DOI QR코드

DOI QR Code

LiFePO4 배터리의 습식 재활용 방법에 대한 최근 연구 동향 고찰

Comprehensive Review on Wet Recycling methods for LiFePO4 Batteries

  • 김대원 (고등기술연구원 신소재공정센터) ;
  • 김희선 (고등기술연구원 신소재공정센터) ;
  • 최희락 (부경대학교 재료공학과)
  • Dae-Weon Kim (Advanced Materials and Processing Center, Institute for Advanced Engineering (IAE)) ;
  • Hee-Seon Kim (Advanced Materials and Processing Center, Institute for Advanced Engineering (IAE)) ;
  • Hee-Lack Choi (Department of Material Science & Engineering, Pukyong National University)
  • 투고 : 2024.09.06
  • 심사 : 2024.10.14
  • 발행 : 2024.10.31

초록

본 논문에서는 LiFePO4 배터리의 재활용을 위한 습식 공정에 관한 최신 연구 동향에 대하여 종합적으로 고찰하였다. 특히, LiFePO4 배터리에서 리튬을 선택적으로 회수하는 다양한 화학적 침출 방법과 그 효율을 분석하였으며, 강산과 약산을 이용한 리튬 회수 기술, 강산화제를 활용한 침출 공정, 그리고 염을 이용한 동형 치환 반응을 통한 리튬 회수 기술 등을 다루고 있으며, 각 방법의 장단점과 최적의 조건을 제시하였다. 또한, 본 연구는 리튬 회수율을 극대화하기 위해 최적의 침출 조건을 탐구하고, 다양한 화학적 반응식을 제시하여 리튬, 철, 인 등의 선택적 회수 가능성에 대하여 논의하였으며, 최종적으로 LiFePO4 배터리 재활용 기술의 발전과 실용화에 기여할 중요한 참고 자료로서 활용되었으면 한다.

This paper provides a comprehensive review of the latest research trends in wet processing methods for recycling LiFePO4 batteries. In particular, it analyzes various chemical leaching methods for the selective recovery of lithium from these batteries, evaluating their efficiency. The study covers lithium recovery techniques using strong and weak acids, leaching processes utilizing strong oxidants, and lithium recovery through isomorphic substitution reactions involving salts. Additionally, this research explores optimal leaching conditions to maximize lithium recovery, discusses various chemical reactions for the selective recovery of lithium, iron, and phosphorus, and offers insights into their potential. Ultimately, the paper aims to serve as a valuable reference for the advancement and practical application of LiFePO4 battery recycling technologies.

키워드

과제정보

This work was supported by a Research Grant of Pukyong National University(2023 year).

