The purpose of this study was to determine the effects of surface-treatment by zinc salts on break-through and adsorption capacity of toluene. Firstly, the coconut activated carbon treated the surface with zinc salts, were exposed by the spike sample(toluene, 69.02ppm, $260.1mg/m^3$), and then the effects of zinc salts were examined by using the gas adsorption kinetics. The results obtained were as follows : 1) BET(Brumaure Emmett Teller) surface area were $954.4m^3/g$ in coconut activated carbon treated with 0.0001 N $Zn(NO_3)_3$ $6H_2O$, and $830.3m^2/g$ in coconut activated carbon treated with 0.0001 N $ZnCl_2$. 2) Migration was decreased in coconut activated carbon treated with the thin level of zinc salts. 3) Breakthrough volume were 73.07 L in coconut activated carbon treated with 0.0001 N $Zn(NO_3)_3$ $6H_2O$, and 72.76 L in charcoal treated with 0.0001 N $ZnCl_2$. 4) ${\tau}$ values(the time required for 50% breakthrough) were 1046.1 min in coconut activated carbon treated with 0.0001 N $ZnCl_2$ and 921.2 min in coconut activated carbon treated with 0.0001 N $Zn(NO_3)_3$ $6H_2O$. 5) Maximum adsorption capacity was 53.9 mg/tube in coconut activated carbon treated with 0.0001 N $ZnCl_2$ and 47.4 mg/tube in coconut activated carbon treated with 0.0001 N $Zn(NO_3)_3$ $6H_2O$. In conclusion, the coconut activated carbon treated the surface with the thin concentration of zinc salts, decreased the breakthrough and increased the BET surface area and the adsorption capacity in case of sampling airborne toluene.

The purpose of this study is to evaluate the difference of noise level according to noise measuring methods in the noisy working environments. Sound pressure level(SPL), equivalence sound level(Leq) and personal noise exposure dose(Dose) in the fifty-nine unit workplaces of the twenty-eight industries were measured and relating factors which were affected noise level were investigated. The results were as follows ; 1. The noise levels were $88.70{\pm}5.68dB(A)$ by SPL, $89.07{\pm}5.41dB(A)$ by Leq and $89.07{\pm}5.69$ by Dose. The differences of noise levels by three measuring methods were statistically significant(P<0.001) by repeated measure ANOV A. 2. Comparing with noise levels by general classes of noise exposure, noise levels of continuous noise were $89.14{\pm}5.19dB(A)$ by SPL, $89.45{\pm}4.65dB(A)$ by Leq and $90.04{\pm}5.09$ by Dose. Noise levels of intermittent noise were $87.90{\pm}6.52dB(A)$ by SPL, $88.40{\pm}6.63dB(A)$ by Leq and $90.10{\pm}6.80$ by Dose. The differences noise level of noise measuring methods by general classese of noise exposure were statistically not significant by repeated measure ANOV A. 3. Interaction between general classese of noise exposure and noise measuring methods for noise level was not statistically significant by repeated measure ANOVA. And the noise level by noise measuring methods were statistically significant by repeated measure ANOV A(P<.001) 4. Comparing with noise levels by unit workplace size, noise levels of large unit workplace were $90.73{\pm}5.87dB(A)$ by SPL, $91.32{\pm}5.50dB(A)$ by Leq and $91.82{\pm}6.06$ by Dose and noise levels of middle unit workplace were $88.31{\pm}5.26dB(A)$ by SPL, $88.41{\pm}4.83dB(A)$ by Leq and $89.69{\pm}5.05$ by Dose. And noise levels of small unit workplace were $94.89{\pm}4.10dB(A)$ by SPL, $85.35{\pm}4.11dB(A)$ by Leq and $86.87{\pm}4.98$ by Dose. The noise level differences of noise measuring methods by unit workplace size were statistically significant by repeated measure ANOV A(P<.05). 5. The noise level by noise measuring methods were statistically significant by repeated measure ANOV A(P<.001). But Interaction between workplace size and noise level measuring methods for noise level was not statistically significant by repeated measure ANOVA. According to the above results, there was a difference of the noise level among the three measuring methods. Therefore we must use the personal noise exposure dose using by noise dose meter, possible, to prvent occupational hearing loss in noisy working environment.

