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http://dx.doi.org/10.5806/AST.2015.28.6.370

Determination of phenol using solid-phase extraction and HPLC/MSD/FLD in water  

Lee, Taejoon (Gangwon-do Institute of Health and Environment)
Park, Keun-Young (Gangwon-do Institute of Health and Environment)
Pyo, Dongjin (Department of chemistry, Gangwon National University)
Publication Information
Analytical Science and Technology / v.28, no.6, 2015 , pp. 370-376 More about this Journal
Abstract
An analytical method for determining phenol considered priority pollutants of the US EPA and precursor of toxic phenolic compounds by solid-phase extraction (SPE) and high performance liquid chromatographic systems (HPLC) equipped with fluorescence and mass selective detectors have been developed. The SPE process for sample preconcentration was performed on a commercially available Oasis HLB cartridge packed with polymeric sorbents. The effect of pH, elution solvent, and elution volume on the recoveries of the analytes were investigated with HPLC/FLD. Average recovery of >87.0% was achieved with 60 mg sorbents using 5 mL of methanol as an elution solvent at pH=3.
Keywords
phenol; hplc; solid phase extraction(spe); hplc/msd;
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