Browse > Article
http://dx.doi.org/10.7464/ksct.2015.21.4.265

Manufacturing and Electrochemical Characteristics of SnO2/Li4Ti5O12 for Lithium Ion Battery  

Yang, A-Reum (Department of Chemical Engineering, Chungbuk National University)
Na, Byung-Ki (Department of Chemical Engineering, Chungbuk National University)
Publication Information
Clean Technology / v.21, no.4, 2015 , pp. 265-270 More about this Journal
Abstract
In order to increase the capacity of the lithium ion battery, the capacity of the anode should be increased. SnO2 and Li4Ti5O12 were studied to replace the graphite as the anode materials. In this study, SnO2/Li4Ti5O12 composite materials were synthesized by solid-state method. The study reported here attempts to enhance the electrochemical capacity of Li4Ti5O12 through the incorporation of SnO2. Sn-based Li ion storage materials are loaded on Li4Ti5O12 surface. The SnO2/Li4Ti5O12 composite material has higher capacity than Li4Ti5O12, but the cycling capacity was decreased due to SnO2.
Keywords
Lithium secondary battery; Anode material; $SnO_2$; $Li_4Ti_5O_{12}$; Electrochemical properties;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Shen, L., Yuan, C., Luo, H., Zhang, X., Xu, K., and Xia, Y., "Facile Synthesis of Hierarchically Porous Li4Ti5O12 Microspheres for High Rate Lithium Ion Batteries," J. Mater. Chem., 20, 6998-7004 (2012).
2 Zhao, Y., Li, J., Wu, C., and Guan, L., “A General Strategy for Synthesis of Metal Oxide Nanoparticles Attached on Carbon Nanomaterials,” Nanoscale Res. Lett., 6, 71-75 (2011).
3 Courtney, I. A., and Dahn, J. R., “Electrochemical and In-situ X-ray Diffraction Studies of the Reaction of Lithium with Tin oxide composites,” J. Electrochem. Soc., 144, 2045-2052 (1997).   DOI
4 Courtney, I. A., and Dahn, J. R., "Key Factors Controlling the Reversibility of the Reaction of Lithium with SnO2 and Sn2BPO6 Glass," J. Electrochem. Soc., 144, 2943-2948 (1997).   DOI
5 Sivashanmugam, A., Gopukumar, S., Thirunakaran, F., Nithya, C., and Prema, S., "Novel Li4Ti5O12/Sn Nano-composites as Anode Material for Lithium Ion Batteries," Mater. Res. Bull., 46, 492-500 (2011).   DOI
6 Colbow, K. M., Dahn, J. R., and Haering, R. R., "Structure and Electrochemistry of the Spinel Oxides LiTi2O4 and Li4/3Ti5/3O4," J. Power Sources, 26, 397-402 (1989).   DOI
7 Jhan, Y., Lin, C., and Duh, J., "Preparation and Characterization of Ruthenium Doped Li4Ti5O12 Anode Material for the Enhancement of Rate Capability and Cyclic Stability," Mater. Lett., 65, 2502-2505 (2011).   DOI
8 Zhang, H., Song, H., Chen, X. Zhou, J., and Zhang, H., "Preparation and Electrochemical Performance of SnO2@Carbon Nanotube Core-shell Structure Composites as Anode Material for Lithium-ion Batteries," Electrochim. Acta, 59, 160-167 (2012).   DOI
9 Zhao, Y., Dong, G., Duan, L. Qiao, J. Zhang, D. Wang, L., and Qui, Y., “Impact of Sn Precursors on Solution-processed Amorphous Zinc-tin Oxide Films and their Transistors,” RSC Adv., 2, 5307-5313 (2012).   DOI
10 Lassali, T., Boodts, J., and Bulhões, L., "Effect of Sn-precursor on the Morphology and Composition of Ir0.3Sn0.7O2 Oxide Films Prepared by Sol-gel Process," J. Non-cryst. Solids, 273, 129-134 (2000).   DOI
11 Yuan, T., Cai, R., Wang, K., Ran, R., Liu, S., and Shao, Z., "Combustion Synthesis of High-performance Li4Ti5O12 for Secondary Li-ion Battery," Ceram. Int., 35, 1757-1768 (2009).   DOI
12 Huang, J., and Jiang, Z., “The Preparation and Characterization of Li4Ti5O12/Carbon Nano-tubes for Lithium Ion Battery,” Electrochim. Acta, 53, 7756-7759 (2008).   DOI
13 Ohzuku, T., Ueda, A., and Yamamoto, N., "Zero-strain Insertion Material of Li[Li1/3Ti5/3]O4 for Rechargeable Lithium Cells," J. Electrochem. Soc., 142, 1431-1435 (1995).   DOI
14 Shen, C., Zhang, X., Zhou, Y., and Li, H., "Preparation and Characterization of Nanocrystalline Li4Ti5O12 by Sol-gel Method," Mater. Chem. Phys., 78, 437-441 (2002).
15 Hao, Y., Lai, Q., Chen, Y., Lu, J., and Ji, X., “In Situ Deposition Method Preparation of Li4Ti5O12-SnO2 Composite Materials for Lithium Ion Batteries,” J. Alloy. Compd., 162, 404-409 (2008).
16 Li, X., Qu, M., Hual, Y., and Yu, Z., "Preparation and Electrochemical Performance of Li4Ti5O12/Carbon/Carbon Nanotubes for Lithium Ion Battery," Electrochim. Acta, 55, 2978-2982 (2010).   DOI
17 Yin, Y., Li, S., Fan, Z., Ding, X., and Yang, S., "Synthesis of Novel Anode Li4Ti5O12/C with PAN as Carbon Source and its Electrochemical Performance," Mater. Chem. Phys., 130, 186-190 (2011).   DOI