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http://dx.doi.org/10.5806/AST.2007.20.2.091

Analytical method of the polychlorinated biphenyls in soil using GC/ECD and GC/MS  

Kim, Tae-Seung (National institute of Environmental Research, Environmental Diagnostics Research Department)
Shin, Sun-Kyoung (National institute of Environmental Research, Environmental Measurement Standards Department)
Yoon, Jeong-Ki (National institute of Environmental Research, Environmental Diagnostics Research Department)
Kim, Jong-Ha (National institute of Environmental Research, Environmental Diagnostics Research Department)
Kim, Hyoung Seop (Korea Environment & Resources Corporation)
Lee, Jeong Ah (National institute of Environmental Research, Environmental Diagnostics Research Department)
Publication Information
Analytical Science and Technology / v.20, no.2, 2007 , pp. 91-108 More about this Journal
Abstract
This study was investigated both the Korean official soil test method and the international various methods for PCBs in soil sample. The analytical guideline of PCBs in contaminated soil were proposed based on the official soil test methods by discussing the extraction, column cleanup, instrumental conditions, quantification methods of peak matching and individual isomers. The total 28 soil samples were selected by consideration of PCBs-contamination, land use etc., and then analyzed using gas chromatography/electron capture detection (GC/ECD) and gas chromatography/mass spectrometry(GC/MS). In this study, the PCBs were not detected as peak matching method using GC/ECD, but PCBs detected $0.002{\sim}0.487{\mu}g/kg$ using GC/MS in background concentrations.
Keywords
PCBs; Soil; GC/ECD; Aroclor; GC/MS;
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  • Reference
1 Environmental Health Criteria 140, PCBs, WHO, 1993
2 M. D. Erickon, Analytical Chemistry of PCBs, Lewis Publishers, New York, 1997
3 환경부, 폐기물공정시험방법, 2004
4 M. Manz, K.-D. Wenzel, U. Dietze, G. Schuurmann, The Science of the Total Environment, 277, 187-198 (2001)   DOI   PUBMED   ScienceOn
5 C.-T. Fu, S.-C. Wu, Chemosphere, 62, 1786-1794 (2006)   DOI   ScienceOn
6 W. Wilcke, M. Krauss, G. Safronov, A. D. Fokin, M. Kaupenjohann, Environmental Pollution, 141, 327-335 (2006)   DOI   ScienceOn
7 J. L. Zhou, K. Maskaoui, Y.W. Qiu, H.S. Hong, Z.D. Wang, Environmental Pollution, 113, 373-384 (2001)   DOI   ScienceOn
8 임숙현, 구미헌, 김호성, 정기호, 한국환경과학회, 학 술발표초록집, 93-95, 1997
9 A. Motelay-Massei, D. Ollivon, B. Garban, M.J. Teil, M. Blanchard, M. Chevreuil, Chemosphere, 55, 555- 565 (2004)   DOI   ScienceOn
10 국립환경연구원, 폴리염화비페닐류 (PCBs)함유 폐기 물의 적정관리방안에 관한 연구, 2003
11 DIN EN 61619, Insulating liquids-Contamination by polychlorinated biphenyls (PCBs)-Method of determination by capillary column gas chromatography, 1997
12 R. Gibson, M.-J. Wang, E. Padgett, A. J. Beck, Chemosphere, 61, 1336-1344 (2005)   DOI   ScienceOn
13 V. den Berg, M. Birnbaum and A. Bosabel, Environmental Health Perspectives, 106, 775-792 (1998)   DOI   ScienceOn
14 H. Nakata, Y. Hirakawa, M. Kawazoe, T. Nakabo, K. Arizono, S.-I. Abe, T. Kitano, H. Shimada, I. Watanabe, W. Li, X. Ding, Environmental Pollution, 133, 415-429 (2005)   DOI   ScienceOn
15 국립환경과학원, 절연유 중 폴리염화비페닐류 (PCBs) 세부분석지침, 2004
16 S. N. Meijer, W. A. Ockenden, A. Sweetman, K. Breivik, J.O. Grimalt, K. C. Jones, Environmental Scince Technology, 37, 667-672 (2003)   DOI   ScienceOn
17 신호상, 오윤숙, 한국분석화학회, 12(2), (1999)
18 환경부, 토양오염공정시험방법, 2002.
19 일본 JIS방법, 2001
20 C. Backe, I. T. Cousins, P. Larsson, Environmental Pollution, 128, 59-72 (2004)   DOI   ScienceOn
21 ISO 10382, Soil quality-Determination of organochlorine pesticides and polychlorinated biphenyls-Gas chromatographic method with electron capture detection, 2002
22 ぎょうせい, 'PCB 처리기술가이드북', 1999.
23 국립환경과학원, 2003 내분비계장애물질 조사연구사업 결과보고서, 2004.p
24 Francesca Borghini, Joan O. Grimalt, Juan C. Sanchez- Hernandez, Roberto Bargagi, Chemosphere, 58, 271-278 (2005)   DOI   ScienceOn
25 US EPA Method 1668, Chlorinated biphenyl congeners in water, soil, sediment, and tissue by HRGC/HRMS, 1999
26 R. Barra, P. Popp, R. Quiroz, C. Bauer, H. Cid, W. von Tumpling, Chemosphere, 58, 905-915 (2005)   DOI   ScienceOn
27 A. Covaci, C. Hura, P. Schpens, The Science of the Total Environment, 280, 143-152 (2001)   DOI   PUBMED   ScienceOn
28 L. Guzzella, C. Roscioli, L. Vigano, M. Saha, S.K. Sarkar, A. Bhattacharya, Environment International, 31, 523-534 (2005)   DOI   ScienceOn
29 日本環境測定分析協會, 産業廢棄勿分析マニュアル, 1997
30 P. Schmid, E. Gujer, M. Zennegg, T. D. Bucheli, A. Desaules, Chemosphere, 58, 227-234 (2005)   DOI   ScienceOn
31 US EPA Method 8082A, Polychlorinated biphenyls (PCBs) by GC, November 2000