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http://dx.doi.org/10.5806/AST.2006.19.3.211

Self-assembly directed synthesis of tubular conducting polymer inside the channels of MCM-41  

Showkat, Ali Md. (Department of Chemistry Graduate School, Kyungpook National University)
Lee, Kwang-Pill (Department of Chemistry Graduate School, Kyungpook National University)
Gopalan, Anantha Iyengar (Department of Chemistry Graduate School, Kyungpook National University)
Reddy, K. Raghava (Department of Chemistry Graduate School, Kyungpook National University)
Kim, Sang-Ho (Department of Chemistry Graduate School, Kyungpook National University)
Choi, Seong-Ho (Department of Chemistry, Hannam university)
Publication Information
Analytical Science and Technology / v.19, no.3, 2006 , pp. 211-217 More about this Journal
Abstract
Diphenyl amine (DPA) was polymerized inside the channels of the mesoporous silica (MCM-41). MCM-41 (C) and MCM-41 (D) were prepared with cetyltrimethyl ammonium bromide (CTAB) and dodecyltrimethyl ammonium bromide (DTAB), respectively and used as hosts. Initially, the self assembly of DPA inside the pores of MCM-41 was made in ${\beta}$-naphthalene sulfonic acid (NSA) medium and subsequently poly (diphenylamine), PDPA was formed by oxidative polymerization. $N_2$ adsorption-desorption measurements of PDPA loaded MCM-41 (C) and MCM-41 (D) show variations in pore volume and surface area between them. A tubular form of poly (diphenylamine), PDPA was envisaged to form in the pores of MCM-41 and supported by high resolution transmission microscopy. The presence of PDPA inside the channel of MCM-41 was further confirmed by FTIR spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction.
Keywords
Mesoporous silica (MCM-41); poly (diphenylamine); self-assembly;
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