Twenty(20) large commercial buildings located in Seoul with friable sprayed-on surface insulation material on ceilings were investigated for asbestos content in bulk material by polarized light microscopy and for airborne fiber concentrations in buildings by phase contrast microscopy. In addition, such building-related variables as building age, numbers of traffic, airflow, surface conditions of the ceiling, temperature, and humidity were studied for any correlation with airborne fiber concentrations. The results were as follows: 1. Chrysotile asbestos was found in two bulk samples with 3-5% content and with <1%in one sample out of total 20 bulk samples collected. Glass fiber and mineral wool were the two major constituents of the bulk samples. 2. The ceiling surfaces were very friable in 16 buildings and were relatively hard in 4 buildings. The friability of the surface material was dependent upon the type and the amount of binder that had been mixed with the sprayed-on surface material. 3. Airborne fiber concentrations were log-normally distributed and the geometric mean(geometric standard deviation) fiber concentrations in the underground parking lots, inside buildings, and outdoor ambient air were 0.0063(1.97)f/cc, 0.0068(2.29)f/cc, and 0.0033(2.36)f/cc, respectively. 4. No significant relationship of airborne fiber concentrations and all building-related variables studied except humidity was found. The results of this study suggest that the sprayed-on surface insulation material found in some commercial buildings may possibly be contaminated with asbestos. Since most of the ceiling surfaces surveyed were very friable and poorly maintained and the airborne fiber concentrations were relatively high, there is a possibility of asbestos fiber contamination in these buildings, particularly at those buildings with asbestos-contaminated surface material. Since poorly maintained surface conditions were thought to be a source of high airborne fiber concentrations, there is a urgent need of a systematic operation and maintenance program. Further study of non-occupational asbestos exposure in general population utilizing advanced analytical technique such as transmission electron microscopy is highly recommended.

This study was conducted to introduce fundamental data of hand-arm vibration and noise exposure levels with impact wrenches(double-hammer impact wrenches and oil-pulse impact wrenches) used in automobile assembly lines considering the process variables and tool variables. In studing, products per day, required time screwing the bolts or nuts per bolts or nut were considered as process variables, and capacity of bolts or nuts, air consumptions per minute, tool weights, RPM were considered as tool variables. Hand-arm vibration levels of 3 axis in each hand were measured using the instruments compling with ISO/DIS 5349 and noise levels were measured using a noise logging dosimeter. The results were as follows : 1. Required time to screwing the bolt or nut by oil-pulse impact wrenches is shorter than double-hammer impact wrenches but total daily exposure time of oil-pulse impact wrenches was higher than double-hammer impact wrenches because the number of bolts or nuts per cycle was many. 2. Oil-pulse impact wrenches have been used to screwing the large bolt or nut in comparing with double-hammer impact wrenches and required time to screwing the bolts or nuts were shorter than double-hammer impact wrenches because oil-pulse impact wrenches were using high RPM and large air consumption per minute. Noise level of oil-pulse impact wrenches was 8 dB(A) lower than double-hammer impact wrenches. 3. Dominant hand-arm vibration levels of double-hammer impact wrenches in each hand were $8.24m/sec^2$ of Zh axis in right hand and $9.60m/sec^2$ of Xh axis in left hand. Dominant hand-arm vibration level of oil-pulse impact wrenches in each hand was $2.59m/sec^2$ of Xh axis in right hand and $3.23m/sec^2$ of Yh axis in left hand. 4. In double-hammer impact wrenches, corresponding hand-arm vibration levels of Xh, Yh, Zh axis in left hand were higher than hand-arm vibration levels of right hand in 3 axis. In oil-pulse impact wrenches, Xh axis of right, Yh axis of left, Zh axis of left were higher than the corresponding hand-arm vibration levels of Xh, Yh, Zh axis in right and left hand. 5. Correlation coefficients among Xh, Yh. Zh axis of right and left hand hand-arm vibration levels in double-hammer impact wrenches and oil-pulse impact wrenches were commonly high in Yh axis and correlation coefficients of Yh axis in double-hammer impact wrenches and oil-pulse impact wrenches were 0.76 and 0.86,respectively. 6. As a measure repetitiveness, plotting total daily exposure time with the number of bolts or nut per cycle, direct correlation was shown between repetitiveness and hand-arn vibration exposure, and correlation coefficient between the number of bolts or nut per cycle and total daily exposure time in double-hammer impact wrenches, oil-pulse impact wrenches were 0.84 and 0.50, respectively. 7. Considering the total acceleration level and tool variables in double-hammer impact wrenches and oil-pulse impact wrenches, air consumption in right hand, and bolt or nut capacity in left hand were commonly the variable that explainability was high. Considering the noise and tool variables in double-hammer impact wrenches and oil-pulse impact wrenches, air consumption per minute was commonly the variable that explainability was high.

