Corrosion Science and Technology

The Corrosion Science Society of Korea (한국부식방식학회)
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Interfacial Degradation Reaction between Cathode and Solid Electrolyte in All-Solid-State Batteries

고체전해질과 양극의 계면 열화 반응

  • Jae-Hun Kim (School of Materials Science and Engineering, Kookmin University)
  • 김재헌 (국민대학교 신소재공학부)
  • Received : 2024.07.30
  • Accepted : 2024.08.13
  • Published : 2024.08.30
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Abstract

The need for efficient and sustainable energy storage solutions has emerged due to a rapidly increasing energy demand and growing concerns about environmental issues. Among various energy storage methods, lithium secondary batteries are widely used in a variety of electronic devices such as smartphones, laptops, electric vehicles, and large-scale power storage systems due to their high energy density, long lifespan, and cost competitiveness. Recently, all-solid-state batteries (ASSBs) have attracted great attention because they can reduce the risk of fire associated with liquid electrolytes. Additionally, using high-capacity alternative anodes and cathodes in ASSBs can enhance energy density. However, ASSBs that use solid electrolytes experience a degradation in their electrochemical performances due to resistance at solid-solid interfaces. These interfaces can also result in poor physical contact and the presence of products formed from chemical and electrochemical reactions. Solving this interface problem is a critical issue for the commercialization of ASSBs. This review summarizes interfacial reactions between the cathode and solid electrolyte, along with research aimed at improving these interactions. Future development directions in this field are also discussed.

Keywords

Acknowledgement

이 논문은 2023년도 대한민국 교육부와 한국연구재단의 지원(NRF-2021S1A5A2A03065436)과 2024년도 대한민국 산업통상자원부 및 한국산업기술기획평가원의 연구비 지원(20026752)에 의해 수행된 연구임.

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