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http://dx.doi.org/10.4150/KPMI.2018.25.1.60

Recent Developments in H2 Production Photoelectrochemical Electrode Materials by Atomic Layer Deposition  

Han, Jeong Hwan (Department of Materials Science and Engineering, Seoul National University of Science and Technology)
Publication Information
Journal of Powder Materials / v.25, no.1, 2018 , pp. 60-68 More about this Journal
Abstract
The design and fabrication of photoelectrochemical (PEC) electrodes for efficient water splitting is important for developing a sustainable hydrogen evolution system. Among various development approaches for PEC electrodes, the chemical vapor deposition method of atomic layer deposition (ALD), based on self-limiting surface reactions, has attracted attention because it allows precise thickness and composition control as well as conformal coating on various substrates. In this study, recent research progress in improving PEC performance using ALD coating methods is discussed, including 3D and heterojunction-structured PEC electrodes, ALD coatings of noble metals, and the use of sulfide materials as co-catalysts. The enhanced long-term stability of PEC cells by ALD-deposited protecting layers is also reviewed. ALD provides multiple routes to develop improved hydrogen evolution PEC cells.
Keywords
Photoelectrochemical electrode; Hydrogen evolution; Atomic Layer Deposition; Heterojunction; Nanostructure;
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