The size characteristics of lead particle which is one of the important factors associated with absorption of lead were ignored in establishing lead standard. This study was conducted to investigate distribution of lead particles by operation of industry. Aerodynamic Mass Median Diameters (MMD) of airborne lead particles in the battery and litharge manufacturing industry were $14.1{\mu}m$ and $15.1{\mu}m$, respectively. There was no significant difference between those two values(p>0.05). However, the diameters in radiator manufacturing and secondary smelting industry were $1.3{\mu}m$, $4.9{\mu}m$, respectively. Those were significantly smaller than the particle sizes in other industries(p<0.05). Total lead concentrations in the secondary smelting industry were higher than those in the battery and litharge manufacturing industry. Total lead concentrations in other industries except radiator manufacturing industry exceeded the standard of $50{\mu}g/m^3$. Only radiator manufacturing industry indicated lead concentrations significantly lower than those in other industries(p<0.05). Concentrations of lead particles smaller than $1{\mu}m$ defined as respirable fraction by OSHA's CPA model assumption were $72.4{\mu}g/m^3$ in the secondary smelting industry, exceeding $50{\mu}g/m^3$. The relationship of concentrations between total lead and lead of particles smaller than $1{\mu}m$ was log Y = 0.46 logX + 0.06(n=119, $r^2=0.44$, p=0.0001). Relationship of respirable lead concentrations between OSHA and ACGIH was significantly detected in the litharge and battery manufacturing industry(p=0.0001), but was not significant in the radiator(p=0.2720) and secondary smelting manufacturing industry(p=0.2394). As MMDs of lead particles generated in industry were small, difference of respirable lead concentration between OSHA and ACGIH became smaller. There was a significant difference between concentrations respirable lead defined by two organizations such as OSHA and ACGIH in the battery and litharge manufacturing industry. Average concentration of respirable lead by ACGIH definition was 43.3 % of total lead in secondary smelting and 48.9 % in radiator manufacturing industry, and lower fractions were indicated in battery and litharge manufacturing industry. Relationships of total lead with IPM, TPM, and RPM were significant respectively(p=0.0001) and lead concentrations by particle size could be estimated using this relationship. Linear regression equation between total lead concentration(X) and ACGIH-RPM concentration(Y) was log Y = 0.76 log X - 0.40($r^2=0.89$, p=0.0001).

