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http://dx.doi.org/10.5806/AST.2020.33.3.134

Study on simultaneous determination of aromatic material causing allergic in children's products by GC-MSD  

Ko, Kyeong Mok (Sports Facilities Center, Korea Conformity Laboratories)
Rhu, Chan Joo (Consumer Product Center, Korea Conformity Laboratories)
Ko, Byeong Rae (Environmental Testing Center, Korea Conformity Laboratories)
Lee, Seok Ki (Department of Applied Chemistry, Woosuk University)
Publication Information
Analytical Science and Technology / v.33, no.3, 2020 , pp. 134-142 More about this Journal
Abstract
Twenty-one allergy-induced aromatic material in children's products were analyzed using gas chromatography mass spectrometer(GC-MSD). The analytes were extracted using an automatic Soxhlet extractor, centrifuged for 10 minutes in a fast freezing centrifuge, and the supernatant was filtered with a syringe filter and then transferred into a 2 mL vial and injected in a split mode. In the established condition, the calibration curve showed linearity with a determination coefficient of 0.9981 or more. Sensitivity was 0.3145 ~ 1.6757, which showed a fairly wide range of sensitivity for each substance. The detection limit of the device was 0.0016 ~ 0.0423 ㎍/mL and the maximum detection limit was less than 0.05 ㎍/mL. The method detection limit ranged from 0.0030 ~ 0.0589 ㎍/mL. In addition, the limit of quantification ranged from 0.0096 to 0.1876 ㎍/mL, with precision ranging from 0.41 to 10.49 % and accuracy ranging from 83 to 116 %. The analytical method developed in this study was applied to commercial products.
Keywords
allergy; aromatic material; children's products; fragrance; GC-MSD;
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