참고문헌

  1. Nam, J. H., 2021 : Overview of secondary batteries, Technology & Innovation, 450, pp.13-14. 
  2. Shin, Y. R., 2021 : Market Trends and Technological Development of Secondary Batteries for Electric Vehicles, KDB Report, 790, pp.34-53. 
  3. Ding, Y., Fu, J., Zhang, S., et al., 2024 : Advances in recycling LiFePO4 from spent lithium batteries : A critical review, Separation and Purification Technology, 338, pp.126551-126563. 
  4. Vasconcelos, D., Tenorio, J., 2023 : Circular Recycling Strategies for LFP Batteries: A Review Focusing on Hydrometallurgy Sustainable Processing, Metals, 13(3), pp.543-571. 
  5. Fatima, N., Solangi, N., Safdar, F., 2022 : A short overview of recycling and treatment of spent LiFePO4 battery, North American Academic Research, 5(7), pp.76-87. 
  6. Shin, E., Kim, S., Noh, J., et al., 2015 : A green recycling process designed for LiFePO4 cathode materials for Li-ion batteries, J. Mater. Chem. A, 3(21), pp.11493-11502. 
  7. Bian, D., Sun, Y., Li, S., et al., 2016 : A novel process to recycle spent LiFePO4 for synthesizing LiFePO4/C hierarchical microflowers, Electrochim. Acta, 190, pp.134-140. 
  8. Yang, Y., Zheng, X., Cao, H., et al., 2017 : A Closed-Loop Process for Selective Metal Recovery from Spent Lithium Iron Phosphate Batteries through Mechanochemical Activation, ACS Sustain. Chem., 5, pp.9972-9980. 
  9. Li, H., Xing, S., Liu, Y., et al., 2017 : Recovery of Lithium, Iron, and Phosphorus from Spent LiFePO4 Batteries Using Stoichiometric Sulfuric Acid Leaching System, ACS Sustainable Chem. Eng., 5, pp.8017-8024. 
  10. Zheng, R., Zhao, L., Wang, W., et al., 2016 : Optimized Li and Fe recovery from spent lithium ion batteries via a solution-precipitation method, RSC Adv., 6, pp43613-43625. 
  11. Cai, G., Fung, K., Ng, K., et al., 2014 : Process Development for the Recycle of Spent Lithium Ion Batteries by Chemical Precipitation, Ind. Eng. Chem. Res., 53(47), pp.18245-18259. 
  12. Song, Y., Xie, B., Song, S., et al., 2021 : Regeneration of LiFePO4 from spent lithium-ion batteries via a facile process featuring acid leaching and hydrothermal synthesis, Green Chem., 23, pp. 3963-3972. 
  13. Lou, W., Zhang, Y., Zhang, Y., et al., 2021 : Leaching performance of Al-bearing spent LiFePO4 cathode powder in H2SO4 aqueous solution, Trans. Nonferrous Met. Soc. China, 31, pp. 817-831. 
  14. Wu, D., Wang, D., Liu, Z., et al., 2022 : Selective recovery of lithium from spent lithium iron phosphate batteries using oxidation pressure sulfuric acid leaching system, Trans. Nonferrous Met. Soc. China, 32, pp. 2071-2079. 
  15. Kim, D. W. and Kim, H. S., 2023 : Efficient Selective Recovery of Lithium from Waste LiFePO4 Cathode Materials using Low Concentration Sulfuric Solution and 2-step Leaching Method, Clean Technol., 29(2), pp.87-94. 
  16. Mahandra, H., and Ghahreman, A., 2021 : A sustainable process for selective recovery of lithium as lithium phosphate from spent LiFePO4 batteries, Resources, Conservation & Recycling, 175, pp.105883-105894. 
  17. Peng, D., Zhang, J., Zou, J., et al., 2021 : Closed-loop regeneration of LiFePO4 from spent lithium-ion batteries : "A feed three birds with one scone" strategy toward advanced cathode materials, J. of Cleaner Production, 316, pp.128098-128109. 
  18. Zhang, J., Hu, J., Liu, Y., et al., 2019 : Sustainable and Facile Method for the Selective Recovery of Lithium from Cathode Scrap of Spent LiFePO4 Batteries, ACS Sustain. Chem. Eng., 7(6), pp.5626-5631. 
  19. Yang, Y., Meng, X., Cao, H., et al., 2018 : Selective recovery of lithium from spent lithium iron phosphate batteries : a sustainable process, Green Chem, 20(13), pp. 3121-3133. 
  20. Fan, E., Li, L., Zhang, X., et al., 2018 : Selective Recovery of Li and Fe from Spent Lithium Ion Batteries by an Environmentally Friendly Mechanochemical Approach, ACS Sustain. Chem. & Eng., 6(8), pp. 11029-11035. 