The airborne concentrations of the welding fumes produced during $CO_2$ arcwelding process at shipbuilding, shiprepairing, container manufacturing and car accessary manufacturing industry were investigated. The effects how much reduced the welding fume were checked when the portable fan was used. The results were as follows; 1.The geometric mean of welding fume concentration in shipbuilding factory was $10.05mg/m^3$. This exposure concentration was higher than other 3 manufacturing industries at 95% confidence level. 2. The sampling filters for welding fume could be digested with acid within 1 hour by microwave oven. The recoveries for investigated metal elements were all over 95%. 3. The optimal wavelength could be selected for the simultaneous analysis of 8 metal elements by ICP(Inductively Coupled Plasma). 4. Noxious gases($O_1,NO_2$) produced during $CO_1$ gas arc welding process were detected that the concentration of ozone($O_1$) was less than 0.01 ppm and that of nitrogen dioxide($NO_2$) was 0.01-0.03 ppm. 5. The geometric mean of welding fume particle diameter was $1.26{\mu}m$ and geometric standard deviation was 1.51 for the counts when particle an analyzer(ELZONE) had been used. 6. When the portable fan had been used,the reduced percent of total welding fume for workers was about 47.8% when portable fan was applied to blow and 71.7% when to exhaust.

This study was performed to evaluate methods for determination of airbone mercury in industrial environments. Three methods, such as Hopcalite method, passive monitoring method and Jerome method were evaluated at two (2) fluorescent lamp manufacturing Plants in Korea during a period from May 24 to May 31, 1994 and the result are as follows: 1. The average were concentrations of airbone mercury were $26{\mu}g/m^3$ by Hopcalite method, $25{\mu}g/m^3$ by passive monitoring method, and $38{\mu}g/m^3$ by the Jerome method, respectively, which were below the permissible exposure limit of $50{\mu}g/m^3$ established by both the Korean Ministry of Labor and ACGIH. However, 12 out of 49 cases(24.4%) in plant A and 2 out of 31 cases(6.5%) in plant B were in excess of the standard. 2. The relationship between the results by Hopcalite method and the passive monitoring method was significant(r=0.892). 3. The variation among three results by eath of three methods were different by process. The highest variation was determined at quality control process("process b") which invoved in large variation of concentrations. 4. When short term high concentrations were produced, the Hopcalite method was more efficient then the passive method.

This study was designed to investigate the difference of time weighted average(TWA) of noise levels and noise doses by the different operating parameter settings such as exchange rate, threshold level and criterion level for noise dosimeter in the field measurements of noise at industrial working environments. The time weighted averages of noise level and noise doses for noise working environments were determined by noise dosimeter on 80 workers employed at 20 industrial establishments of 8 industries. The results obtained were as follows: 1. The mean time weighted average(TWA) of the noise working environments by the operating parameter settings showed 93.4 dB(A) in 3 dB of exchange rate, 80 dB of threshold level and 90dB of criterion level 92.0 dB(A) in 3 dB-exchange rate, 90 dB-threshold level and 90 dB-criterion level, in 90.8 dB(A) in 5 dB of exchange rate, 80 dB of threshold level and 90 dB of criterion level, and 86.7 dB(A) in 5 dB of exchange rate, 90 dB of threshold level and 90dB of criterion level. 2. ln group of noise level less than 90 dB(A), mean TWAs of 80 dB of threshold level were significantly higher than that of 90 dB of threshold level in 3 dB and 5 dB of exchange rate. 3. The case exceeded threshold limit value of noise was 49(61.3 %) in 3dB, 80dB and 90 dB setting, 44(55.0 %) in 3 dB, 90 dB, 90 dB setting, 33(41.3 %) in 5 dB, 80dB, 90 dB setting and 26(32.5%) in 5 dB, 90 dB, 90 dB setting. Above considerations in mind, it is suggested that exchange rate and threshold level be specified in related laws and regulations in the evaluation of working environments noise.

