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http://dx.doi.org/10.5572/KOSAE.2011.27.6.751

Estimating Influence of Biogenic Volatile Organic Compounds on High Ozone Concentrations over the Seoul Metropolitan Area during Two Episodes in 2004 and 2007 June  

Kim, Soon-Tae (Division of Environmental, Civil & Transportation Engineering, Ajou University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.27, no.6, 2011 , pp. 751-771 More about this Journal
Abstract
Biogenic Volatile Organic Compound (BVOC) emissions are estimated with BEIS3.12 (Biogenic Emissions Inventory System version 3.12) over the Seoul Metropolitan Area (SMA) and then used in CMAQ (Community Multiscale Air Quality) simulations for two high ozone episodes in 2004 and 2007 June. The first- and second-order sensitivity coefficients of ozone to BVOC emissions are estimated with High-order Decoupled Direct Method (HDDM) simulation in order to estimate the influence of BVOC emissions on ozone using the Zero-Out Contribution (ZOC) approach. ZOC analysis shows that relative contribution of BVOC emissions on daily maximum 1-hr ozone is as high as 30% for high ozone days above 100 ppb. However simulated isoprene concentrations were over-estimated by a factor of 2 when compared to the observations at the PAMS (Photochemical Air Monitoring Station) for the 2007 episode. When assumed that actual BVOC emissions are 50% less than estimated, the ZOC of BVOC emissions on daily maximum ozone drops by more than 10 ppb for the episode. The result indicates that uncertainty in BVOC emissions may have significant impact on high ozone prediction in the SMA.
Keywords
Biogenic volatile organic compound; Isoprene; Ozone; First- and second-order sensitivities; Uncertainty;
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Times Cited By KSCI : 6  (Citation Analysis)
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