  21. Li, L., Bian, Y., Zhang, X., et al., 2019 : A Green and Effective Room-Temperature Recycling Process of LiFePO4 Cathode Materials for Lithium-Ion Batteries, Waste Management, 85, pp.437-444. 
  22. Kumar, J., Shen, X., Li, B., et al., 2020 : Selective Recovery of Li and FePO4 from Spent LiFePO4 Cathode Scraps by Organic Acids and the Properties of the Regenerated LiFePO4, Waste Management, 113, pp.32-40. 
  23. Kim, D. W., Ban S. H., Kim H. S., et al., 2024 : A Study on the Prior Leaching and Recovery of Lithium from the Spent LiFePO4 Cathode Powder Using Strong Organic Acid, Clean Technol., 30(2), pp.105-112. 
  24. Yadav, P., Jie, C. J., Tan, S., et al., 2020 : Recycling of Cathode from Spent Lithium Iron Phosphate Batteries, J. of Hazardous Materials, 399, pp.123068-123078. 
  25. Zhang, J., Hu, J., Liu, Y., et al., 2019 : Sustainable and Facile Method for the Selective Recovery of Lithium from Cathode Scrap of Spent LiFePO4 Batteries, ACS Sustain. Chem. Eng., 7(6), pp.5626-5631. 
  26. Liu, K., Liu, L., Tan, Q., et al., 2021 : Selective extraction of lithium from a spent lithium iron phosphate battery by mechanochemical solid-phase oxidation, Green Chemistry, 23(3), pp.1344-1352. 
  27. Yue, X., Zhang, C., Zhang, W., et al., 2021 : Recycling phosphorus from spent LiFePO4 battery for multifunctional slow-release fertilizer preparation and simultaneous recovery of Lithium, Chemical Engineering J., 426, pp. 131311-131323. 
  28. Peng, D., Zhang, J., Zou, J., et al., 2021 : Closed-loop regeneration of LiFePO4 from spent lithium-ion batteries: A "feed three birds with one scone" strategy toward advanced cathode materials, Journal of Cleaner Production, 316, pp.128098. 
  29. Kim, H. S., Kim, D. W., Jang, D. H., et al., 2022 : A Study on the Leaching Effect and Selective Recovery of Lithium Element by Persulfate-based Oxidizing Agents from Waste LiFePO4 Cathode, Resources Recycling, 31(4), pp.40-48. 
  30. Gangaja, B., Nair, S., and Santhanagopalan, D., 2021 : Reuse, Recycle, and Regeneration of LiFePO4 Cathode from Spent Lithium-Ion Batteries for Rechargeable Lithium- and Sodium-Ion Batteries, ACS Sustainable Chem. Eng., 9, pp.4711-4721. 
  31. Liu, P., Fei, Z., Zhang, Y., et al., 2022 : Efficient Oxidation Approach for Selective Recovery of Lithium from Cathode Materials of Spent LiFePO4 Batteries, JOM, 74(5), pp.1934-1944. 
  32. Yan, T., Zhong, S., Zhou, M., 2020 : High-efficiency method for recycling lithium from spent LiFePO4 cathode, Nanotechnology Reviews, 9, pp.1586-1593. 
  33. Liu, K., Tan, Q., Liu, L., et al., 2019 : Acid-free and selective extraction of lithium from spent lithium iron phosphate batteries via a mechanochemically induced isomorphic substitution, Environmental Science & Technology, 53(16), pp.9781-9788. 
  34. Dai, Y., Xu, Z., Hua, D., et al., 2020 : Theoretical-molar Fe3+ recovering lithium from spent LiFePO4 batteries: an acid-free, efficient, and selective process, Journal of Hazardous Materials, 396, pp.122707. 
  35. Zhang, B., Qu, X., Chen, X., et al., 2022 : A sodium salt-assisted roasting approach followed by leaching for recovering spent LiFePO4 batteries, Journal of Hazardous Materials, 424, pp.127586. 
  36. Niu, Y., Peng, X., Li, J., et al., 2023 : Recovery of Li2CO3 and FePO4 from spent LiFePO4 by coupling technics of isomorphic substitution leaching and solvent extraction, Chinese Journal of Chemical Engineering, 54, pp.306-315. 
  37. Kim, H. S., Kim, D. W., Chae, B. M., et al., 2023, A Study on the Leaching and Recovery of Lithium by Reaction between Ferric Chloride Etching Solution and Waste Lithium Iron Phosphate Cathode Powder, Resources Recycling, 32(3), pp.9-17.