This study was designed to evaluate the effects of temperature and humidity on the sampling efficiency of mixed organic vapors of l,2-DCE, benzene, and MIBK by 3 different types of diffusion monitors. Independent variables used for the study were temperatures ($25^{\circ}C$, $35^{\circ}C$), humidities (30%, 80%), and vapor concentrations (low, medium, and high). In addition, vapor concentrations measured by the traditional charcoal tube method were used as reference values and were compared with those of by diffusion monitors. The results were as follows: 1. The desorption efficiencies(DE) of 1,2-DCE and benzene from charcoal tubes and from diffusion monitors ranged from 98% to 105%. In contrast, the DEs of MIBK from charcoal tubes and diffusion monitors except DM1 ranged from 71% to 85%. The DE of MIBK from DM1 was 98%. 2. No statistically significant differences of 1,2-DCE concentrations and the sampling efficiencies regardless of temperatures and humidities studied between charcoal tube and 3 diffusion monitors were found. 3. At 80% humidity, increasing frequencies of 1,2-DCE breakthrough at higher temperature and higher vapor concentration measured by charcoal tubes were observed. 4. No statistically significant difference of benzene concentrations were found between charcoal tube and diffusion monitors except DM3. The sampling efficiencies of DM3 were statistically significantly lower at all experimental conditions except the $35^{\circ}C$ and 30% humidity condition. 5. No statistically significant difference of MIBK concentrations were found between charcoal tube and diffusion monitors except DM3. The sampling efficiencies of DM3 were statistically significantly higher at higher humidity conditions regardless of temperature. Although statistically not significant, sampling efficiency of MIBK showed positive correlation with humidity while negative correlation with concentration was observed. 6. For sampling 1,2-DCE and benzene, no significant variations of concentrations among three diffusion monitors regardless of temperature and humidity conditions were found. For MIBK sampling, however, wide variations with increasing humidity among diffusion monitors were obtained. In conclusion, this study suggests that diffusion monitors will be a reasonables substitute for the traditional charcoal tubes for sampling non-polar organic vapors at temperature and humidity conditions studied. For polar organic vapors, use of an alternative desorption solution other than CS2 is recommended because of its low desorption efficiency. In addition, since variable among diffusion monitors for polar organic vapors particularly at higher humidity conditions were observed, further study is recommended of the effects of humidity on the performance of diffusion monitors.

This study was performed in a diatomite factory located at Pohang City, Kyeongsangbuk-Do. The major objectives were to evaluate sampling and analytical methods of diatomaceous earth dust. Concentrations of total and respirable diatomaceous earth dust were measured. Size distribution of dust was analyzed by a personal cascade impactor and the particle size analyzer which is an application of multiple diffraction method. Also crystalline silica in respirable and total dust samples was analyzed quantitatively by X-ray diffraction and Fourie Transform Infrared Spectroscopy(FTIR). The results were as follows: The airborne total and respirable dust concentrations, particle size distribution, and cristalline silica(quartz) concentrations showed approximately a log-normal distribution. The means of totaldust concentrations at flour maufacturing, fire brick grinding and packaging processes exceeded the Korean and American Conference of Governmental Industrial Hygienists standards, $10mg/m^3$. The size distribution of diatomaceous earth dust was log-normal and identified as the rspirable particle mass and thoracic particle mass. The crystalline silica in respirable and total dust samples was identified to quartz and contained about 10 % in those samples. Finally, it is necessary to study the applicability of multiple diffraction for particle size distribution to compare the ACGIH's size selective sampling with other materials containing crystalline silica. Also, advanced quantitative study to X-ray diffraction and FTIR methods shoud be carried out 10 verify general and specific characteristics for respirable crystalline silica.

This research has a purpose to achieve experimental data used for design of ventilation systems necessary for indoor air quality control and their operation and management. For the study, spatial concentration distribution of indoor air quality according to pollutant site in a simplified model chamber. In low flow ventilation, flow pattern of indoor air was mainly influenced by diffusion and additionally, spatial distribution was formed by convection. Distribution of ventilation efficiency according to each pattern of model chamber was evaluated. It was confirmed that diffusion patterns of a pollutant among sites were formed, centering around main stream areas of supply and exhaust outlets.