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Study on Adsorption and Recovery of Heavy Metal Ions, Cd(II) and Pb(II), by Chitin  

Kim, Eun-Kyung (Department of Chemical Engineering, Kongju National University)
Cho, Young-Koo (Department of Chemical Engineering, Samchok National University)
Kwon, Young-Du (Department of Environmental Engineering, Donghae University)
Park, Mi-A (Department of Environmental & Applied Chemical Engineering, Kangnung National University)
Kim, Han-Soo (Department of Environmental & Applied Chemical Engineering, Kangnung National University)
Park, Kwang-Ha (Department of Environmental & Applied Chemical Engineering, Kangnung National University)
Publication Information
Analytical Science and Technology / v.15, no.2, 2002 , pp. 163-171 More about this Journal
Abstract
The adsorption characteristics of Cd(II) and Pb(II) ions has been studied by using chitin as an adsorbent. The pure chitin was obtained from the extraction of red-crab shell dumped by fish factory. Adsorption kinetics of Cd(II) and Pb(II) ions on the chitin reached at the maximum adsorption within two minutes. Adsorbed amounts of heavy metals were pH 7.0>10.5>3.5 in the following order. Adsorption ratio by chitin was 21${\sim}$99% for Cd(II) ion and 24${\sim}$95% for Pb(II) ion. Recovery ratio of Cd(II) ion on the chitin was 22${\sim}$53%, and that of Pb(II) ion was 22${\sim}$73%. The adsorption behavior of these heavy metals was explained well by Freundlich adsorption isotherm.
Keywords
chitin; adsorption; recovery; heavy metal; batch method;
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  • Reference
1 D. Brady, A. Stoll, and F. R. Duncan, Environmental Technology, 15, 428-429(1994).
2 N. J. Robinson, Journal of Applied Phycology, 1, 5(1989).
3 M. J. Bebianno and W. J. Langston, Marine Biology, 108, 91(1991).
4 H. B. Xue, W. Stumm and L. Sigg, Wat. Res., 22(7), 917(1988).
5 M. Tsezos and T. J. Horikohi, Appl. Microbiol., 16, 88(1982).
6 M. G. Lee, J. H. Suh and S. K. Kam, J. Kor. Env. Sci. Soc., 6(15), 531(1997).
7 K. H. Park, Y. H. Kim, M. A. Park, S. I. Park, T. J. Kim and K. C. Lee, J. Kor. Env. Sci. Soc., 7(6), 803 (1998).
8 K. H. Park, B. O. Jun, H. S. Kim and Y. H. Kim, Anal. Sci. & Tech, 9(4), 373(1996).
9 K. H. Park, M. A. Park and Y. H. Kim, Anal. Sci. & Tech, 13(3), 368(2000).
10 J. S. Hong, H. G. Kim, G. H. and Lee, H. S. Ahn, J. of KSEE, 6(2), 63-71(1984).
11 B. Y. Son, K. T. Lee and O. J. Kang, J. Chitin Chitosan, 5(4). 228-223(2000).
12 N. J. Robinson and P. J. Jackson, Physiol. Plant, 67, 499(1986).
13 M. S. Masri and M. Friendman, Environmental Science and Technology, 7, No. 10(1973).
14 I. R. Davinson T. H. Reed, Phycologia, 24, 449 (1985).
15 R. W. Henderson, D. S. Andrews, G. R. Lightsey and N. A. Poonawala, Bull. Environ. Contam. Toxicol., 17, 355(1976).
16 D. Khummongkol, G. S. Canterford and C. Freyer, Biotechnol. Bioeng., 24, 2643(1982).
17 H. Crist, K. O. Norman Shank and M. Nguyen, Env. Sci. Tech., 15, 1212(1981).
18 J. Pavicic, B. Raspor and D. Martincic, Marine Biology, 115, 435(1993).
19 K. H. Ahn, Y. K. Shin and K. H. Suh, J. Kor. Env. Sci. Soc., 6(1), 61(1997).
20 Foster, A. B. and Webber, J. M., Advances in Carbohydrate Chemistry, 15, 371-393(1960).
21 M. Rockstein, 'Biochem. of Insects, Univ. of Miami Coral Gable', Florida Academic Press, New York 1978.
22 D. Kurita, Y. Koyma and S. Chikaoka, Polymer. J., 20. 1083-1089(1988).
23 Metcalf & Eddy, 'Wastewater engineering', 3rd ed., McGraw-Hill, 318-319(1991).
24 P. O. Harris and G. J. Ramelow, Environ. Sci. Technol., 24, 220(1990).
25 EPA Report No. 540/5-90/005a, cincinati, OH, August (1990).
26 G. H. Wikfors, A. Neeman and P. J. Jackson, Mar. Ecol. Prog. Ser., 79, 163(1991).
27 F. E. Sami and H. J. Abdel, Egypt. J. Microbio. 1, 21, 263(1983).
28 R. A. A. Muzzarelli, 'Chitin', Pergamon Press, Oxford 1977.
29 F, L. Slejko,'Adsorption Technology : A Step-by-Step Approach to Process Evaluation and Application', Marcel Dekker, New York 1985.
30 S. C. Gupta and P. B. Goldsrough, Plant Physiol., 97, 306(1991).
31 T. Skowronski and M, Przytocka, Chemosphere, 15, 77(1983).
32 K. H. Park, M. A. Park, K. H. Kim and Y. H. Kim, Anal. Sci. & Tech, 12(5), 360(1999).
33 B. Volesky, 'Biosorption and biosorbents,'Biosorpion of Heavy metals, CRC Press, Boston, 3-5(1990).
34 P. R. Austin, and Sennet, S., 'Chitin in Nature and technology', Plenum press, New York 1986.