Application of Cationic Cetyltrimethylammonium Chloride Surfactant to Collecting of Hanji Sludge

A technique which could collect the traditional and the industrial hanji fibrous sludge efficiently from wastewater using a cationic surfactant cetyltrimethylammonium chloride (CTAC) was developed. When the concentration of CTAC was $1{\mu}g/mL$ in wastewater that the amount of the traditional hanji fibrous sludge was about 0.08 g/L, the collecting yield was more than 95% and the collecting time was less than 30 sec. When only CTAC was used to collect the industrial hanji fibrous sludge, about 90% of collecting yield was obtained at more than $15{\mu}g/mL$ CTAC. But the sludge layer at the surface of solution was not stabilized and the flotation time was relatively longer. And, when $5{\mu}g/mL$ CTAC and various amount of PAMID$^{(R)}$ was added to the industrial hanji sludge, the collecting yield was increased and sludge layer also was more stabilized. But the collecting yield was higher in the traditional hanji sludge than in the industrial hanji sludge.

양이온 계면활성제 Cetyltrimethylammonium Chloride를 이용한 한지 슬러지의 제거

전통한지 섬유질 슬러지 및 기계한지 섬유질 슬러지를 양이온 계면활성제 cetyltrimethylammonium chloride(CTAC)를 이용하여 효과적으로 제거하는 방법에 대해 연구하였다. 전통한지 슬러지 시료일 경우 고형분의 양이 약 0.08 g/L 일 때 CTAC의 농도가 $1{\mu}g/mL$ 되면 제거율이 95% 이상 되었으며, 이 때 걸리는 시간은 30초 이내이었다. 기계한지 슬러지에 대해 CTAC만을 이용하여 슬러지를 제거하였을 때 $15{\mu}g/mL$ 이상에서 90% 정도의 제거효율을 보였으나 슬러지 층이 안정하지 못하고, 부상시간이 비교적 오래 걸렸다. $5{\mu}g/mL$의 CTAC에 PAMID$^{(R)}$를 첨가하여 부상시켰을 때는 CTAC만을 이용하였을 때 보다 제거율이 증가하였으며 슬러지 층도 또한 안정하였다. 기계한지 슬러지보다 전통한지 슬러지를 제거할 때 더 효율적이었다.