbon but inorganic ion compounds. By correlating the volume concentrations by optical particle sizer (OPS), water soluble organic carbon can be highly related to the secondary organic products. AIMS-TOC method can be potentially applied to probe the formation and evolution mechanism of a variety of SOA behaviors in ambient air.
Keywords
Water soluble organic carbon; Organic carbon; Optical particle sizer;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Park, D.J., J.Y. Ahn, H.J. Shin, and M.S. Bae (2014) Characteristics of $PM_{2.5}$ Carbonaceous Aerosol using PILS-TOC and GC/MS-TD in Seoul, J. Korean Soc. Atmos. Environ., 30(5), 461-476. (in Korean with English Abstract)   DOI
2 Parshintsev, J., M. Kivilompolo, J. Ruiz-Jimenez, K. Hartonen, M. Kulmala, and M. Riekkola (2010) Particle-into-Liquid Sampler on-line coupled with solidphase extraction-liquid chromatography-mass spectrometry for the determination of organic acids in atmospheric aerosols, J. Chromatogr. A., 1217(33), 5427-5433.   DOI
3 Simpson, C., M. Paulsen, R. Dills, L. Liu, and D. Kalman (2005) Determination of methoxyphenols in ambient atmospheric particulate matter: tracers for wood combustion, Environ. Sci. Technol., 39(2), 631-637.   DOI
4 Sullivan, A., R. Peltier, C. Brock, J. de Gouw, J. Holloway, C. Warneke, A. Wollny, and R. Weber (2006) Airborne measurements of carbonaceous aerosol soluble in water over northeastern United States: method development and an investigation into water-soluble organic carbon sources, J. Geophys. Res. Atmos., 111(D23).
5 Surratt, J., A. Chan, N. Eddingsaas, M. Chan, C. Loza, A. Kwan, S. Hersey, R. Flagan, P. Wennberg, and J. Seinfeld (2010) Reactive intermediates revealed in secondary organic aerosol formation from isoprene, P. Natl. Acad. Sci. USA., 107(15), 6640-6645.   DOI
6 Weber, R., D. Orsini, Y. Daun, Y.N. Lee, P. Klotz, and F. Brechtel (2001) A particle-intoliquid collector for rapid measurement of aerosol bulk chemical composition, Aerosol. Sci. Tech., 35(3), 718-727.   DOI
7 Zahardis, J., B. LaFranchi, and G. Petrucci (2006) The heterogeneous reaction of particle-phase methyl esters and ozone elucidated by photoelectron resonance capture ionization: direct products of ozonolysis and secondary reactions leading to the formation of ketones, Int. J. Mass Spectrom., 253, 38-47.   DOI
8 Bae, M., J. Schauer, J. DeMinter, J. Turner, D. Smith, and R. Cary (2004) Validation of a Semi-Continuous Instrument for Elemental Carbon and Organic Carbon Using a Thermal-Optical Method, Atmos. Environ., 38, 2885-2893.   DOI
9 Bae, M.S., J. Schwab, Q. Zhang, O. Hogrefe, K. Demerjian, S. Weimer, K. Rhoads, D. Orsini, P. Venkatachari, and P. Hopke (2007) Interference of organic signals in highly time resolved nitrate measurements by low mass resolution aerosol mass spectrometry, J. Geophys. Res., 112, D22305.   DOI
10 Chan, M., J. Surratt, A. Chan, K. Schilling, J. Offenberg, M. Lewandowski, E. Edney, T. Kleindienst, M. Jaoui, E. Edgerton, R. Tanner, S. Shaw, M. Zheng, E. Knipping, and J. Seinfeld (2011) Influence of aerosol acidity on the chemical composition of secondary organic aerosol from beta-caryophyllene, Atmos. Chem. Phys., 11, 1735-1751.   DOI
11 Cheng, Y., K.B. He, F.K. Duan, M. Zheng, Y.L. Ma, and J.H. Tan (2009) Positive sampling artifact of carbonaceous aerosols and its influence on the thermal-optical split of OC/EC, Atmos. Chem. Phys., 9, 7243-7256.   DOI
12 Clark, C., S. Nakao, A. Asa-Awuku, K. Sato, and D. Cocker (2013) Real-time study of particle-phase products from alpha-pinene ozonolysis and isoprene photooxidation using particle into liquid sampling directly coupled to a time-of-flight mass spectrometer (PILSToF), Aerosol Sci. Tech., 47, 1374-1382.   DOI
13 Draxler, R.R. and G.D. Rolph (2015) HYSPLIT (HYbrid Single-Particle Lagrangian Integrated Trajectory) Model access via NOAA ARL READY Website (http://www.arl.noaa.gov/HYSPLIT.php). NOAA Air Resources Laboratory, College Park, MD.
14 Dye, C. and K. Yttri (2005) Determination of monosaccharide anhydrides in atmospheric aerosols by use of high-performance liquid chromatography combined with high-resolution mass spectrometry, Anal. Chem., 77(6), 1853-1858.   DOI
15 Jimenez, J., J. Jayne, O. Shi, C. Kolb, D. Worsnop, I. Yourshaw, J. Seinfeld, R. Flagan, X. Zhang, K. Smith, J. Morris, and P. Davidovits (2003) Ambient aerosol sampling using the aerodyne aerosol mass spectrometer, J. Geophys. Res. Atmos., 108(D7).
16 Fahnestock, K., L. Yee, C. Loza, M. Coggon, R. Schwantes, X. Zhang, N. Dalleska, and J. Seinfeld (2014) Secondary organic aerosol composition from C12 alkanes, J. Phys. Chem. A., 119 (19), 4281-4297.
17 Gelencser, A., A. Hoffer, Z. Krivacsy, G. Kiss, A. Molnar, and E. Meszaros (2002) On the possible origin of humic matter in fine continental aerosol, J. Geophys. Res. Atmos., 107(D12).
18 Isaacman, G., K. Wilson, A. Chan, D. Worton, J. Kimmel, T. Nah, T. Hohaus, M. Gonin, J. Kroll, D. Worsnop, and A. Goldstein (2012) Improved resolution of hydrocarbon structures and constitutional isomers in complex mixtures using gas chromatographyvacuum ultraviolet-mass spectrometry, Anal. Chem., 84(5), 2335-2342.   DOI
19 Lavrich, R. and M. Hays (2007) Validation studies of thermal extraction-GC/MS applied to source emissions aerosols. 1. Semivolatile analyte-nonvolatile matrix interactions, Anal. Chem., 79(10), 3635-3645.   DOI
20 Lin, Y., Z. Zhang, K. Docherty, H. Zhang, S. Budisulistiorini, C. Rubitschun, S. Shaw, E. Knipping, E. Edgerton, T. Kleindienst, A. Gold, and J. Surratt (2012) Isoprene epoxydiols as precursors to secondary organic aerosol formation: acid-catalyzed reactive uptake studies with authentic compounds, Environ. Sci. Technol., 46(1), 250-258.   DOI
21 Park, D.J., I.H. Cho, and M.S. Bae (2015) Determination of Amino Acids on Wintertime $PM_{2.5}$ using HPLC-FLD, J. Korean Soc. Atmos. Environ., 31(5), 482-492. (in Korean with English Abstract).   DOI