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The Removal of Carbon Dioxide using AMP+HMDA in Absorption/Regeneration Continuous Process  

Choi, Won-Joon (Department of Environmental Engineering, Pusan National University)
Cho, Ki-Chul (Department of Environmental Engineering, Pusan National University)
Oh, Kwang-Joong (Department of Environmental Engineering, Pusan National University)
Publication Information
Journal of Korean Society for Atmospheric Environment / v.21, no.5, 2005 , pp. 507-513 More about this Journal
Abstract
Increasing amounts of anthropogenic $CO_2$ emitted to the atmosphere are believed to be a significant factor in global climate change. Hence, the method of chemical absorption has been suggested to separate and recover acid gases such as $CO_2$. In this study, the characteristics of absorption and regeneration of $CO_2$ for the absorbent which adding HMDA (hexamethylenediamine) into AMP (2-amino-2-methyl-1-propanol), hindered amine, was investigated in lab-scale absorption/regeneration reactor. As a result of this study, the removal efficiency of $CO_2$ increased when adding $5.9\%,\;11.7\%\;and\;23.4\%$ HMDA into $30\%$ AMP respectively. Also, the removal efficiency of $CO_2$ increased $6.5\%,\;8.4\%,\;10.3\%$ respectively as compared to AMP alone when the gas flow rate was 7.5 SL/min. In addition, all absorbents used in the study revealed the high stripping efficiency, which was almost $99\%$, at the temperature of $110^{\circ}C$. Thus, the regeneration tower should be operated at $110^{\circ}C$. At this time, the concentration of exhausted $CO_2$ was higher than $99\%$.
Keywords
Absorption; Regeneration; AMP (2-amino-2-methyl-1-propanol); HMDA (hexame-thylenediamine);
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